Showing papers by "Technische Universität Darmstadt published in 2000"

A pattern approach to interaction design.

Abstract: To create successful interactive systems, user interface designers need to cooperate with developers and application domain experts in an interdisciplinary team. These groups, however, usually miss a common terminology to exchange ideas, opinions, and values.This paper presents an approach that uses pattern languages to capture this knowledge in software development, HCI, and the application domain. A formal, domain-independent definition of design patterns allows for computer support without sacrificing readability, and pattern use is integrated into the usability engineering life cycle.As an example, experience from building an award-winning interactive music exhibit was turned into a pattern language, which was then used to inform follow-up projects and support HCI education.

WNT signalling molecules act in axis formation in the diploblastic metazoan Hydra

Abstract: Members of the Wnt/wingless family of secreted proteins act as short-range inducers and long-range organizers during axis formation, organogenesis and tumorigenesis in many developing tissues. Wnt signalling pathways are conserved in nematodes, insects and vertebrates. Despite its developmental significance, the evolutionary origin of Wnt signalling is unclear. Here we describe the molecular characterization of members of the Wnt signalling pathway--Wnt, Dishevelled, GSK3, beta-Catenin and Tcf/Lef--in Hydra, a member of the evolutionarily old metazoan phylum Cnidaria. Wnt and Tcf are expressed in the putative Hydra head organizer, the upper part of the hypostome. Wnt, beta-Catenin and Tcf are transcriptionally upregulated when head organizers are established early in bud formation and head regeneration. Wnt and Tcf expression domains also define head organizers created by de novo pattern formation in aggregates. Our results indicate that Wnt signalling may be involved in axis formation in Hydra and support the idea that it was central in the evolution of axial differentiation in early multicellular animals.

As-rigid-as-possible shape interpolation

Abstract: We present an object-space morphing technique that blends the interiors of given two- or three-dimensional shapes rather than their boundaries. The morph is rigid in the sense that local volumes are least-distorting as they vary from their source to target configurations. Given a boundary vertex correspondence, the source and target shapes are decomposed into isomorphic simplicial complexes. For the simplicial complexes, we find a closed-form expression allocating the paths of both boundary and interior vertices from source to target locations as a function of time. Key points are the identification of the optimal simplex morphing and the appropriate definition of an error functional whose minimization defines the paths of the vertices. Each pair of corresponding simplices defines an affine transformation, which is factored into a rotation and a stretching transformation. These local transformations are naturally interpolated over time and serve as the basis for composing a global coherent least-distorting transformation.

Proton-powered turbine of a plant motor

Abstract: ATP synthases are enzymes that can work in two directions to catalyse either the synthesis or breakdown of ATP, and they constitute the smallest rotary motors in biology The flow of protons propels the rotation1 of a membrane-spanning complex of identical protein subunits, the number of which determines the efficiency of energy conversion This proton-powered turbine is predicted to consist of 12 subunits2,3,4, based on data for Escherichia coli5 The yeast mitochondrial enzyme, however, has only 10 subunits6 We have imaged the ATP synthase from leaf chloroplasts by using atomic force microscopy and, surprisingly, find that its turbine has 14 subunits, arranged in a cylindrical ring

Silazane derived ceramics and related materials

Abstract: This review highlights the synthesis, processing and properties of non-oxide silicon-based ceramic materials derived from silazanes and polysilazanes. A comprehensive summary of the preparation of precursor compounds containing Si–N–Si units, including commercially available materials, is followed by the discussion of various processing techniques. The fabrication of dense bulk ceramics in the Si/E/C/N systems is reported which involves cross-linking of the polymeric ceramic precursor followed by a polymer-to-ceramic transformation step. The cross-linked precursor can be milled, compacted and pyrolysed to form dense, additive-free, amorphous silicon carbonitride monoliths or polycrystalline composites which withstand oxidation in air at 1600°C. Furthermore, an overview is given on the fabrication of silazane derived powders and coatings involving chemical vapour deposition (CVD) methods utilising volatile precursors. Fibre spinning and fibre properties, as well as other processing techniques like infiltration of preforms, the preparation of porous ceramics and joining are briefly discussed. A state of the art of the mechanical properties of polymer derived amorphous Si/C/N and Si/B/C/N ceramics with respect to hardness as well as high-temperature creep and oxidation resistance is summarised. Finally, some important aspects of industrial applications will be considered. The review is in part based on our own work related to the polysilazane derived ceramics, but will also cover a comprehensive state of the art including the published literature in this field.

