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Defect-engineered graphene chemical sensors with ultrahigh sensitivity

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TLDR
This study revealed that defect engineering in graphene has significant potential for fabricating ultra-sensitive graphene chemical sensors and systematically investigated the mechanism of gas sensing, which indicated that the vacancy defect is a major contributing factor to the enhanced sensitivity.
Abstract
We report defect-engineered graphene chemical sensors with ultrahigh sensitivity (e.g., 33% improvement in NO2 sensing and 614% improvement in NH3 sensing). A conventional reactive ion etching system was used to introduce the defects in a controlled manner. The sensitivity of graphene-based chemical sensors increased with increasing defect density until the vacancy-dominant region was reached. In addition, the mechanism of gas sensing was systematically investigated via experiments and density functional theory calculations, which indicated that the vacancy defect is a major contributing factor to the enhanced sensitivity. This study revealed that defect engineering in graphene has significant potential for fabricating ultra-sensitive graphene chemical sensors.

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Citations
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Surface functionalization of epitaxial graphene on SiC by ion irradiation for gas sensing application

TL;DR: In this paper, surface functionalization of epitaxial graphene grown on silicon carbide was performed by ion irradiation to investigate their gas sensing capabilities, and the surface morphology of irradiated graphene layers showed graphene folding, hillocks, and formation of wrinkles at highest fluence.
Journal ArticleDOI

Efficient hydrogen production from ethanol steam reforming over layer-controlled graphene-encapsulated Ni catalysts

TL;DR: In this paper, a graphene-encapsulated Ni nanoparticles (Ni@Gr) were fabricated via in-situ growth method to decrease the graphene layer number, and an approach to fabricate defects on the graphene surface was presented.
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Optical response and gas sequestration properties of metal cluster supported graphene nanoflakes

TL;DR: The metal clusters lower the Fermi levels of the host nanoflakes and enable them to exhibit reasonably good optical response properties such as polarizability and static first hyperpolarizability, and the dynamic stability of M3O(+)@GR/B GR/BNGR moieties is confirmed.
Journal ArticleDOI

Fabrication of piezoresistive based pressure sensor via purified and functionalized CNTs/PDMS nanocomposite: Toward development of haptic sensors

TL;DR: In this paper, a chemically modified technique via screen printing method was used to fabricate carbon nanotubes (CNTs)/Polydimethylsiloxane (PDMS) nanocomposite to monitor the piezoresistive behavior of nanocomposition while applying pressure.
References
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Generalized Gradient Approximation Made Simple

TL;DR: A simple derivation of a simple GGA is presented, in which all parameters (other than those in LSD) are fundamental constants, and only general features of the detailed construction underlying the Perdew-Wang 1991 (PW91) GGA are invoked.
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TL;DR: An efficient scheme for calculating the Kohn-Sham ground state of metallic systems using pseudopotentials and a plane-wave basis set is presented and the application of Pulay's DIIS method to the iterative diagonalization of large matrices will be discussed.
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Special points for brillouin-zone integrations

TL;DR: In this article, a method for generating sets of special points in the Brillouin zone which provides an efficient means of integrating periodic functions of the wave vector is given, where the integration can be over the entire zone or over specified portions thereof.
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The rise of graphene

TL;DR: Owing to its unusual electronic spectrum, graphene has led to the emergence of a new paradigm of 'relativistic' condensed-matter physics, where quantum relativistic phenomena can now be mimicked and tested in table-top experiments.
Journal ArticleDOI

Ab initio molecular dynamics for liquid metals.

TL;DR: In this paper, the authors present an ab initio quantum-mechanical molecular-dynamics calculations based on the calculation of the electronic ground state and of the Hellmann-Feynman forces in the local density approximation.
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This study revealed that defect engineering in graphene has significant potential for fabricating ultra-sensitive graphene chemical sensors.