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Journal ArticleDOI

Dibenzothiophene-S,S-dioxide-fluorene co-oligomers. Stable, highly-efficient blue emitters with improved electron affinity.

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TLDR
Incorporation of dibenzothiophene-S,S-dioxide units into conjugated fluorene oligomers changes the frontier orbital energy levels and presents an effective way to increase the electron affinity of these materials.
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This article is published in Chemical Communications.The article was published on 2005-07-01. It has received 125 citations till now. The article focuses on the topics: Electron affinity (data page) & Fluorene.

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Citations
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Journal ArticleDOI

Light-Emitting Polythiophenes†

TL;DR: In this article, a review of the light-emitting properties of conjugated polymers is presented, with a focus on the application of polythiophenes as electroluminescent materials.
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Solution-processable single-material molecular emitters for organic light-emitting devices.

TL;DR: Emphasis is placed on the relationships between the molecular structure and the electronic properties of molecular emitters, in which high photoluminescence efficiency, synthetic accessibility and processability are combined by design with additional functions such as hole and/or electron injection and transport.

Stabilized Blue Emission from Polyfluorene-Based Light-Emitting Diodes: Elimination of Fluorenone Defects

Xiong Gong
TL;DR: In this paper, the photoluminescence (PL) and electroluminescent (EL) of polyfluorene (PF)-based light-emitting diodes (LEDs) were studied and it was shown that the low-energy emission band originates from fluorenone defects which are introduced by photo-oxidization, thermal oxidation, or during device fabrication.
References
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Journal ArticleDOI

Density‐functional thermochemistry. III. The role of exact exchange

TL;DR: In this article, a semi-empirical exchange correlation functional with local spin density, gradient, and exact exchange terms was proposed. But this functional performed significantly better than previous functionals with gradient corrections only, and fits experimental atomization energies with an impressively small average absolute deviation of 2.4 kcal/mol.
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Development of the Colle-Salvetti correlation-energy formula into a functional of the electron density

TL;DR: Numerical calculations on a number of atoms, positive ions, and molecules, of both open- and closed-shell type, show that density-functional formulas for the correlation energy and correlation potential give correlation energies within a few percent.
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Density-functional exchange-energy approximation with correct asymptotic behavior.

TL;DR: This work reports a gradient-corrected exchange-energy functional, containing only one parameter, that fits the exact Hartree-Fock exchange energies of a wide variety of atomic systems with remarkable accuracy, surpassing the performance of previous functionals containing two parameters or more.
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Semiconducting Polyfluorenes—Towards Reliable Structure–Property Relationships

TL;DR: In this paper, the authors focus on reliable structure-property relationships regarding substitution pattern, solid state morphology, and optical/electronic properties, and the key role of degradation-induced keto defect sites in fluorerse-type polymers and strategies for obtaining defect-free polyfluorenes.
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