(Non)Thermal Aspects of Charmonium Production and a New Look at J/$\psi$ Suppression

Abstract: To investigate a recent proposal that J/$\psi$ production in ultra-relativistic nuclear collisions is of thermal origin we have reanalyzed the data from the NA38/50 collaboration within a thermal model including charm. Comparison of the calculated with measured yields demonstrates the non-thermal origin of hidden charm production at SPS energy. However, the ratio $\psi^{'}$/(J/$\psi)$ exhibits, in central nucleus-nucleus collisions, thermal features which lead us to a new interpretation of open charm and charmonium production at SPS energy. Implications for RHIC and LHC energy measurements will be discussed.

Supported Gold Nanoparticles from Quantum Dot to Mesoscopic Size Scale: Effect of Electronic and Structural Properties on Catalytic Hydrogenation of Conjugated Functional Groups

Abstract: Titania- and zirconia-supported gold particles of 1−5 nm size, prepared by various routes of synthesis, were employed in the partial hydrogenation of acrolein. In-depth characterization of their structural and electronic properties by electron microscopy, electron paramagnetic resonance, and optical absorption spectroscopy aimed at disclosing the nature of the active sites controlling the hydrogenation of CO vs CC bonds. The structural characteristics of the catalysts, as mean particle size, size distribution, and dispersion, distinctly depend on the synthesis applied and the oxide support used whereby the highest gold dispersion (DAu = 0.78, Au/TiO2) results from a modified sol−gel technique. For extremely small gold particles on titania and zirconia (1.1 and 1.4 nm mean size), conduction electron spin resonance of the metal and paramagnetic F-centers (trapped electrons in oxygen vacancies) of the support were observed. Besides the influence of the surface geometry on the adsorption mode of the α,β-unsat...

Evaluation of instant light-response curves of chlorophyll fluorescence parameters obtained with a portable chlorophyll fluorometer on site in the field

Abstract: Miniaturized pulse-amplitude modulated photosynthesis yield analysers are primarily designed for measuring effective quantum yield (ΔF/Fm′) of photosystem II under momentary ambient light conditions in the field. Although this provides important ecophysiological information, it is often necessary to learn more about the potential intrinsic capacities of leaves by measuring light-response curves. Thus, instruments provide light-curve programmes, where light intensities are increased in short intervals and instant light-response curves are recorded within a few minutes. This method can be criticized because photosynthesis will most likely not be in steady state. This technical report shows that with the appropriate precautions instant light curves can nevertheless provide reliable information about cardinal points of photosynthesis. First, the geometry of the light source of the instrument in relation to the quantum sensor must be considered and quantum sensor readings must be corrected. Second, the measurements of the light-response curves must be compared with readings of effective quantum yield of photosystem II under ambient light conditions where photosynthesis is in steady state. This may show that in the critical range of the light curves either both measurements perfectly coincide or are offset against each other by a constant value (examples are given here). In the first case results of light curves can be taken at face values, and in the second case a simple correction can be applied. With these precautions and careful interpretations instant light-response curves can be an enormous advantage in ecophysiological field work.

International Socialization in the New Europe: Rational Action in an Institutional Environment

Abstract: The international relations of the `new Europe' are shaped by a process of international socialization in which the Western community transmits its constitutive liberal norms to Central and Eastern Europe. This process neither fits rationalist assumptions about international politics in a technical environment nor sociological theories of action. Rather, international socialization in the new Europe is best explained as a process of rational action in a normatively institutionalized international environment. Under these conditions, rational state behaviour is constrained by value-based norms of legitimate statehood and proper conduct. Selfish political actors conform to these norms in order to reap the benefits of international legitimacy, but as instrumental actors they also calculate whether these benefits are worth the costs of conformity and how they can be reaped efficiently. An empirical analysis of the behaviour of the Western socialization agencies and the CEE countries supports this perspective ...

