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Journal ArticleDOI

Highly sensitive, ambient temperature CO sensor using tin oxide based composites

TLDR
In this article, the authors reported an excellent gas sensing performance of the unique nanocomposite films prepared with the help of different materials such as semiconductor metaloxide, polymer and metal for carbon monoxide gas sensing at ambient temperature.
Abstract
In the present work, we report an excellent gas sensing performance of the unique nanocomposite films prepared with the help of different materials such as semiconductor metal-oxide, polymer and metal for carbon monoxide gas sensing at ambient temperature. The fabrication of SnO2/PANI/Pd nanocomposite film was performed using the hydrothermal route. The fabricated films were characterized with various analytical techniques such as X-ray diffraction (XRD), Field emission scanning electron microscope (FESEM), and Raman spectroscopy, Fourier transform infrared spectroscopy (FTIR) etc. Furthermore, DFT results are used to examine the transport and electronic properties of all prepared films. The computing results show that after hybridizing with Pd and SnO2, the response of the fabricated SnO2 and polyaniline (PANI) films to CO gas molecules is considerably improved. At room temperature, sensing characterization of the fabricated sensing films was carried out by using target gas concentrations with varying ppm level of 50–300. At ambient temperature, the SnO2/PANI/Pd film has the maximum sensitivity ~ 400.8% out of all the fabricated films at 0.3% of the target gas. Our findings show that SnO2, SnO2/Pd, PANI, and SnO2/PANI/Pd composite sensing films have a bright future in the gas sensing application with incredibly-higher sensitivity towards CO gas.

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Citations
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Journal ArticleDOI

Designing Cu2+ as a Partial Substitution of Protons in Polyaniline Emeraldine Salt: Room-Temperature-Recoverable H2S Sensing Properties and Mechanism Study.

TL;DR: In this paper , a copper-II chloride-doped polyaniline emeraldine salt (PANI-CuCl2) was devised for RT-recoverable H2S detection, where the copper ion (Cu2+) was designed as a partial substitution of protons (H+) in PANI.
Journal ArticleDOI

Development of a Ferrite Film Based Solid State Sensor System for Ultra Low Concentration Hydrogen Sulfide Gas Detection

TL;DR: In this paper , a selective hydrogen sulfide gas sensor based on zinc ferrite film which is obtained by a microwave-assisted solvothermal deposition route is reported. And a dual-differential subtractor based auto balancing interface circuit is proposed to drive this sensor which is advantageous in terms of accuracy and particularly suitable for a device such as ours, which has a wide dynamic range.
Journal ArticleDOI

Bimetal PtPd functionalized Bi2MoO6 microspheres for conductometric detection of CO: A combined experimental and theoretical study

TL;DR: In this paper , the bimetallic nanoparticles modified polymetallic oxides are considered to be an attractive method to improve sensing performance, and the results showed the sensor based on BMO-1.5% exhibited an excellent response value of 7.18-200 ppm carbon monoxide (CO), which was approximately 5.28-fold higher than that of the initial BMO sensor (1.36).
Journal ArticleDOI

Comparative study on adsorption behaviour of the monolayer graphene, boron nitride and silicon carbide hetero-sheets towards carbon monoxide: Insights from first-principle studies

TL;DR: In this paper , a comprehensive study on the sensitivity of graphene, boron nitride, silicon carbide and their in-plane hetero-sheets towards carbon monoxide (CO) was performed using first-principle density functional theory calculations.
References
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Journal ArticleDOI

Nanoscale metal oxide-based heterojunctions for gas sensing: A review

TL;DR: In this paper, the dominant electronic and chemical mechanisms that influence the performance of metal-oxide-based resistive-type gas sensors are discussed, including p-n and n-n potential barrier manipulation, n-p-n response type inversions, spillover effects, synergistic catalytic behavior, and microstructure enhancement.
Journal ArticleDOI

Size effects in the Raman spectra of TiO2 nanoparticles

TL;DR: In this paper, the authors investigated the relationship between the particle size and the Raman bands of TiO 2 nanoparticles using transmission electron microscopy (TEM), X-ray absorption near edge structure (XANES), extended Xray absorption fine structure (EXAFS), and Raman spectroscopy.
Journal ArticleDOI

Composites of Intrinsically Conducting Polymers as Sensing Nanomaterials

TL;DR: The resonance-stabilized structure of ICPs allows for the incorporation of ions, nanoparticles, or nanowires of metals, metal oxides, carbon, or molecular species such as metallophthalocyanines or biologically active components such as enzymes, antibodies, and antigens.
Book

Nanostructures & nanomaterials : synthesis, properties & applications

Guozhong Cao
TL;DR: In this paper, the synthesis and fabrication of nanostructures and nanomaterials is discussed, as well as properties and applications of these materials, particularly inorganic ones.
Journal ArticleDOI

Polyaniline (PANi) based electrode materials for energy storage and conversion

TL;DR: In this article, a review summarizes the recent progress in PANi-based composites for energy storage/conversion, like application in supercapacitors, rechargeable batteries, fuel cells and water hydrolysis.
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