University of Akron

About: University of Akron is a education organization based out in Akron, Ohio, United States. It is known for research contribution in the topics: Polymer & Polymerization. The organization has 17401 authors who have published 29127 publications receiving 702386 citations. The organization is also known as: The University of Akron.

Economic freedom versus political freedom: cross‐country influences on corruption*

Abstract: Using a well-known index of corruption, this paper examines the determinants of corruption for a large sample of countries. Specifically, the present study brings empirical evidence to bear on the question of whether economic freedom or political freedom serves as a deterrent to corrupt activity. In particular, does greater economic freedom or greater political freedom yield a more ‘clean’ society? Our results show that greater economic freedom seems to matter more in this regard. Examining different components of economic freedom, we find that not all these components are equally effective in reducing corruption. For instance, monetary policy seems to have a stronger influence on the level of corrupt activity in a country than fiscal policy. Robustness of these findings is checked and policy implications are discussed.

Effect of Plasticization on Ionic Conductivity Enhancement in Relation to Glass Transition Temperature of Crosslinked Polymer Electrolyte Membranes

Abstract: The relationship between glass transition (Tg) and ionic conductivity (σ) of an amorphous crosslinked polymer electrolyte membrane (PEM) was examined based on ion–dipole complexation between dissociated lithium cations and ether oxygen of poly(ethylene glycol diacrylate) and plasticization by succinonitrile (SCN). In a binary PEM consisting of a lithium salt/polymer network, Tg increased due to a strong ion–dipole interaction, whereas σ declined due to lower ion mobility coupled to reduced chain mobility. Above the threshold salt concentration of 7 mol %, dual loss tangent peaks were observed in dynamic mechanical studies, which may be ascribed to segmental relaxations of ion–dipole complexed networks and that of polymer chains surrounding the undissociated lithium salt acting like “fillers”. Upon SCN plasticization, these two peaks merged into one that was further suppressed below Tg of the pure network, whereas σ improved to the superionic conductor level. The role of plasticization on the ionic conduct...