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Eco-Friendly Higher Manganese Silicide Thermoelectric Materials: Progress and Future Challenges

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TLDR
In this paper, the authors summarized the crystal structure, band structure, synthesis method, and pristine thermoelectric performance of different higher manganese silicides and highlighted the strategies for enhancing electrical performance and reducing lattice thermal conductivity.
Abstract
As a promising thermoelectric material, higher manganese silicides are composed of earth-abundant and eco-friendly elements, and have attracted extensive attention for future commercialization. In this review, the authors first summarize the crystal structure, band structure, synthesis method, and pristine thermoelectric performance of different higher manganese silicides. After that, the strategies for enhancing electrical performance and reducing lattice thermal conductivity of higher manganese silicides as well as their synergism are highlighted. The application potentials including the chemical and mechanical stability of higher manganese silicides and their energy conversion efficiency of the assembled thermoelectric modules are also summarized. By analyzing the current advances in higher manganese silicides, this review proposes that potential methods of further enhancing zT of higher manganese silicides, lie in enhancing electrical performance while simultaneously reducing lattice thermal conductivity via reducing effective mass, optimizing carrier concentration, and nanostructure engineering.

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Advanced Thermoelectric Design: From Materials and Structures to Devices

TL;DR: This review aims to comprehensively summarize the state-of-the-art strategies for the realization of high-performance thermoelectric materials and devices by establishing the links between synthesis, structural characteristics, properties, underlying chemistry and physics.
Journal ArticleDOI

Flexible Thermoelectric Materials and Generators: Challenges and Innovations.

TL;DR: The state-of-the-art in the development of flexible thermoelectric materials and devices is summarized, including exploring the fundamentals behind the performance of flexible temperature-conversion efficiency and properties by relating materials chemistry and physics to properties.
Journal ArticleDOI

Thermoelectric GeTe with Diverse Degrees of Freedom Having Secured Superhigh Performance.

TL;DR: The most recent progress in superhigh-performance GeTe-based thermoelectric materials is reviewed with a focus on the crystal structures, phase transitions, resonant bondings, multiple valance bands, and phonon dispersions, which diversify the degrees of freedom to tune the transport properties of electrons and phonons for GeTe.
Journal ArticleDOI

Promising and Eco-Friendly Cu 2 X-Based Thermoelectric Materials: Progress and Applications

TL;DR: The effective strategies in enhancing the thermoelectric performance of Cu2 X-based thermoeLECTric materials are summarized, in which the proper optimization of carrier concentration and minimization of the lattice thermal conductivity are the main focus.
Journal ArticleDOI

High-Performance GeTe-Based Thermoelectrics: from Materials to Devices

TL;DR: In this article, an overview of the structural and electronic band characteristics of GeTe-based thermoelectric materials is presented, and it is recognized that the performance of Gete-based materials can be further enhanced through synergistic effects, such as carrier concentration optimization, band structure engineering, and restrained lattice thermal conductivity.
References
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Journal ArticleDOI

Complex thermoelectric materials.

TL;DR: A new era of complex thermoelectric materials is approaching because of modern synthesis and characterization techniques, particularly for nanoscale materials, and the strategies used to improve the thermopower and reduce the thermal conductivity are reviewed.
Journal ArticleDOI

Dye-Sensitized Solar Cells

TL;DR: Dye-sensitized solar cells (DSCs) offer the possibilities to design solar cells with a large flexibility in shape, color, and transparency as mentioned in this paper, and many DSC research groups have been established around the world.
Journal ArticleDOI

Cooling, heating, generating power, and recovering waste heat with thermoelectric systems.

Lon E. Bell
- 12 Sep 2008 - 
TL;DR: Thermoelectric materials are solid-state energy converters whose combination of thermal, electrical, and semiconductor properties allows them to be used to convert waste heat into electricity or electrical power directly into cooling and heating.
Journal ArticleDOI

High-Thermoelectric Performance of Nanostructured Bismuth Antimony Telluride Bulk Alloys

TL;DR: Electrical transport measurements, coupled with microstructure studies and modeling, show that the ZT improvement is the result of low thermal conductivity caused by the increased phonon scattering by grain boundaries and defects, which makes these materials useful for cooling and power generation.
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