Martin Lutz

TL;DR: The results show that TRIR spectroscopy is a powerful tool to investigate photoinduced electron transfer in potential dihydrogen-producing catalytic complexes, and that way to optimize their performance by rational approaches.

TL;DR: In this paper, the synthesis and X-ray crystal structure of a number of aryl−rhodium dihalide compounds with bis(imino)aryl type tridentate NCN ligands are reported.

TL;DR: The MgSO4 crystal hydrate formed below approximately 0 °C was proven to be the undecahydrate, Mg SO4·11H2O (meridianiite) instead of the reported dodecahyydrate Mg So4·12H 2O as mentioned in this paper.

TL;DR: In this article, the reaction of the phenol-based ligand 4-methyl-2,6-bis{[(2-methylpyridyl)( 2-methylthiophenyl)amino]methyl}phenol(Hpy2th2s), containing pyridine and thiophene substituents, with copper(II) chloride and bromide yields two new dinuclear complexes with the composition [Cu2(py 2th 2s)X3], where X = Cl or Br.

TL;DR: A wide-bite-angle diphosphinine ligand has been designed and synthesized, which exhibits structural features for a preferred formation of trans complexes as mentioned in this paper, due to the linear orientation of the lone pair electrons of the phosphorus donors in combination with an appropriate P−P distance, trans coordination toward a Rh center was observed and the corresponding LRh(CO)I complex could be characterized crystallographically.