The soil food web of two beech forests (Fagus sylvatica) of contrasting humus type: stable isotope analysis of a macro- and a mesofauna-dominated community.

Abstract: The structure of the soil food web in two beech (Fagus sylvatica) forests, the Gottinger Wald and the Solling forest (Northern Germany), was investigated using variations in tissue 15N concentrations of animal species or taxa. The Gottinger Wald is located on a limestone plateau and characterized by mull humus with high macrofauna activity, particularly of Lumbricidae, Diplopoda and Isopoda. In contrast, the Solling forest is located on a sandstone mountain range and characterized by moder humus. The soil fauna of this forest is dominated by mesofauna, particularly by Collembola, Enchytraeidae and Oribatida. In June 1995 soil fauna was sampled using heat extraction. Three soil layers were analysed at each of the sites. 15N/14N ratios of bulk material increased strongly with soil depth in both forests. This also applied to the water-soluble fraction at the Gottinger Wald, but not at the Solling. Generally, the water-soluble fraction was more enriched in 15N than the bulk materials. For most animals studied 15N/14N ratios varied little with soil depth. In both forests soil animals could be classified either as saprophages, including microphytophages, or predators. On average, the δ15N of predatory taxa (Chilopoda, Araneida, Gamasina, Staphylinidae) exceeded that of saprophagous or microphytophagous taxa (Lumbricidae, Isopoda, Diplopoda, Collembola, Oribatida, Enchytraeidae) by 4.4 and 3.9‰ for the Gottinger Wald and the Solling, respectively. We assume that most of the saprophagous or microphytophagous taxa studied consist of primary and secondary decomposers and hypothesize that predators prey more on secondary than primary decomposers. Generally, average δ15N values differed little between saprophagous (Lumbricidae, Diplopoda, Isopoda) and microphytophagous taxa (Collembola, Oribatida). The variations in δ15N values of species within these taxa consistently exceeded the variation between them, indicating that the species of each of these taxa form a continuum from primary to secondary decomposers. Also, variations in δ15N values within predatory taxa in most cases exceeded that between taxa excluding top predators like Sorex. We conclude that using higher taxonomic units in soil food web analysis is problematic and in general not consistent with nature. Higher taxonomic units may only be useful for depicting very general trophic groupings such as predators or microbi-detritivores.

Representing animations by principal components

Abstract: In this paper, we present a representation for three-dimensional geometric animation sequences. Different from standard key-frame techniques, this approach is based on the determination of principal animation components and decouples the animation from the underlying geometry. The new representation supports progressive animation compression with spatial, as well as temporal, level-of-detail and high compression ratios. The distinction of animation and geometry allows for mapping animations onto other objects.

Mining Minimal Non-redundant Association Rules Using Frequent Closed Itemsets

Abstract: The problem of the relevance and the usefulness of extracted association rules is of primary importance because, in the majority of cases, real-life databases lead to several thousands association rules with high confidence and among which are many redundancies. Using the closure of the Galois connection, we define two new bases for association rules which union is a generating set for all valid association rules with support and confidence. These bases are characterized using frequent closed itemsets and their generators; they consist of the nonredundant exact and approximate association rules having minimal antecedents and maximal consequents, i.e. the most relevant association rules. Algorithms for extracting these bases are presented and results of experiments carried out on real-life databases show that the proposed bases are useful, and that their generation is not time consuming.

