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Journal ArticleDOI

Flexible SnS nanobelts: Facile synthesis, formation mechanism and application in Li-ion batteries

Jun Lu, +4 more
- 01 Jan 2013 - 
- Vol. 6, Iss: 1, pp 55-64
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TLDR
In this paper, a tin sulfide nanobelts with a length/thickness ratio of 100 have been synthesized by a facile hydrothermal method without any surfactants, and they have shown good strain-accommodating properties as well as good electrochemical performance as the anode for Li-ion batteries.
Abstract
[020]-oriented tin sulfide nanobelts with a length/thickness ratio of 100 have been synthesized by a facile hydrothermal method without any surfactants, and the nanobelts have shown good strain-accommodating properties as well as good electrochemical performance as the anode for Li-ion batteries. The formation of the nanobelts results from a precipitation-dissolution-transformation mechanism, and the [020] oriented growth can be ascribed to the {010} facet family having the lowest atomic density. In particular, SnS shows clear Li-Sn alloying/de-alloying reversible reactions in the potential range 0.1–1.0 V. Based on galvanostatic measurements and electrochemical impedance spectroscopy, SnS nanobelts have shown impressive rate performance. The post-cycled SnS nanobelts were completely transformed into metallic tin, and preserved the one-dimensional structure due to their flexibility which accommodates the large volumetric expansion. Open image in new window

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Citations
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Journal ArticleDOI

Array of nanosheets render ultrafast and high-capacity Na-ion storage by tunable pseudocapacitance

TL;DR: A high-capacity and high-rate sodium-ion anode based on ultrathin layered tin(II) sulfide nanostructures, in which a maximized extrinsic pseudocapacitance contribution is identified and verified by kinetics analysis.
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Enhanced sodium-ion battery performance by structural phase transition from two-dimensional hexagonal-SnS2 to orthorhombic-SnS.

TL;DR: The first report on a SnS@graphene architecture for application as a sodium-ion battery anode, which is built from two-dimensional SnS and graphene nanosheets as complementary building blocks, finds the performance was found to be much better than those of most reported anode materials for Na-ion batteries.
Journal ArticleDOI

Two-dimensional transistors beyond graphene and TMDCs

TL;DR: The recent efforts and progress in exploring novel 2DSCs beyond graphene and TMDCs for ultra-thin body transistors are reviewed, discussing the merits, limits and prospects of each material.
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A General Strategy to Fabricate Carbon-Coated 3D Porous Interconnected Metal Sulfides: Case Study of SnS/C Nanocomposite for High-Performance Lithium and Sodium Ion Batteries

TL;DR: A novel general strategy is proposed to fabricate a 3D porous interconnected metal sulfide/carbon nanocomposite by the electrostatic spray deposition technique without adding any expensive carbonaceous materials such as graphene or carbon nanotube.
Journal ArticleDOI

Achieving high gravimetric energy density for flexible lithium-ion batteries facilitated by core–double-shell electrodes

TL;DR: In this article, a 39.0 cm2 all-flexible lithium-ion battery with high gravimetric energy density (314 W h kg−1), excellent flexibility, and good storage performance is presented.
References
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Journal ArticleDOI

High-performance lithium battery anodes using silicon nanowires

TL;DR: The theoretical charge capacity for silicon nanowire battery electrodes is achieved and maintained a discharge capacity close to 75% of this maximum, with little fading during cycling.
Journal ArticleDOI

Tin-Based Amorphous Oxide: A High-Capacity Lithium-Ion-Storage Material

TL;DR: A tin-based amorphous composite oxide (TCO) was synthesized in this paper to replace the carbon-based lithium intercalation materials currently in extensive use as the negative electrode (anode) of lithium-ion rechargeable batteries.
Journal ArticleDOI

Tin-Nanoparticles Encapsulated in Elastic Hollow Carbon Spheres for High-Performance Anode Material in Lithium-Ion Batteries†

TL;DR: Zhang et al. as mentioned in this paper designed a new approach to synthesize tin nanoparticles encapsulated elastic hollow carbon spheres (TNHCs) with uniform size, in which multiple tin particles with a diameter of less than 100 nm were encapsulated in one thin hollow carbon sphere with a thickness of only about 20 nm, thus leading to both the content of Sn up to over 70% by weight and the void volume in carbon shell as high as about 70-80%by volume.
BookDOI

Handbook of Battery Materials

TL;DR: In this article, the structural stability of transition metal oxide insertion electrodes for battery systems failure mechanism, mechanical properties, and Advanced in-situ Characterization Methods Battery Safety Battery Manufacturing and Economic Aspects.
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