Journal ArticleDOI
Mixed-valence copper(I)copper(II) compounds: analysis and classification of crystallographic data
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This article is published in Coordination Chemistry Reviews.The article was published on 1988-01-01. It has received 71 citations till now. The article focuses on the topics: Valence (chemistry) & Copper.read more
Citations
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Conductive metal–organic frameworks and networks: fact or fantasy?
TL;DR: The Mott insulator-to-metal transition should be possible in semiconducting metal-organic frameworks, but has yet to be observed and the important role of materials modelling in the field is reviewed.
Journal ArticleDOI
Different oxidation states of copper(I, I/II, II) thiocyanate complexes containing 1,2,4-triazole as a bridging ligand: syntheses, crystal structures, and magnetic properties of 2-D polymer Cu I(admtrz)SCN, linear trinuclear [CuI2CuII(admtrz)6(SCN)2](ClO4)2, and triangular trinuclear [CuII3(admtrz)4(SCN)3(mu3-OH)(H2O)](ClO4)2.H2O (admtrz = 4-amino-3,5-dimethyl-1,2,4-triazole).
TL;DR: The layered-type structure of 1 can be regarded as constructed from the tetranuclear copper units double bridged by one of the two unique thiocyanate and admtrz ligands to form a two-dimensional layered structure along the a and b directions.
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Mixed-valence Cu(II)/Cu(I) complex of quinolone ciprofloxacin isolated by a hydrothermal reaction in the presence of L-histidine: comparison of biological activities of various copper-ciprofloxacin compounds.
Petra Drevenšek,Tatjana Zupančič,Boris Pihlar,Roman Jerala,Uwe Kolitsch,Andreja Plaper,Iztok Turel +6 more
TL;DR: The DNA gyrase inhibition tests and antibacterial activity tests have shown that the effect of copper complexes is comparable to that of free quinolone.
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Biosynthetic inorganic chemistry.
TL;DR: This review summarizes the progress in the synthesis of close models of complex metalloproteins, followed by a description of recent advances in using the approach for making novel compounds that are unprecedented in either inorganic chemistry or biology.
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The first self-penetrating topology based on an unusual α-Po net with double edges constructed from a 12-connected Gd2(μ2-Ocarboxylate)2(μ2-OH2)2(μ3-OH)2Cu2 core
TL;DR: In this paper, the first self-penetrating topology based on an unusual α-Po net with double edges self-assembled from a 12-connected Gd2(μ2-Ocarboxylate) 2(μ 2-OH2)2 (μ 3-OH)2Cu2 core was obtained hydrothermally by the reaction of isonicotinic acid (HIN), Gd 2O3, and CuCl2 in the presence of HClO4, (NH4)HCOO.
References
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Study of the relation between the structural data and magnetic interaction in oxo-bridged binuclear copper(II) compounds
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Binuclear complexes of macrocyclic ligands: electrochemical and spectral properties of homobinuclear Cu/sup II/Cu/sup II/, Cu/sup II/Cu/sup I/, and Cu/sup I/Cu/sup I/ species including an estimated intramolecular electron transfer rate
TL;DR: In this paper, the electron transfer properties of a binuclear copper macrocyclic ligand complex and its reduced derivatives were investigated using a quasi-reversible, one-electron process.
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Structure, properties, and function of a copper(I)-copper(II) complex of D-penicillamine: pentathallium(I) .mu.8-chloro-dodeca(D-penicillaminato)octacuprate(I)hexacuprate(II) n-hydrate
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Absorption Spectra of Co(III) Complexes. II. Redetermination of the Spectrochemical Series
Yoichi Shimura,Ryutaro Tsuchida +1 more
TL;DR: The visible and ultra-violet absorption spectra of many cobaltic ammine, oxalato, carbonato and amino-acido complexes have been determined in solution.
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Solid-state structure and electronic properties of a mixed-valence two-dimensional metal, potassium copper sulfide (KCu4S3)
David B. Brown,Jon Zubieta,P. A. Vella,James T. Wrobleski,Timothy Watt,William E. Hatfield,Peter Day +6 more
TL;DR: In this paper, a two-dimensional mixed-valence Cu(I,I, I,II) complex with a unique layered structure is described, where double layers of tetrahedrally -coordinated (by S) copper ions are separated by layers of potassium ions.