Polymer Network–Stabilized Liquid Crystals

Abstract: The fabrication and properties of polymer network–stabilized liquid crystals, formed by polymerization of a small amount of a bifunctional photoreactive monomer dissolved in a liquid-crystalline phase, are reviewed. The polymer network morphology is strongly related to preparation conditions such as monomer content, polymerization temperature, and ultraviolet (UV) curing conditions. The transfer of anisotropic liquid-crystalline order onto the network is discussed in detail. The electro-optical performance of network-stabilized nematics, cholesterics, and ferroelectric smectics is largely dependent on the morphology of the network, as will be demonstrated with an emphasis laid on polymer-stabilized cholesteric textures (PSCTs). A general correlation between polymerization conditions, network morphology, and electro-optical behavior will be outlined and aspects concerning applications discussed.

A triplet of differently shaped spin-zero states in the atomic nucleus 186Pb

Abstract: Understanding the fundamental excitations of many-fermion systems is of significant current interest. In atomic nuclei with even numbers of neutrons and protons, the low-lying excitation spectrum is generally formed by nucleon pair breaking and nuclear vibrations or rotations. However, for certain numbers of protons and neutrons, a subtle rearrangement of only a few nucleons among the orbitals at the Fermi surface can result in a different elementary mode: a macroscopic shape change. The first experimental evidence for this phenomenon came from the observation of shape coexistence in 16O (ref. 4). Other unexpected examples came with the discovery of fission isomers and super-deformed nuclei. Here we find experimentally that the lowest three states in the energy spectrum of the neutron deficient nucleus 186Pb are spherical, oblate and prolate. The states are populated by the alpha-decay of a parent nucleus; to identify them, we combine knowledge of the particular features of this decay with sensitive measurement techniques (a highly efficient velocity filters with strong background reduction, and an extremely selective recoil-alpha-electron coincidence tagging methods). The existence of this apparently unique shape triplet is permitted only by the specific conditions that are met around this particular nucleus.

The structure of oribatid mite communities (Acari, Oribatida): patterns, mechanisms and implications for future research

Abstract: FORUM is a lighter channel of communication between readers and contributors; it aims to stimulate discussion and debate, particularly by presenting new ideas and by suggesting alternative interpretations to the more formal research papers published in ECOGRAPHY and elsewhere A lighter prose is encouraged and no summary is required Contributions should be concise and to the point, with a relatively short bibliography Formal research papers, however short, will not be considered

Hydrolysis of esters in subcritical and supercritical water

Abstract: The task of this work was to gain a better understanding of the hydrolysis of esters in sub- and supercritical water (SCW). Therefore, the kinetics of the hydrolysis of ethyl acetate as a model reaction was studied in the pressure and temperature range of 23–30 MPa and 250–400°C, respectively. The corresponding reaction mechanisms in sub- and supercritical water were discussed.

Rare-Earth-Containing Magnetic Liquid Crystals

Abstract: Rare-earth-containing metallomesogens with 4-alkoxy-N-alkyl-2-hydroxybenzaldimine ligands are reported. The stoichiometry of the complexes is [Ln(LH)(3)(NO3)(3)], where Ln is the trivalent rare-earth ion;(Y, La, and Pr to Lu, except Pm) and LH is the Schiff base. The Schiff base ligands are in the zwitterionic form and coordinate through the phenolic oxygen only. The three nitrate groups coordinate in a bidentate fashion. The X-ray single-crystal structures of the nonmesogenic homologous complexes [Ln(LH)(3)(NO3)(3)]where Ln = Nd(III), Tb(III), and Dy(III) and LH = CH3OC6H3(2-OH)CH=NC4H9, are described. Although the Schiff base Ligands do not exhibit a mesophase, the metal complexes do (SmA phase). The mesogenic rare-earth complexes were studied by NMR, IR, EPR, magnetic susceptibility measurements, X-ray diffraction,and molecular modeling. The metal complexes in the mesophase have a very large magnetic anisotropy, so that these magnetic liquid crystals can easily be aligned by an external magnetic field.

