Journal ArticleDOI
Novel Vanadium-Catalyzed Oxidation of Alcohols to Aldehydes and Ketones under Atmospheric Oxygen
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TLDR
Oxidation of alcohols to aldehydes and ketones has been studied in high yields using atmospheric oxygen and a catalytic amount of V2O5 in toluene under heating.About:
This article is published in Organic Letters.The article was published on 2004-01-22. It has received 179 citations till now. The article focuses on the topics: Alcohol oxidation & Catalysis.read more
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3d Transition Metals for C-H Activation.
Parthasarathy Gandeepan,Thomas Müller,Daniel Zell,Gianpiero Cera,Svenja Warratz,Lutz Ackermann +5 more
TL;DR: A comprehensive overview on first row transition metal catalysts for C-H activation until summer 2018 is provided.
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V2O5 Nanowires with an Intrinsic Peroxidase-Like Activity
Rute André,Filipe Natalio,Madalena Humanes,Jana Leppin,Katja Heinze,Ron Wever,Heinz-Christoph Schröder,Werner E. G. Müller,Wolfgang Tremel +8 more
TL;DR: In this paper, the V2O5 nanowires have been shown to exhibit an intrinsic catalytic activity towards classical peroxidase substrates such as 2,2-azino-bis (ABTS) and 3,3,5,5,-tetramethylbenzdine (TMB) in the presence of H2O2.
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Transition metal based catalysts in the aerobic oxidation of alcohols
TL;DR: In this article, the authors give an overview on the most important advances made by the scientific community in the last 15 years in the field of aerobic oxidations of alcohols catalyzed by transition metals in the form of homogeneous catalysts and, more recently, nanoparticles.
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Visible-Light-Induced Aerobic Oxidation of Alcohols in a Coupled Photocatalytic System of Dye-Sensitized TiO2 and TEMPO
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Creation of a Monomeric Ru Species on the Surface of Hydroxyapatite as an Efficient Heterogeneous Catalyst for Aerobic Alcohol Oxidation
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Efficient, Catalytic, Aerobic Oxidation of Alcohols with Octahedral Molecular Sieves
TL;DR: Mixed-valent manganese octahedral molecular sieves K-OMs-2 and H-K-OMS-2 are used to oxidize a wide range of alcohols with 100 % selectivity and 90-100% conversion in most cases.
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Efficient ruthenium-catalyzed aerobic oxidation of alcohols using a biomimetic coupled catalytic system.
TL;DR: Most alcohols are oxidized to ketones in high yield and selectivity within 1-2 h, and the catalytic system tolerates a wide range of O(2) concentrations without being deactivated.
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The First Example of Activation of Molecular Oxygen by Nickel in Ni‐Al Hydrotalcite: A Novel Protocol for the Selective Oxidation of Alcohols
TL;DR: NiO in association with aluminum oxide has been identified by temperature-programmed reduction as the active species in the Ni-Al hydrotalcite catalyst that oxidizes α-ketols as well as benzylic and allylic alcohols to their corresponding carbonyl compounds in oxygen in quantitative yields under mild reaction conditions as mentioned in this paper.
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Efficient Oxidation of Alcohols to Carbonyl Compounds with Molecular Oxygen Catalyzed by N-Hydroxyphthalimide Combined with a Co Species
TL;DR: Highly efficient catalytic oxidation of alcohols with molecular oxygen by N-hydroxyphthalimide (NHPI) combined with a Co species was developed and 2-octanol in the presence of catalytic amounts of NHPI and Co(OAc)2 under atmospheric dioxygen in AcOEt at 70 degrees C gave 2- Octanol in 93% yield.