Book ChapterDOI
Chapter 3 - The Oxide Chemistry of Molybdenum
A.M. Chippindale,A.K. Cheetham +1 more
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This article is published in Studies in Inorganic Chemistry.The article was published on 1994-01-01. It has received 19 citations till now. The article focuses on the topics: Molybdenum & Oxide.read more
Citations
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POLYMERIC GASEOUS SPECIES IN THE SUBLIMATION OF MOLYBDENUM TRIOXIDE. Period covered: To June 30, 1956. Technical Report No. 2 on THERMODYNAMICS OF REFRACTORY MATERIALS AS DETERMINED WITH A MASS SPECTROMETER
TL;DR: In this article, a mass spectometric analysis of the vapor in thermodynamic equilibrium with powdered molybdenum trioxide, as sampled from a Knudsen effusion cell, has shown that the vapor phase consists of Mo3O9, Mo4O12 and Mo5O15 molecules.
Journal ArticleDOI
Influence of 2-Aminopyridine on the Formation of Molybdates under Hydrothermal Conditions
K. Pavani,Arunachalam Ramanan +1 more
TL;DR: In this article, the role of 2-aminopyridine (2ampy) in the formation of the different solids under hydrothermal conditions is discussed, and the structures of these materials were established by single-crystal and powder X-ray diffraction techniques.
Journal ArticleDOI
Chemical etching of molybdenum trioxide : a new tailor-made synthesis of moo3 catalysts
TL;DR: In this article, a chemical etching method has been developed for restructuring these thermally processed catalysts using a 0.1 M NaOH etchant, where the surface steps, ledges, and terraces are created.
Journal ArticleDOI
Tuning the interlayer of transition metal oxides for electrochemical energy storage
TL;DR: In this article, a review of the benefits and methods for interlayer modification of layered transition metal oxides, which include the presence of structural water, solvent cointercalation and exchange, cation exchange, polymers, and small molecules, exfoliation, and exfoliated heterostructures, is presented.
Journal ArticleDOI
A chemists view: Metal oxides with adaptive structures for thermoelectric applications
Gregor Kieslich,Giacomo Cerretti,Igor Veremchuk,Raphaël P. Hermann,Martin Panthöfer,Juri Grin,Wolfgang Tremel +6 more
TL;DR: In this article, the structural aspects of the crystallographic shear planes and the resulting thermoelectric properties of transition metal oxides with adaptive structures have been investigated with respect to their thermal properties.
References
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Journal ArticleDOI
Synthesis, structure and properties of Mn1.5Mo8O11, a unique structure type among compounds having infinite chains of Trans-Edge-Shared Octahedral Cluster Units
TL;DR: The compound Mn1.5Mo8O11 is prepared in single phase form by reaction of intimate mixtures of MnMoO4, MoO3 and molybdenum powders in the mole ratio 9:10:29 as discussed by the authors.
Journal ArticleDOI
Low-temperature synthesis of novel layered alkali metal-MoO3 bronzes and hexagonal bronzes of the type KyW1−xMoxO3
TL;DR: In this article, a new class of layered alkali metal-MoO/sub 3/ bronzes, A/sub x/MoO-sub 3 / (A = Li, Na, K, Rb), with nearly the same unit cell parameters as the host oxide has been synthesized by the solid-state reaction of MoO/Sub 3/ with alkali metals iodides around 575 K.
Journal ArticleDOI
A Lithium-Scandium-Molybdenum (IV) Oxide
Paul C. Donohue,Lewis Katz +1 more
TL;DR: The structure of compounds A2IIMo3IVO8, where AII may be Mg, Mn, Fe, Co, Ni, Zn, and Cd, has been reported.
Journal ArticleDOI
The crystal structure of D1.7MoO3 by powder neutron diffraction
TL;DR: The crystal structure of D 1.7 MoO 3 has been determined by powder neutron diffraction as mentioned in this paper, and the structure was refined using the Rietveld method of powder profile analysis in the space group C 2/m.
Journal ArticleDOI
The crystal structure of La3Mo4.33Al0.67O14 and the electronic structure of La3Mo4XO14 (X = Si; Mo13Al23; Al12V12)
TL;DR: In this paper, the authors proposed the La/sub 3/Mo/sub 4.33/Al/sub 0.67/O/sub 14/ was prepared by electrolytic reduction at 1100/sup 0/C of an alumina crucible.