Journal ArticleDOI
Iron-catalyzed domino indole fluorination/allenic aza-Claisen rearrangement.
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TLDR
The synthesis of 2-allenyl-2-substituted-3,3-difluoroindolines has been accomplished, taking advantage of the reaction between N-allanyl-indoles and Selectfluor under iron catalysis.About:
This article is published in Chemical Communications.The article was published on 2016-05-12. It has received 16 citations till now. The article focuses on the topics: Claisen rearrangement & Selectfluor.read more
Citations
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Pd/PC-Phos-Catalyzed Enantioselective Intermolecular Denitrogenative Cyclization of Benzotriazoles with Allenes and N-Allenamides.
TL;DR: An asymmetric Pd/PC-Phos-catalyzed denitrogenative cyclization of benzotriazoles with allennes and N-allenamides is reported, which represents the first example of enantioselective denitrogensative cyclized benzotRIazoles.
Journal ArticleDOI
Synthesis of 3-Fluoroindoles via Photoredox Catalysis.
Liubov I. Panferova,Vladimir O. Smirnov,Vitalij V. Levin,Vladimir A. Kokorekin,Marina I. Struchkova,Alexander D. Dilman +5 more
TL;DR: A method for the synthesis of 3-fluoroindoles from N-arylamines substituted with the CF2I group is described, mediated by a ruthenium photocatalyst in the presence of a substoichiometric amount of triphenylphosphine upon irradiation with blue light.
Journal ArticleDOI
Organocatalytic Synthesis of gem‐Difluorinated C2‐Spiro Indolines and Pyrimido[1,2‐a]benzimidazoles from 2‐Alkynyl‐3,3‐Difluoro‐3H‐Indoles
Journal ArticleDOI
A Pd-catalyzed domino Larock annulation/dearomative Heck reaction
TL;DR: A palladium-catalyzed domino Larocks annulation/dearomative Heck reaction is developed, which delivers a range of tetracyclic indoline derivatives in moderate to excellent yields through a Larock annulation of N-bromobenzoyl o-iodoanilines with alkynes.
Journal ArticleDOI
When Indoles Meet Allene and its Derivatives
Jose M. Alonso,María Paz Muñoz +1 more
TL;DR: In this paper, a critical review of the wide and fascinating ways allenes and indoles can interact, and the structural diversity that can be achieved, is presented, as well as a detailed analysis of the interactions between the two functional groups.
References
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Gold-catalyzed carbon-heteroatom bond-forming reactions.
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