Institution
Centro de Investigación y Desarrollo Tecnológico en Electroquímica
About: Centro de Investigación y Desarrollo Tecnológico en Electroquímica is a based out in . It is known for research contribution in the topics: Cyclic voltammetry & Catalysis. The organization has 537 authors who have published 682 publications receiving 10382 citations. The organization is also known as: Centro de Investigacion y Desarrollo Tecnologico en Electroquimica & Center of Research and Technologic Development in Electrochemistry.
Papers published on a yearly basis
Papers
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TL;DR: In this article, the X-ray diffraction patterns for spinous flower-like, cone, flower and coral reef-like palladium architectures were calculated through the diffraction pattern, resulting in sizes of 33, 56, 44 and 47 nm.
Abstract: Flower-like nanoparticles exhibit unique properties due to the presence of edge and corner atoms, ad-atoms, pits and other collection of defects. In this work, flower-like Pd nanoparticles were obtained by surfactantless and additiveless square wave voltammetry as an electrochemical method of synthesis. Furthermore, other well-defined Pd shapes with dendritic growth such as spinous flower-like, cone and coral reef-like shapes were obtained by electrochemical methods using cyclic voltammetry, differential pulse amperometry and second harmonic AC voltammetry. Crystal sizes were calculated through the X-ray diffraction patterns for the spinous flower-like, cone, flower and coral reef-like palladium architectures resulting in sizes of 33, 56, 44 and 47 nm, respectively. SEM and cross-section TEM images confirmed that the architectures were composed of micro and nanostructures with dendritic growths. Cyclic voltammetry in acidic medium confirmed the presence of certain facets and terraces in both, flower-like Pd and the dendritic growths. The electrocatalytic properties of the palladium architectures were evaluated to the formic acid electrooxidation at 0.1, 0.5 and 1 M. The flower-like Pd architectures exhibited the highest tolerance to CO poisoning due to the process being carried out by a direct pathway and can be related to the effect of the unique flower-like shape which due to its nature exhibits a high presence of terraces and defects.
20 citations
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TL;DR: The feasibility of use of these composite materials was evaluated in different supports to observe the development of the electrochemical responses as a function of the nature of the electrical collecting substrate as discussed by the authors.
Abstract: TiO 2 nanotube membranes (TNM) were synthesized, separated (by electrochemical anodization) and modified with Pt-Ru electrocatalyst to assess their photoelectrocatalytic activity towards methanol (MeOH) oxidation. The feasibility of use of these composite materials was evaluated in different supports to observe the development of the electrochemical responses as a function of the nature of the electrical collecting substrate. The results suggested that, while the Pt-Ru decorated TMN present photoelectrocatalytic activity, the electrical contact in the back might be the limiting step in current collection. Such findings were demonstrated by performing scanning electrochemical microscopy SECM over the surface of the TNMs, where methanol was oxidized in the microelectrode tip of the SECM. This approach corroborated the suitability of TNMs to be modified with an electrocatalyst and its application in current technology such as microfluidic fuel cells.
20 citations
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TL;DR: In this paper, the silver reduction process was studied in a new, low cyanide concentration solution in which the predominant species is the ion Ag(CN) 2 - and the pH is fixed by the presence of potassium pyrophosphate.
Abstract: The silver reduction process was studied in a new, low cyanide concentration solution in which the predominant species is the ion Ag(CN) 2 - and the pH is fixed by the presence of potassium pyrophosphate. The electrochemical reduction of silver occurs via an adsorbed electroactive species assumed to be Ag(CN) 2 - . The silver reduction appears to be a quasi-reversible process at 20°C, and its kinetic parameters are presented as well as the effect of temperature in a 10 to 60°C range ; silver reduction is fast when the temperature is high, and the activation energy was evaluated. Linear sweep voltammetry and the use of an electrochemical quartz crystal microbalance prove the existence of the adsorbed electroactive species and additional evidence was found by chronopotentiometry.
19 citations
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19 citations
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TL;DR: In this article, four phenolic compounds, either as single molecules or in mixtures, were treated by heterogeneous electro-Fenton using an undivided cell with a Ti mesh cathode, put in contact with a composite made of Fe3O4 nanoparticles (NPs) on chitosan made by chemical reduction, and a boron-doped diamond (BDD) anode.
19 citations
Authors
Showing all 537 results
Name | H-index | Papers | Citations |
---|---|---|---|
Juan-Manuel Anaya | 70 | 438 | 17483 |
Luis A. Godínez | 33 | 130 | 3867 |
Luis Gerardo Arriaga | 33 | 166 | 3704 |
Juan M. Peralta-Hernández | 30 | 83 | 3021 |
Janet Ledesma-García | 26 | 121 | 2466 |
Thomas W. Chapman | 25 | 75 | 2875 |
Gabriel Trejo | 23 | 54 | 1318 |
Yunny Meas | 23 | 75 | 1607 |
Goldie Oza | 21 | 67 | 1252 |
Minerva Guerra-Balcázar | 21 | 69 | 1390 |
Eduardo Coutino-Gonzalez | 19 | 48 | 1191 |
Erika Bustos | 17 | 93 | 1141 |
María Honrubia Pérez | 17 | 67 | 697 |
Luis Ortiz-Frade | 16 | 72 | 762 |
Noé Arjona | 15 | 68 | 777 |