Journal ArticleDOI
A Microporous Metal-Organic Framework Supramolecularly Assembled from a Cu II Dodecaborate Cluster Complex for Selective Gas Separation
TLDR
The good cyclability and high water/thermal stability render it suitable for real industrial applications, and the practical separation performance of C3 H8 /CH4 and C2 H6 / CH4 was confirmed by dynamic breakthrough experiments.Abstract:
A novel 3D metal-organic framework BSF-1 based on the closo-dodecaborate cluster [B12 H12 ]2- was readily prepared at room temperature by supramolecular assembly of CuB12 H12 and 1,2-bis(4-pyridyl)acetylene. The permanent microporous structure was studied by X-ray crystallography, powder X-ray diffraction, IR spectroscopy, thermogravimetric analysis, and gas sorption. The experimental and theoretical study of the gas sorption behavior of BSF-1 for N2 , C2 H2 , C2 H4 , CO2 , C3 H8 , C2 H6 , and CH4 indicated excellent separation selectivities for C3 H8 /CH4 , C2 H6 /CH4 , and C2 H2 /CH4 as well as moderately high separation selectivities for C2 H2 /C2 H4 , C2 H2 /CO2 , and CO2 /CH4 . Moreover, the practical separation performance of C3 H8 /CH4 and C2 H6 /CH4 was confirmed by dynamic breakthrough experiments. The good cyclability and high water/thermal stability render it suitable for real industrial applications.read more
Citations
More filters
Journal ArticleDOI
Microporous Metal-Organic Framework Materials for Gas Separation
TL;DR: In this paper, the uniqueness and basic design principles of metal-organic frameworks (MOFs) for gas separation in terms of their specific pore chemistry and molecular recognition are discussed.
Journal ArticleDOI
Integrating the Pillared-Layer Strategy and Pore-Space Partition Method to Construct Multicomponent MOFs for C2H2/CO2 Separation.
Lizhen Liu,Zizhu Yao,Yingxiang Ye,Yike Yang,Quanjie Lin,Zhangjing Zhang,Michael O'Keeffe,Shengchang Xiang +7 more
TL;DR: A serial of porous mm-MOFs constructed from pillared-layer and pore-space partition (PL-PSP) have been achieved and a new (3,9,12)-connected llz topology is shown.
Journal ArticleDOI
Benchmark C 2 H 2 /CO 2 Separation in an Ultra‐Microporous Metal–Organic Framework via Copper(I)‐Alkynyl Chemistry
Ling Zhang,Ke Jiang,Lifeng Yang,Libo Li,Enlai Hu,Ling Yang,Kai Shao,Huabin Xing,Yuanjing Cui,Yu Yang,Bin Li,Banglin Chen,Guodong Qian +12 more
TL;DR: In this article, the authors used copper(I)-alkynyl chemistry within an ultra-microporous MOF (CuI @UiO-66-(COOH)2 ) to achieve ultrahigh C2 H2 /CO2 separation selectivity.
Journal ArticleDOI
Rational Design of Microporous MOFs with Anionic Boron Cluster Functionality and Cooperative Dihydrogen Binding Sites for Highly Selective Capture of Acetylene
Yuanbin Zhang,Jianbo Hu,Rajamani Krishna,Lingyao Wang,Lifeng Yang,Xili Cui,Simon Duttwyler,Huabin Xing +7 more
TL;DR: Two novel dodecaborate-hybrid metal organic frameworks, MB 12 H 12 (dpb) 2 and BSF-3-Co, are reported for highly selective capture of C 2 H 2 .
Journal ArticleDOI
A hydrostable cage-based MOF with open metal sites and Lewis basic sites immobilized in the pore surface for efficient separation and purification of natural gas and C2H2.
TL;DR: Stability studies showed that the cage-based MOF assembled from a tetranuclear Cu4O-based SBU and an amine-functionalized N,O-mixed donor ligand maintained its structural integrity after being immersed in HCl/NaOH aqueous solutions within a pH range of 4-11 at ambient temperature for 24 h, indicating its good hydrolytic stability under harsh chemical conditions, which might lay a solid foundation for its practical applications.
References
More filters
Journal ArticleDOI
Design and synthesis of an exceptionally stable and highly porous metal-organic framework
TL;DR: In this article, an organic dicarboxylate linker is used in a reaction that gives supertetrahedron clusters when capped with monocarboxyates.
Journal ArticleDOI
Metal–Organic Frameworks and Self-Assembled Supramolecular Coordination Complexes: Comparing and Contrasting the Design, Synthesis, and Functionality of Metal–Organic Materials
Journal ArticleDOI
Seven chemical separations to change the world
David S. Sholl,Ryan P. Lively +1 more
TL;DR: This list is not exhaustive; almost all commercial chemicals arise from a separation process that could be improved, and here, seven chemical separation processes that, if improved, would reap great global benefits.
Journal ArticleDOI
Hydrocarbon Separations in a Metal-Organic Framework with Open Iron(II) Coordination Sites
Eric D. Bloch,Wendy L. Queen,Wendy L. Queen,Rajamani Krishna,Joseph M. Zadrozny,Craig M. Brown,Craig M. Brown,Jeffrey R. Long,Jeffrey R. Long +8 more
TL;DR: In this paper, the metal-organic framework Fe2(dobdc) was demonstrated to exhibit excellent performance characteristics for separation of ethylene/ethane and propylene/propane mixtures at 318 kelvin.
Journal ArticleDOI
Recent advances in gas storage and separation using metal–organic frameworks
TL;DR: In this article, the authors highlight the recent advances in gas storage and separation using metal-organic frameworks (MOFs) and summarize the gas uptakes of some benchmark MOFs, emphasizing on the desired chemical properties of MOFs for different gas storage/separation scenarios.