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Conductivity and transference number measurements on polymer electrolytes

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TLDR
In this article, straight-forward methods based on dc techniques are described which permit reliable evaluation of both the total conductivity and transference numbers of binary polymer electrolytes, and measurements are presented for PEOLiCF 3 SO 3 (9:1) electrolyte as a function of temperature.
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This article is published in Solid State Ionics.The article was published on 1988-09-01. It has received 312 citations till now. The article focuses on the topics: Conductivity & Electrolyte.

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Nanomaterials for rechargeable lithium batteries

TL;DR: Some of the recent scientific advances in nanomaterials, and especially in nanostructured materials, for rechargeable lithium-ion batteries are reviewed.
Journal ArticleDOI

Inorganic Solid-State Electrolytes for Lithium Batteries: Mechanisms and Properties Governing Ion Conduction

TL;DR: Insight is provided into the physical parameters affecting the diffusion process, to allow for more efficient and target-oriented research on improving solid-state ion conductors.
Journal ArticleDOI

Electrolytes for solid-state lithium rechargeable batteries: recent advances and perspectives

TL;DR: This critical review presents an overview of the various classes of Li(+) conductors for use as electrolytes in lithium polymer batteries and all-solid state microbatteries and focuses on the physico-chemical and functional parameters relevant for optimal electrolytes preparation.
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A review of composite solid-state electrolytes for lithium batteries: fundamentals, key materials and advanced structures.

TL;DR: In this article, a comprehensive overview of the recent developments in composite solid-state electrolytes (CSSEs) is presented, and four main types of advanced structures for CSSEs are classified and highlighted according to the recent progress.
References
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Journal ArticleDOI

Electrochemical measurement of transference numbers in polymer electrolytes

TL;DR: In this article, the transference number of lithium and trifluoromethanesulphonate ions in poly(ethylene oxide) at 90°C was measured and a mean value of 0.46 ± 0.02 was reported for lithium.
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Conductivity, charge transfer and transport number—an ac-investigation of the polymer electrolyte LiSCN-poly(ethyleneoxide)

TL;DR: In this paper, a series of impedance measurements in the frequency range 10−4−2 × 105 Hz and in the temperature range 20-170°C is reported for the cell: Li-metal/LiSCN [dissolved in poly (ethyleneoxide)]/Li-metal On the basis of the measurements a whole range of electrical properties such as the conductivity, the charge transfer resistance, the transport number for the Li+-ion, the double layer capacity and the dielectric constant were determined for the polymer complex.
Journal ArticleDOI

Formation of a passivating film at the lithium-PEO-LiCF3SO3 interface

TL;DR: In this article, the formation of a passivating film on lithium electrodes was demonstrated using ac impedance analysis, which is formed by an electrochemical reaction between the lithium electrode and the electrolyte, which consists of poly (ethylene oxide) and LiCF3SO3.
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