M
Martin Lutz
Researcher at Utrecht University
Publications - 595
Citations - 18692
Martin Lutz is an academic researcher from Utrecht University. The author has contributed to research in topics: Ligand & Catalysis. The author has an hindex of 62, co-authored 592 publications receiving 17289 citations. Previous affiliations of Martin Lutz include University of Amsterdam & ETH Zurich.
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Journal ArticleDOI
Cyclometalation of aryl-substituted phosphinines through C-H-bond activation: a mechanistic investigation.
Leen E. E. Broeckx,Sabriye Güven,Frank J. L. Heutz,Martin Lutz,Dieter Vogt,Dieter Vogt,Christian Müller,Christian Müller +7 more
TL;DR: A concerted base-assisted metalation-deprotonation (CMD) mechanism, which is electrophilic in nature, is proposed based on the observed trends during the mechanistic investigation of the cyclometalation reaction.
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C-H activation of 2, 4, 6-Triphenylphosphinine: unprecedented formation of cyclometalated [(P^C)Ir(III)] and [(P^C)Rh(III)] complexes
TL;DR: An unprecedented C-H activation of 2,4,6-triphenylphosphinine by Ir( III) and Rh(III) has been observed, demonstrating a remarkable difference in reactivity between these two structurally related aromatic heterocycles.
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A Structural Model for [Fe]-Only Hydrogenases.
Vincent E. Kaasjager,Richard K. Henderson,Elisabeth Bouwman,Martin Lutz,Anthony L. Spek,Jan Reedijk +5 more
TL;DR: The complex is a first generation structural model for [Fe]-only hydrogenases; it incorporates both a sulfur-rich environment and coordinated carbon monoxide ligands, as observed in [NiFe]-hydrogenases.
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A Multicomponent Reaction Towards N‐(Cyanomethyl)amides
Niels Elders,Eelco Ruijter,Frans J. J. de Kanter,Elwin Janssen,Martin Lutz,Anthony L. Spek,Romano V. A. Orru +6 more
TL;DR: The group contributed in this field by trapping 1-azadienes generated by the three-component reaction (3-CR) between phosphonates, nitriles and aldehydes, with various reactants resulting in novel 4-CRs for a variety of heterocyclic scaffolds.
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iPr2N–P═Fe(CO)4 in Olefinic Solvents: A Reservoir of a Transient Phosphinidene Complex Capable of Substrate Hopping
Jan B. M. Wit,G. Bas de Jong,Marius Schakel,Martin Lutz,Andreas W. Ehlers,J. Chris Slootweg,Koop Lammertsma +6 more
TL;DR: In this paper, Collman's reagent and iPr2NPCl2 were used in the olefins 1-pentene and 1-hexene to give the more stable phosphirenes that display dynamic covalent behavior.