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Journal ArticleDOI

Effects of pressure on biomass pyrolysis. II. Heats of reaction of cellulose pyrolysis

William Shu Lai Mok, +1 more
- 01 Oct 1983 - 
- Vol. 68, pp 165-186
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TLDR
In this article, the effects of pressure and purge gas flow rate (gas phase residence time) on the heat demands of cellulose pyrolysis were investigated using a Setaram DSC in conjunction with stainless steel pressure vessels.
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This article is published in Thermochimica Acta.The article was published on 1983-10-01. It has received 219 citations till now. The article focuses on the topics: Levoglucosan & Char.

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Citations
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Thermochemical biofuel production in hydrothermal media: A review of sub- and supercritical water technologies

TL;DR: Several biomass hydrothermal conversion processes are in development or demonstration as mentioned in this paper, which are generally lower temperature (200-400 °C) reactions which produce liquid products, often called bio-oil or bio-crude.
Journal ArticleDOI

Modeling chemical and physical processes of wood and biomass pyrolysis

TL;DR: In this article, the state of the art in modeling chemical and physical processes of wood and biomass pyrolysis is reported, and the main achievements of numerical simulations are discussed.
Journal ArticleDOI

The Art, Science, and Technology of Charcoal Production†

TL;DR: In this article, the authors summarize the knowledge of the production and properties of charcoal that has been accumulated over the past 38 millenia and summarize the potential of charcoal as a renewable fuel.
Journal ArticleDOI

A state-of-the-art review of biomass torrefaction, densification and applications

TL;DR: In this article, the authors provide a comprehensive review of research progress in this area, drawing on major contributions from two major research groups of the authors on torrefaction and densification at Canada and Taiwan as well as literatures.
References
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Journal ArticleDOI

A kinetic model for pyrolysis of cellulose.

TL;DR: In this article, it was shown that the pyrolysis of cellulose at low pressure (1.5 Torr) can be described by a three reaction model, where an initialization reaction leads to formation of an active cellulose which subsequently decomposes by two competitive first-order reactions, one yielding volatiles and the other char and a gaseous fraction.
Journal ArticleDOI

Thermogravimetric and differential thermal analysis of cellulose, hemicellulose, and lignin

TL;DR: In this article, the authors investigated the thermal degradation of cellulose, hemicellulose, and lignin using the techniques of thermogravimetric analysis (TGA) and differential thermal analysis (DTA) between room temperature and 600°C.
Journal ArticleDOI

Competitive Reactions in the Thermal Decomposition of Cellulose

TL;DR: In this paper, it was shown that when cellulose is heated it undergoes two competitive reactions and the actual sequence of these is clarified, being different from that previously postulate.
Journal ArticleDOI

Effects of reactor severity on the gas-phase pyrolysis of cellulose- and kraft lignin-derived volatile matter

TL;DR: In this paper, the dependence of gas yields on temperature and residence time was explained by a global mechanism composed of two competing reactions: the first creates permanent gases by cracking the volatile matter, whereas the second creates refractory condensable materials.
Journal ArticleDOI

Effects of pressure on biomass pyrolysis. I. Cellulose pyrolysis products

TL;DR: In this article, a three phase research program, using a tubular, laminar flow, micro reactor system, was undertaken to study the effects of pressure on biomass pyrolysis.
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