Book ChapterDOI
Chapter 3 - The Oxide Chemistry of Molybdenum
A.M. Chippindale,A.K. Cheetham +1 more
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This article is published in Studies in Inorganic Chemistry.The article was published on 1994-01-01. It has received 19 citations till now. The article focuses on the topics: Molybdenum & Oxide.read more
Citations
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POLYMERIC GASEOUS SPECIES IN THE SUBLIMATION OF MOLYBDENUM TRIOXIDE. Period covered: To June 30, 1956. Technical Report No. 2 on THERMODYNAMICS OF REFRACTORY MATERIALS AS DETERMINED WITH A MASS SPECTROMETER
TL;DR: In this article, a mass spectometric analysis of the vapor in thermodynamic equilibrium with powdered molybdenum trioxide, as sampled from a Knudsen effusion cell, has shown that the vapor phase consists of Mo3O9, Mo4O12 and Mo5O15 molecules.
Journal ArticleDOI
Influence of 2-Aminopyridine on the Formation of Molybdates under Hydrothermal Conditions
K. Pavani,Arunachalam Ramanan +1 more
TL;DR: In this article, the role of 2-aminopyridine (2ampy) in the formation of the different solids under hydrothermal conditions is discussed, and the structures of these materials were established by single-crystal and powder X-ray diffraction techniques.
Journal ArticleDOI
Chemical etching of molybdenum trioxide : a new tailor-made synthesis of moo3 catalysts
TL;DR: In this article, a chemical etching method has been developed for restructuring these thermally processed catalysts using a 0.1 M NaOH etchant, where the surface steps, ledges, and terraces are created.
Journal ArticleDOI
Tuning the interlayer of transition metal oxides for electrochemical energy storage
TL;DR: In this article, a review of the benefits and methods for interlayer modification of layered transition metal oxides, which include the presence of structural water, solvent cointercalation and exchange, cation exchange, polymers, and small molecules, exfoliation, and exfoliated heterostructures, is presented.
Journal ArticleDOI
A chemists view: Metal oxides with adaptive structures for thermoelectric applications
Gregor Kieslich,Giacomo Cerretti,Igor Veremchuk,Raphaël P. Hermann,Martin Panthöfer,Juri Grin,Wolfgang Tremel +6 more
TL;DR: In this article, the structural aspects of the crystallographic shear planes and the resulting thermoelectric properties of transition metal oxides with adaptive structures have been investigated with respect to their thermal properties.
References
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Journal ArticleDOI
Preparation of bronzes by an alkali azide-metal oxide reaction
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Crystal structure of the red cesium molybdenum bronze, Cs0.33MoO3
TL;DR: The crystal structure of Cs0.33MoO3 has been determined from single-crystal X-ray diffraction data as discussed by the authors, and the crystal is isostructural with those of the red molybdenum bronzes K 0.33 MoO3 and Tl 0.25 MoOO3.
Journal ArticleDOI
Crystal structure of Li0.33MoO3, a stoichiometric, triclinic, lithium molybdenum bronze
TL;DR: Li/sub 0.33/MoO/sub 3/ crystallizes in space group P1 with a = 13.079, b = 15.453, c = 7.476, and Z = 24.
Journal ArticleDOI
Structures with Oligomeric Condensed Clusters in Indium Oxomolybdates
Journal ArticleDOI
Hydrothermal synthesis and structure of Cu1+6Mo6+5O18
TL;DR: In this article, the Bridgman technique was used to grow single crystals of Cu 1+ 6 Mo 6+ 5 O 18 from stoichiometric mixtures of the binary oxides, and the structure was solved by the Patterson method and refined to R = 0.027 using 1164 independent reflections.