Saint Mary's University

About: Saint Mary's University is a education organization based out in Halifax, Nova Scotia, Canada. It is known for research contribution in the topics: Population & Stars. The organization has 1931 authors who have published 4993 publications receiving 143226 citations.

Portable electrochemical surface-enhanced Raman spectroscopy system for routine spectroelectrochemical analysis.

Abstract: A simple, portable electrochemical surface-enhanced Raman spectroscopy (SERS) system is reported, consisting of a small benchtop Raman spectrometer, a laptop computer, and a portable USB potentiostat. Screen printed electrodes modified with silver colloidal nanoparticles are used as the SERS-active electrode, which exhibit long-term stability once prepared. Spectroelectrochemical analyses of para-aminothiophenol and melamine as model systems was conducted. In both cases, an increase in SERS signal is observed upon modulation of the applied voltage, indicating an inherent benefit of such a system wherein the surface charge can be easily tuned. Given the low cost, rapid analysis time, and good sensitivity of this system, this simple setup could be implemented for many on-site sensing applications, ranging from food and drug analysis to environmental monitoring and to chemical and biological warfare agent detection.

The Comptonization of accretion disc X-ray emission: consequences for X-ray reflection and the geometry of AGN coronae

Abstract: We consider the Comptonisation of the photons that make up the relativistically blurred reflection that is commonly detected from the accretion discs of AGN by the coronae of energetic particles believed to give rise to the powerful X-ray continua by the inverse-Compton scattering of thermal seed photons from the disc. Recent measurements of the emissivity profiles of accretion discs as well as reverberation time lags between the primary X-ray continuum and the reflection suggest that this corona is situated at a low height above the disc and extends radially, tens of gravitational radii over the disc surface, hence should also Compton scatter the reflected X-rays. We find that the detection of blurred reflection from as close in as the innermost stable circular orbits (ISCOs) of maximally rotating black holes is consistent with such coronae, but requires that the corona be patchy, consisting perhaps of a number of isolated flares throughout the region. Considering only the requirement that it be possible to detect reflection from the ISCO, we find that at any given moment, the covering fraction of the inner part of the accretion disc by the corona needs to be less than 85 per cent, though allowing for the detection of 'reflection-dominated' spectra in which the total reflected flux exceeds that seen in the continuum requires covering fractions as low as 50 or 25 per cent.

The moderating effect of normative commitment on the service quality-customer retention relationship

Abstract: Purpose – Limited attention has been given to the effects of normative commitment (NC) in a marketing relationship. This paper investigates the effects of service quality and normative commitment on customer retention in a consumer-retailer relationship. Design/methodology/approach – Two distinct studies; a longitudinal experiment and a SEM model were conducted to tease out the normative commitment-service quality interaction on customer switching intentions in services. Findings – Both studies supported the existence of a significant normative commitment-service quality interaction on switching, in addition to the main effects of both variables. Research limitations/implications – The longitudinal experiment has the limitation of being a simple test of theory in a controlled setting. Study II validates this theory in a real-world retail services setting, but there are questions about the extent to which the relationship may hold in other service sectors. The results indicate that the effect of service qu...

The Bimodality of Accretion in T Tauri Stars and Brown Dwarfs

Abstract: We present numerical solutions of the collapse of prestellar cores that lead to the formation and evolution of circumstellar disks. The disk evolution is then followed for up to three million years. A variety of models of different initial masses and rotation rates allow us to study disk accretion around brown dwarfs and low-mass T Tauri stars (TTSs), with central object mass M{sub *} < 0.2 M{sub sun}, as well as intermediate- and upper-mass TTSs (0.2 M{sub sun} < M{sub *} < 3.0 M{sub sun}). Our models include self-gravity and allow for nonaxisymmetric motions. In addition to the self-consistently generated gravitational torques, we introduce an effective turbulent alpha-viscosity with alpha = 0.01, which allows us particularly to model accretion in the low-mass regime where disk self-gravity is diminishing. A range of models with observationally motivated values of the initial ratio of rotational-to-gravitational energy yield a correlation between mass accretion rate M-dot and M{sub *} that is relatively steep, as observed. Additionally, our modeling reveals evidence for a bimodality in the M-dot - M{sub *} correlation, with a steeper slope at lower masses and a shallower slope at intermediate and upper masses, as also implied by observations. Furthermore, we show thatmore » the neglect of disk self-gravity leads to a much steeper M-dot - M{sub *} relation for intermediate- and upper-mass TTSs. This demonstrates that an accurate treatment of global self-gravity is essential to understanding observations of circumstellar disks.« less

Variable accretion in the embedded phase of stellar evolution

Abstract: Motivated by the recent detection of a large number of embedded young stellar objects (YSOs) with mass accretion rates that are inconsistent with the predictions of the standard model of inside-out collapse (Shu 1977), we perform a series on numerical hydrodynamic simulations of the gravitational collapse of molecular cloud cores with various initial masses, rotation rates, and sizes. We focus on the early Class I stage of stellar evolution when circumstellar disks are exposed to high rates of mass deposition from infalling envelopes. Our numerical modeling reproduces the large observed spread in accretion rates inferred for embedded YSOs in Perseus, Serpens, and Ophiuchus star forming regions by Enoch et al. (2009), yielding 37%--75% of objects with "sub-Shu" accretion rates \dot{M} \la 10^{-6} Msun/yr and 1%--2% of objects with "super-Shu" accretion rates \dot{M}>10^{-5} Msun/yr. Mass accretion rates in the Class I stage have a log-normal distribution, with its shape controlled by disk viscosity and disk temperature. The spread in $\dot{M}$ is greater in models with lower viscosity and smaller in models with higher viscosity and higher disk temperature, suggesting that gravitational instability may be a dominant cause of the observed diversity in $\dot{M}$ in embedded YSOs. Our modeling predicts a weak dependence between the mean mass accretion rates and stellar masses in the Class I stage, in sharp contrast to the corresponding steep dependence for evolved T Tauri stars and brown dwarfs.