scispace - formally typeset
Journal ArticleDOI

Digital processing and communication with molecular switches

Françisco M. Raymo
- 18 Mar 2002 - 
- Vol. 14, Iss: 6, pp 401-414
Reads0
Chats0
TLDR
In this paper, the three basic logic operations (AND, NOT, and OR) and more complex logic functions (EOR, INH, NOR, XNOR, and XOR) have been reproduced already at the molecular level.
Abstract
The tremendous pace in the development of information technology is rapidly approaching a limit. Alternative materials and operating princlples for the elaboration and communication of data in electronic circults and optical networks must be identified. Organic molecules are promising candidates for the realization of future digital processors. Their attractive features are the miniaturized dimensions and the high degree of control on molecular design possible in chemical synthesis. Indeed, nanostructures with engineered properties and specific functions can be assembled relying on the power of organic synthesis. In particular, certain molecales can be designed to switch from one state to another, when addressed with chemical, electrical, or optical stimulations, and to produce a detectable signal in response to these transformations. Binary data can be enceded on the input stimulations and output signals employing logic conventions and assumptions similar to those ruting digital electronics. Thus, binary inputs can be transduced into binary outputs relying on molecular switches. Following these design principles, the three basic logic operations (AND, NOT, and OR) and more complex logic functions (EOR, INH, NOR, XNOR, and XOR) have been reproduced already at the molecular level. Presently, these simple "molecular processors" are far from any practical application. However, these encouraging results demonstrate already that chemical systems can process binary data with designed logic protocols. Further fundamental studies on the various facets of this emerging area will reveal if and how molecular switches can become the basic components of furture logic devices. After all, chemical computers are available atready. We all carry one in our head!

read more

Citations
More filters
Journal ArticleDOI

Atypical photomagnetic properties in a series of binuclear iron(II) spin crossover complexes

TL;DR: In this paper, the photomagnetic properties of a series of binuclear iron(II) complexes of formula [{Fe(L)(NCX)2}2bpym], where L is bpym = 2,2′-bipyrimidine and X = S, Se, by light irradiation at 647.1-676.4 nm and at 830 nm, were examined.
Journal ArticleDOI

Molecular Processors: From Qubits to Fuzzy Logic

TL;DR: It is demonstrated how it is possible to process different types of logic through molecules, as long as decoherent effects are maintained far away from a pure quantum mechanical system, quantum logic can be processed.
Journal ArticleDOI

Novel 4-(2,2,6,6-tetramethylpiperidin-4-ylamino)-1,8-naphthalimide based yellow-green emitting fluorescence sensors for transition metal ions and protons

TL;DR: In this article, the photophysical characteristics of the dyes were investigated in both DMF and water/DMF (4:1, v/v) solutions, and the results clearly show that only Cu2+ ions and protons were effectively detected.
Journal ArticleDOI

Towards the development of Eu(III) luminescent switching/sensing in water permeable hydrogels

TL;DR: In this article, the synthesis of the Eu(III) complex 1.Eu and photophysical studies of this complex in solution are described and the luminescent properties of the resulting polymeric films are investigated using confocal laser-scanning microscopy as well as using steady-state luminescence.
References
More filters
Journal ArticleDOI

Molecular computation of solutions to combinatorial problems

TL;DR: This experiment demonstrates the feasibility of carrying out computations at the molecular level by solving an instance of the directed Hamiltonian path problem with standard protocols and enzymes.
Journal ArticleDOI

Conductance of a Molecular Junction

TL;DR: In this paper, benzene-1,4-dithiol molecules were self-assembled onto the two facing gold electrodes of a mechanically controllable break junction to form a statically stable gold-sulfur-aryl-solfur-gold system, allowing for direct observation of charge transport through the molecules.
Journal ArticleDOI

Electronics using hybrid-molecular and mono-molecular devices

TL;DR: ‘mono-molecular’ electronics, in which a single molecule will integrate the elementary functions and interconnections required for computation, is proposed.
Journal ArticleDOI

Logic circuits with carbon nanotube transistors

TL;DR: This work demonstrates logic circuits with field-effect transistors based on single carbon nanotubes that exhibit a range of digital logic operations, such as an inverter, a logic NOR, a static random-access memory cell, and an ac ring oscillator.
Related Papers (5)