Showing papers in "Inorganic Chemistry Communications in 2006"

TL;DR: In this article, a novel fluorescent sensor was prepared and used as an ion-selective chemosensor for Al(III) via intramolecular excimer formation, from which a significant red shift along with an intensity enhancement of the excimer emission was observed in the presence of Al (III)

TL;DR: In this paper, a new copper(II) complexes of 14-membered hexaaza macrocyclic ligands have been prepared by the in situ one-pot template synthesis (IOPTS) of formaldehyde and 1,2-phenylenediamine with alkyl or benzyl amine.

TL;DR: A linear trinuclear mixed valence complex (CoII{(μ-L)(μ-OAc)CoIII(NCS)}2] has been prepared and its molecular structure has been elucidated on the basis of X-ray crystallography.

TL;DR: The ability to decorate a silica surface with specific ligand fields and/or metal complexes creates powerful new capabilities for catalysis, chemical separations and sensor development as mentioned in this paper.

TL;DR: In this article, two non-interpenetrated supramolecular networks, [Ag(Mtta)]n (1) and [Ag[Ag(Etta]n (2), were constructed by cycloaddition of nitriles and azides in methanol.

TL;DR: The synthesis of an unsymmetrical phthalocyanine, 2-carboxyphthalOCyanine zinc 1 , with a single carboxylic group on phthalcyanine ring, and the design of its chromatographic purification is reported.

TL;DR: In this article, a novel 3D coordination polymer, Cd2(pydc)2(H2O), was synthesized and characterized by the elemental analyses, IR spectrum and single crystal X-ray diffraction.

TL;DR: In this article, MeCN-based solvent mixtures yield complexes with similar triangles of CuII ions, centered by a triply bridging hydroxo ligand and with three edge-bridging oximate groups from the three 2.1110 (py)2CNO− ions.

TL;DR: Two uranyl-containing organic coordination polymers, (UO2)2(μ2-OH)(pdc)2 Zn(bpy)(Ac) 2(H2O)9 (1) (H2pdc=pyridine-2,6-dicarboxylic acid, bpy=4,4′-bipyridine, HAc=acetic acid) and UO2(pdc)(H 2O) (2) have been prepared through a hydrothermal route and characterized by single-

TL;DR: In this paper, two morpholine-containing silicon (IV) phthalocyanines, namely bis (2-morpholine) ethoxy phthylocyaninatosilicon (2 ) and bis(2-( N -methylmorpholine)) diiodide (3 ), have been prepared.

TL;DR: A dinuclear Schiff base zinc(II) complex was synthesized, characterized and evaluated for the first time for its effect on the xanthine oxidase (XO).

TL;DR: An ionic liquid, 1-butyl-3-methylimidazolium bromide, is used as reaction medium for the synthesis and crystallization of a coordination polymer, (BMIM)2[Cd3(BDC)3Br 2] (1) ( BMIM = ǫ-1,butyl 3methyloridazolate, BDC = 1,4-benzenedicarboxylate), which forms an anionic two-dimensional framework with the imidazilium cations located between the layers

TL;DR: This mini-review highlights some recent progresses in developing bifunctional complexes through derivatization strategies ranging from the design of dimeric complexes and chromophore-quencher systems to the development of biotin–metal complex conjugates for avidin-mediated detection of biomolecules.

TL;DR: Two cis-related palladium(II) complexes [PdCl2(PPh3)(tu)] (1) and [pdCl 2(tmen)] (2) have been synthesized and characterized by elemental analysis, IR and NMR spectroscopies, and single crystal X-ray diffraction as mentioned in this paper.

TL;DR: In this article, a structurally important self-assembly of dinuclear and trinuclear zinc-benzoate complexes having formula [Zn 3 (μ-OBz) 6 (py) 2 ], where OBz is benzoate and py is pyridine ligand, is reported.

