Journal ArticleDOI
Dual Emission through Thermally Activated Delayed Fluorescence and Room-Temperature Phosphorescence, and Their Thermal Enhancement via Solid-State Structural Change in a Carbazole-Quinoline Conjugate
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TLDR
Experimental studies on dual emission of carbazole-quinoline conjugate show that the intensity of the dual features is enhanced with increasing temperatures up to 100 °C, which can be explained by a thermal-induced structural change (TISC) mechanism that compensates the emission losses due to nonradiative transitions at elevated temperatures.Abstract:
The emergence of single-component organic dual light emitters holds great promise for white light-emitting diodes (WLEDs) and biological detection due to the involvement of broad emission covering visible spectrum. Here we show experimental studies on dual emission of carbazole-quinoline conjugate (CQ) that exhibits both thermally activated delayed fluorescence (TADF) via reverse intersystem crossing (rISC) from the higher-lying triplet state (T2) to the singlet state (S1) and room-temperature phosphorescence (RTP) from the lowest triplet state (T1) due to low energy gap between T2 and S1, and energetic proximity of T1 with T2. We found in thermal effect that the intensity of the dual features is enhanced with increasing temperatures up to 100 °C, which can be explained by a thermal-induced structural change (TISC) mechanism that compensates the emission losses due to nonradiative transitions at elevated temperatures. This property, in addition to its enhanced TADF and phosphorescence decay rates (∼107 s–...read more
Citations
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Dual Emission: Classes, Mechanisms and Conditions.
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Dual emission in purely organic materials for optoelectronic applications.
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Molecular Engineering Approaches Towards All-Organic White Light Emitting Materials
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Highly efficient phosphorescent emission from organic electroluminescent devices
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TL;DR: In this article, a host material doped with the phosphorescent dye PtOEP (PtOEP II) was used to achieve high energy transfer from both singlet and triplet states.
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Density-Functional Theory for Time-Dependent Systems
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Highly efficient organic light-emitting diodes from delayed fluorescence
Hiroki Uoyama,Kenichi Goushi,Kenichi Goushi,Katsuyuki Shizu,Hiroko Nomura,Chihaya Adachi,Chihaya Adachi +6 more
TL;DR: A class of metal-free organic electroluminescent molecules in which the energy gap between the singlet and triplet excited states is minimized by design, thereby promoting highly efficient spin up-conversion from non-radiative triplet states to radiative singlet states while maintaining high radiative decay rates.