Martin Lutz

TL;DR: The single-crystal X-ray structures of two new linear trinuclear copper(II) complexes of 3,5-pyrazoledicarboxylic acid (H3L) are reported in this article.

TL;DR: In this paper, a P-stereogenic bis-phosphoramidite pincer palladium complexes were derived from (S)-(−)-α,α-diphenyl-2-pyrrolidinemethanol and (S)(+)-indolinemethyl-indolinerethanol.

TL;DR: A transmetallation route, using silver(I) precursors, to several zero- and di-valent palladium complexes with chelating bis(N-heterocyclic carbene) ligands bearing various N-substituents has been established and complex 3a showed activity and selectivity comparable to its monodentate counterparts in the semihydrogenation of 1-phenyl-1-propyne with molecular hydrogen.

TL;DR: Electrochemical and spectroscopic studies, together with the information gained from IR spectroelectrochemical studies of the dimetallic complex [Ru(TPPdSCN)(tpy)](PF6)2, are indicative of charge redistribution through the bridging ligand TPBr.

TL;DR: This investigation unambiguously reveals that thermodynamic immiscibility and crystallization direct the self-assembly of ODMS-based block molecules, and highlights the “ingredient approach” to obtain perfect order in sub-10 nm structured materials with a simple strategy built on a crystalline “hard” moiety and an incompatible “soft” ODMS partner.