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Journal ArticleDOI

Digital processing and communication with molecular switches

Françisco M. Raymo
- 18 Mar 2002 - 
- Vol. 14, Iss: 6, pp 401-414
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TLDR
In this paper, the three basic logic operations (AND, NOT, and OR) and more complex logic functions (EOR, INH, NOR, XNOR, and XOR) have been reproduced already at the molecular level.
Abstract
The tremendous pace in the development of information technology is rapidly approaching a limit. Alternative materials and operating princlples for the elaboration and communication of data in electronic circults and optical networks must be identified. Organic molecules are promising candidates for the realization of future digital processors. Their attractive features are the miniaturized dimensions and the high degree of control on molecular design possible in chemical synthesis. Indeed, nanostructures with engineered properties and specific functions can be assembled relying on the power of organic synthesis. In particular, certain molecales can be designed to switch from one state to another, when addressed with chemical, electrical, or optical stimulations, and to produce a detectable signal in response to these transformations. Binary data can be enceded on the input stimulations and output signals employing logic conventions and assumptions similar to those ruting digital electronics. Thus, binary inputs can be transduced into binary outputs relying on molecular switches. Following these design principles, the three basic logic operations (AND, NOT, and OR) and more complex logic functions (EOR, INH, NOR, XNOR, and XOR) have been reproduced already at the molecular level. Presently, these simple "molecular processors" are far from any practical application. However, these encouraging results demonstrate already that chemical systems can process binary data with designed logic protocols. Further fundamental studies on the various facets of this emerging area will reveal if and how molecular switches can become the basic components of furture logic devices. After all, chemical computers are available atready. We all carry one in our head!

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Citations
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Polypyridyl-imidazole based smart Ru(II) complex mimicking advanced Boolean and Fuzzy logic functions

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Organic charge-transfer complexes for STM-based thermochemical-hole-burning memory

TL;DR: In this article, the authors present an overview of the recent advances and representative achievements of scanning probe microscopy-based data storage from the viewpoints of recording techniques including electrical bistability, photoelectrochemical conversion, field-induced charge storage, atomic manipulation or deposition, local oxidation, magneto-optical or magnetic recording, thermally induced physical deformation or phase change, and so forth.
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Short-Term Memory Dynamics of TiN/Ti/TiO2/SiOx/Si Resistive Random Access Memory

TL;DR: The results herein presented confirm the viability of implementing a CMOS-compatible neuromorphic chip and demonstrate spike-timing-dependent plasticity with the change in synaptic weight is performed by the time difference between the pre- and postsynaptic neurons.
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Survey on Langmuir–Blodgett Films of Polymer and Polymeric Composite

TL;DR: A concise review of research performed in the field of Langmuir-blodgett films can be found in this article, where various types of conducting polymers such as piezoelectric/pyroelectric polymers, and ferro-electric polymeric polymers have been utilized for fabrication of polymeric and composite LBLD films.
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Electric field control of proton-transfer molecular switching: molecular dynamics study on salicylidene aniline

TL;DR: A novel, ultrafast, efficient molecular switch whose switching mechanism involves the electric field-driven intramolecular proton transfer is proposed and the switching performance of an isolated salicylidene aniline molecule is examined.
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Journal ArticleDOI

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