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Comment on "Epitaxial BiFeO3 multiferroic thin film heterostructures".

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TLDR
It is argued that epitaxial strain does not enhance the magnetization and polarization in BiFeO3 and suggests the potential for novel devices that exploit the anticipated strain-mediated magnetoelectric coupling between the two ordered ground states.
Abstract
Wang et al recently reported multiferroic behavior, with ferromagnetic and ferroelectric polarizations that are both large at room temperature, in thin strained films of BiFeO3 (BFO). Although at room temperature, bulk BFO is ferroelectric and anti-ferromagnetic , Wang et al. reported that a 70-nm film shows both an enhanced ferroelectric polarization (90 μC cm–2) and a substantial magnetization (1 μB/Fe). This remains the only report of a robust room-temperature multiferroic and suggests the potential for novel devices that exploit the anticipated strain-mediated magnetoelectric coupling between the two ordered ground states. In this Comment, we argue that epitaxial strain does not enhance the magnetization and polarization in BiFeO3

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Citations
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Size-Dependent Magnetic Properties of Single-Crystalline Multiferroic BiFeO3 Nanoparticles

TL;DR: As-prepared, single-crystalline bismuth ferrite nanoparticles show strong size-dependent magnetic properties that correlate with increased suppression of the known spiral spin structure with decreasing nanoparticle size and uncompensated spins and strain anisotropies at the surface.
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Visible-Light Photocatalytic Properties of Weak Magnetic BiFeO3 Nanoparticles

TL;DR: Polycrystalline BiFeO3 nanoparticles (size 80-120 nm) are prepared by a simple sol-gel technique as discussed by the authors, which are very efficient for photocatalytic decomposition of organic contaminants under irradiation from ultraviolet to visible frequencies.
References
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Journal ArticleDOI

Epitaxial BiFeO3 multiferroic thin film heterostructures.

TL;DR: Enhanced polarization and related properties in heteroepitaxially constrained thin films of the ferroelectromagnet, BiFeO3, and combined functional responses in thin film form present an opportunity to create and implement thin film devices that actively couple the magnetic and ferroelectric order parameters.
Journal ArticleDOI

Spiral magnetic ordering in bismuth ferrite

TL;DR: In this article, the magnetic ordering of the iron ions in bismuth ferrite BiFeO3 was obtained by a study with a high-resolution time-of-flight neutron diffractometer.
Journal ArticleDOI

Weak ferromagnetism and magnetoelectric coupling in bismuth ferrite

TL;DR: In this paper, the coupling between the ferroelectric and magnetic order parameters in the magnetoelectric multiferroic was analyzed using density functional theory within the local spin density approximation (LSDA) and the $\mathrm{LSDA}+\mathm{U}$ method.
Journal ArticleDOI

First-principles study of spontaneous polarization in multiferroic Bi Fe O 3

TL;DR: In this paper, the ground-state structural and electronic properties of ferroelectric are calculated using density functional theory within the local spin-density approximation (LSDA) and the $\mathrm{LSDA}+U$ method.
Journal ArticleDOI

Dielectric hysteresis in single crystal BiFeO3

TL;DR: In this paper, single crystals of BiFeO3 of perovskite structure were grown with dimensions of greater than 1 mm from a Bi2O3 flux and dielectric hysteresis loops were measured on these crystals.
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