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Journal ArticleDOI

Electromagnetic interference shielding with 2D transition metal carbides (MXenes)

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TLDR
The mechanical flexibility and easy coating capability offered by MXenes and their composites enable them to shield surfaces of any shape while providing high EMI shielding efficiency.
Abstract
Materials with good flexibility and high conductivity that can provide electromagnetic interference (EMI) shielding with minimal thickness are highly desirable, especially if they can be easily processed into films. Two-dimensional metal carbides and nitrides, known as MXenes, combine metallic conductivity and hydrophilic surfaces. Here, we demonstrate the potential of several MXenes and their polymer composites for EMI shielding. A 45-micrometer-thick Ti3C2Tx film exhibited EMI shielding effectiveness of 92 decibels (>50 decibels for a 2.5-micrometer film), which is the highest among synthetic materials of comparable thickness produced to date. This performance originates from the excellent electrical conductivity of Ti3C2Tx films (4600 Siemens per centimeter) and multiple internal reflections from Ti3C2Tx flakes in free-standing films. The mechanical flexibility and easy coating capability offered by MXenes and their composites enable them to shield surfaces of any shape while providing high EMI shielding efficiency.

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Citations
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Journal ArticleDOI

Ultrathin Topological Insulator Absorber: Unique Dielectric Behavior of Bi2Te3 Nanosheets Based on Conducting Surface States.

TL;DR: Benefiting from the outstanding impedance matching, Bi2Te3 nanosheets exhibit an ultra-thin microwave absorption with the qualified frequency bandwidth of 3.0 GHz at only 0.77 mm thickness, which is thinner than other absorbers in reported references.
Journal ArticleDOI

A TTF–TCNQ complex: an organic charge-transfer system with extraordinary electromagnetic response behavior

TL;DR: In this paper, a nanostructural tetrathiofulvlene-7,7,8,8-tetracyanoquinodimethane (TTF-TCNQ) complex, an organic charge transfer system, was prepared via a solution mixing route.
Journal ArticleDOI

Developing MXenes from Wireless Communication to Electromagnetic Attenuation

TL;DR: In this article, the authors systematically review the recent advances in MXene-based materials with different structural designs for wireless communication, electromagnetic interference (EMI) shielding, and EM wave absorption.
Journal ArticleDOI

MnO2 nanorods/MXene/CC composite electrode for flexible supercapacitors with enhanced electrochemical performance

TL;DR: In this article, a highly deformable and conductive freestanding electrode based on the composite of MnO2 and MXene on carbon cloth is designed, and the capacitance of the composite electrode was reduced by only 17% after 10,000 cycles.
Journal ArticleDOI

Nacre-Inspired Tunable Electromagnetic Interference Shielding Sandwich Films with Superior Mechanical and Fire-Resistant Protective Performance

TL;DR: An electrical insulating sandwich structured film based on Ca ion crosslinked sodium alginate (SA)-montmorillonite (MMT) and Ti3C2Tx MXene through step-by-step vacuum-assisted filtration process provides a novel EMI material strategy to facilitate its future application in flexible electronics.
References
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Journal ArticleDOI

Two‐Dimensional Nanocrystals Produced by Exfoliation of Ti 3 AlC 2

TL;DR: 2D nanosheets, composed of a few Ti 3 C 2 layers and conical scrolls, produced by the room temperature exfoliation of Ti 3 AlC 2 in hydrofl uoric acid are reported, which opens a door to the synthesis of a large number of other 2D crystals.
Journal ArticleDOI

25th Anniversary Article: MXenes: A New Family of Two‐Dimensional Materials

TL;DR: In this article, a new family of two-dimensional early transition metal carbides and carbonitrides, called MXenes, was discovered and a detailed outlook for future research on MXenes is also presented.
Journal ArticleDOI

Conductive two-dimensional titanium carbide ‘clay’ with high volumetric capacitance

TL;DR: This capacitance report reports a method of producing two-dimensional titanium carbide ‘clay’ using a solution of lithium fluoride and hydrochloric acid that offers a much faster route to film production as well as the avoidance of handling hazardous concentrated hydrofluoric acid.
Journal ArticleDOI

Cation Intercalation and High Volumetric Capacitance of Two-Dimensional Titanium Carbide

TL;DR: This study demonstrates the spontaneous intercalation of cations from aqueous salt solutions between two-dimensional (2D) Ti3C2 MXene layers, and provides a basis for exploring a large family of 2D carbides and carbonitrides in electrochemical energy storage applications using single- and multivalent ions.
Journal ArticleDOI

Electromagnetic interference shielding effectiveness of carbon materials

TL;DR: Carbon materials for electromagnetic interference (EMI) shielding are reviewed in this article, including composite materials, colloidal graphite and flexible graphite, and they include carbon filaments of submicron diameter.
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