Ant Colony Optimization for the Total Weighted Tardiness Problem

Abstract: In this article we present an application of the Ant Colony Optimization (ACO) metaheuristic to the single machine total weighted tardiness problem. First, we briefly discuss the constructive phase of ACO in which a colony of artificial ants generates a set of feasible solutions. Then, we introduce some simple but very effective local search. Last, we combine the constructive phase with local search obtaining a novel ACO algorithm that uses a heterogeneous colony of ants and is highly effective in finding the best-known solutions on all instances of a widely used set of benchmark problems.

Application of model-based fault detection to a brushless DC motor

Abstract: In comparison to classical DC motors, brushless DC motors are very reliable, Nevertheless, they can also fail, caused by, e.g., overheating or mechanical wear. This paper proposes a parameter estimation technique for fault detection on this type of motor. Simply by measuring the motor's input and output signals, its parameters can be estimated. This method is based on a mathematical model of the process. In the presented work, a square-wave motor is considered. An appropriate model is derived. To be able to implement the method also on low-cost microcontroller-based control units, only the power inverter supply voltage, DC current, and the motor's angular velocity have to be measured. The parameter estimation technique provides information about the electrical resistance and the back-EMF constant as well as about the mechanical parameters. Comparing the nominal with the computed parameters, faults can be detected. The approach might be applied to both end-of-line and online fault detection. Results for simulated data demonstrate the capabilities of the proposed procedure. Finally, a real-world application-an actuation system with a brushless DC motor mounted to a gearbox-is given.

Results from the EISMINT model intercomparison : the effects of thermomechanical coupling

Abstract: This paper discusses results from the second phase of the European Ice sheet Modelling Initiative (EISMINT). It reports the intercompartison of ten operational ice-sheet models and uses a series of experiments to examine the implications of thermomechanical coupling for model behaviour. A schematic, circular ice sheet is used in the work which investigates both steady states and the response to stepped changes in climate. The major finding is that radial symmetry implied in the experimental design can, under certain circumstances, break down with the formation of distinct, regularly spaced spokes of cold ice which extended from the interior of the ice sheet outward to the surrounding zone of basal melt. These features also manifest themselves in the thickness and velocity distributions predicted by the models. They appear to be a common feature to all of the models which took part in the intercomparison, and may stem from interactions between ice temperature, flow and surface form. The exact nature of these features varies between models, and their existence appears to be controlled by the overall thermal regimne of the ice sheet. A second result is that there is considerable agreement between the models in their predictions of global-scale response to imposed climate change.

Piezoelectricity in cellular electret films

Abstract: Permanently charged films with a cellular or porous structure represent a new family of polymer electrets. These materials show piezoelectric properties with high piezoelectric constants. The electromechanical response equations of such films are derived for their operation as sensors and as actuators. Experimental results are also presented for cellular polypropylene (pp). In particular, measurements of the direct and inverse piezoelectric constants in the frequency range 0 to 10 kHz and of the variation of these constants across the surface of the films are discussed. These measurements, performed by direct application of stress or by the use of a profilometer, an accelerometer and an interferometer yield a frequency-independent piezoelectric d/sub 33/ constant of /spl lsim/ 220 pC/N. Assuming reasonable charge distributions and charge densities, the calculated piezoelectric constants are in good agreement with the measured values. The theoretical model shows the reciprocity of the piezoelectric constants.

New developments of computer-aided crystallographic analysis in transmission electron microscopy

Abstract: A new computer program for on-line crystallographic analysis in transmission electron microscopy (TEM) is presented. The program is based on the fast on-line determination of single-crystal orientations from Kikuchi and spot patterns. Spot patterns, which are particularly useful in the case of highly deformed metals, are analyzed by a new digital image processing procedure. This procedure improves the precision and ease of the orientation measurement. The program permits the on-line measurement of glide systems characterized by the Burgers vector and the crystallographic line direction of dislocations and their glide planes. The determination of twin systems, based on the misorientation calculation for any crystal structure, is included as well. The possibility of determining the foil thickness permits the complete crystallographic characterization of interfaces. Finally, the program facilitates the discrimination of phases and includes the fit of the lattice parameters a, b and c from diffraction patterns. The new procedures are described in detail. Application examples are given for all functions.