TL;DR: The results of surface photovoltage spectrum (SPS) for three Ni(II) coordination supramolecular polymer complexes (Ni(pdc)(H2O)3]n(1), {Ni(Imh)4(H 2O)2] [Ni(btec)(H 2 O)2 (Imh 2]2]· H2O}n(2), [Ni (opha)(phen)(H 3]3]µ)µ n(1,2,4,5-benzenetet

TL;DR: In this paper, the coordination ability of Al(III) towards 2-(4,5-dihydro-1,3-oxazol-2-yl)phenol (1) and 2-(5,5dihdroid-1.3-imidazol)-2.yl (2) was studied added to the determination of the stoichiometry of the adducts formed in solution and the fluorogenic sensor character of the two studied molecules was then quantified.

TL;DR: In this paper, a TlI coordination polymer of 4-hydroxyphenyl)sulfonyl]-1-benzenol (H2SB) ligand was analyzed.

TL;DR: An unprecedented organic-inorganic hybrid compound [Cu5Cl(4,4′-bipy)5] [SiW12O40]· 1.5H2O (1) was synthesized and characterized by elemental analyses, IR, TG analyses, cyclic voltammetry and single-crystal X-ray diffraction as mentioned in this paper.

TL;DR: Two structurally divergent zinc complexes [Zn·H2L1·Cl2] and ZnN3O2Cl2 ] of the newly designed pentadentate Schiff bases H 2L1 and H2L2 have been synthesized and characterized as mentioned in this paper.

TL;DR: Bimetallic salicylaldimine-nickel complexes, 2,4,6-Me3-1,3-{[N CH-(3′-R-5′-Y-2′-O-C6H3)-κ2-N,O]Ni(Ph) (PPh3)}2 [R=tert-Bu, Y=me, 1b; R=Ph, Y-=Me, 2b] were prepared and their catalytic behaviors of ethylene polymerization were investigated.

TL;DR: In this article, the AgCl elimination reaction in CHCl3 between [AuCl(PPh3)] and the Ag-O bonding precursors such as [Ag2(R-Hpyrrld)(S-Pyrrrd)] and [Ag 2(Rothf)(Sothf)].

TL;DR: A dinuclear copper salicylate [Cu2(HSal)(Sal)(2,2′-bpy)2](ClO4) (1) (H2Sal= salicylic acid) has been synthesized and characterized with the aid of elemental analysis and infrared, ultraviolet and fluorescence spectroscopic studies as discussed by the authors.

TL;DR: In this article, the copper(II) precursor complex, [Cu(1,2-phen)2]2+-NaY, was created by template condensation with formaldehyde and amine.

TL;DR: The mono anionic bidentate Schiff base ligands of N, O bonding system have been employed to synthesize a series of new stable ruthenium(III) complexes of general composition [RuX(EPh3)(L)2] as discussed by the authors.

TL;DR: In this paper, a biomimetic model of the active site of Fe-only hydrogenase [{(μ-SCH2)2N(2-C4H3O)}Fe2(CO)6] (6) was synthesized and characterized by IR, 1H, 13C NMR spectroscopy.

TL;DR: In this article, a hexaamminecobalt(III) complex salt was characterized by elemental analyses, solubility measurement and spectroscopic techniques (e.g. UV/Visible, IR and 13C NMR) and a single crystal X-ray structure determination revealed the presence of discrete [Co(NH3)6]3+ cation and a new anion, [Hg2(SCN)7]3−.

TL;DR: Chiral penta- and hexacoordinate silicon complexes are accessible with O,N,O-ligands, which contain exclusively one stereoisomer prepared from amino acids of the chiral pool as discussed by the authors.

TL;DR: In this article, three kinds of new nickel(II) complexes of α-isoxazolylazo-β-diketones with blue-violet light absorption were synthesized.

TL;DR: In this paper, a polymer-supported Zn catalysts for transesterification were successfully prepared by deliberately choosing the polymer surface anchored AMP (2-aminomethylpyridine) as a ligand.