Journal ArticleDOI
Evaluated kinetic and photochemical data for atmospheric chemistry
Reads0
Chats0
TLDR
A critical evaluation of the kinetics and photochemistry of gas phase chemical reactions of neutral species involved in middle atmosphere chemistry (10-55 km altitude) was carried out by the authors under the auspices of the CODATA Task Group on Chemical Kinetics.Abstract:
This paper contains a critical evaluation of the kinetics and photochemistry of gas phase chemical reactions of neutral species involved in middle atmosphere chemistry (10–55 km altitude). The work has been carried out by the authors under the auspices of the CODATA Task Group on Chemical Kinetics. Data sheets have been prepared for 148 thermal and photochemical reactions, containing summaries of the available experimental data with notes giving details of the experimental procedures. For each reaction a preferred value of the rate coefficient at 298 K is given together with a temperature dependency where possible. The selection of the preferred value is discussed, and estimates of the accuracies of the rate coefficients and temperature coefficients have been made for each reaction. The data sheets are intended to provide the basic physical chemical data needed as input for calculations which model atmospheric chemistry. A table summarizing the preferred rate data is provided, together with an Appendix listing the available data on enthalpies of formation of the reactant and product species.read more
Citations
More filters
Journal ArticleDOI
Atmospheric chemistry of VOCs and NOx
TL;DR: The present status of knowledge of the gas phase reactions of inorganic Ox, Hox and NOx species and of selected classes of volatile organic compounds (VOCs) and their degradation products in the troposphere is discussed in this paper.
Journal ArticleDOI
Tropospheric chemistry: A global perspective
TL;DR: A model for the photochemistry of the global troposphere constrained by observed concentrations of H2O, O3, CO, CH4, NO, NO2, and HNO3 is presented in this paper.
Journal ArticleDOI
Evaluated kinetic and photochemical data for atmospheric chemistry: Volume IV – gas phase reactions of organic halogen species
Roger Atkinson,Donald L. Baulch,R. A. Cox,John Crowley,R. F. Hampson,R. G. Hynes,Michael E. Jenkin,Michel J. Rossi,J. Troe,Timothy J. Wallington +9 more
TL;DR: The IUPAC Subcommittee on Gas Kinetic Data Evaluation for Atmospheric Chemistry (IUPAC-GKDE) as mentioned in this paper has published a series of data sheets for organic halogen species.
Journal ArticleDOI
Gas-phase tropospheric chemistry of organic compounds: A review
TL;DR: The current knowledge of the gas phase reactions occurring in the troposphere for alkanes, alkenes, alkynes, oxygenates and aromatic hydrocarbons and their photooxidation products is reviewed, and areas of uncertainty identified as mentioned in this paper.
Journal ArticleDOI
Trends in NOx abatement: A review
TL;DR: The main focus is put on NO(x) control methods applied in combustion of fossil fuels in power stations and mobile vehicles, as well as methods used in chemical industry, where the implementation of ozone and other oxidizing agents in NO (x) oxidation is emphasized.
References
More filters
Journal ArticleDOI
Predictive possibilities of unimolecular rate theory
TL;DR: In this paper, the authors described the rate constants for thermal unimolecular reactions and recombinations at the low pressure limit, at the high pressure limit and in the intermediate falloff range.
Journal ArticleDOI
Evaluated Kinetic and Photochemical Data for Atmospheric Chemistry: Supplement I CODATA Task Group on Chemical Kinetics
TL;DR: In this paper, a critical evaluation of the kinetics and photochemistry of gas phase chemical reactions of neutral species involved in middle atmosphere chemistry (10-55 km altitude) was carried out under the auspices of the CODATA Task Group on Chemical Kinetics.
Journal ArticleDOI
Photochemistry of small molecules
TL;DR: Okabe et al. as mentioned in this paper described the photochemistry of small molecules and their role in the development and evolution of the human body's ability to communicate with other small molecules, including DNA.
Journal ArticleDOI
The Adsorption of Vapours on Mercury. I. Non-Polar Substances
TL;DR: In this article, the results for the adsorption of benzene, toluene and n-heptane vapours on mercury have been obtained and the films were found to be gaseous and obeyed the Volmer equation F(A-b) = kT, where F = spreading pressure, A = area per molecule and b = co-area.