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Pervaporative desulfurization of gasoline: A review

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TLDR
In this paper, the authors provide an overview of the state-of-the-art research activities related to pervaporative desulfurization of gasoline using organic polymeric membranes.
Abstract
The membrane based pervaporation process for sulfur removal from gasoline has evoked a great deal of attention due to its distinct advantages. Such advantages include: lower operating and energy costs, easier scale-up, as well as higher selectivity. The separation mechanism of pervaporative desulfurization is based on the sorption and diffusion differences between the components of the gasoline mixture. This review aims to provide insight into the state of the art research activities related to pervaporative desulfurization of gasoline using organic polymeric membranes. To obtain a comprehensive perspective about the pervaporative desulfurization, other techniques of desulfurization are discussed briefly in the introduction. The solubility parameter theory for membranes selection and the membranes material modifications are also examined in this review. The effects of various factors including feed sulfur content, operating temperature, permeate pressure and feed flow rate on desulfurization performance are discussed.

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Citations
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Journal ArticleDOI

Review on recent advances in adsorptive desulfurization

TL;DR: In this article, a review of the latest development in ADS is presented, where Zeolite, metal oxide, metal-organic framework, mesoporous material, and carbon are assessed for desulfurization of the model and real feedstocks.
Journal ArticleDOI

Polymeric Nanocomposite Membranes for Next Generation Pervaporation Process: Strategies, Challenges and Future Prospects.

TL;DR: This article evaluates and collaborates the current research towards the development of next generation nanomaterials (NMs) and embedded polymeric membranes with regard to its synthesis, fabrication and application strategies, challenges and future prospects.
Journal ArticleDOI

Deep eutectic solvents based highly efficient extractive desulfurization of fuels – Eco-friendly approach

TL;DR: In this article, several deep eutectic solvents (DESs) were successfully synthesized and studied as extraction solvent for desulfurization of model fuel containing thiophene, benzothiophene (BT), and dibenzothiophenes (DBT).
Journal ArticleDOI

Biodegradable choline-like deep eutectic solvents for extractive desulfurization of fuel

TL;DR: In this article, several choline-like DESs are synthetized and characterized by 1H NMR, FTIR, UV-vis, Raman and ESI-MS.
Journal ArticleDOI

Embedding Ag+@COFs within Pebax membrane to confer mass transport channels and facilitated transport sites for elevated desulfurization performance

TL;DR: In this paper, covalent organic frameworks (COFs) are utilized as carriers to immobilize metal ions in facilitated transport membranes for organic solvent separation for the first time, which greatly intensified the mass transfer of unsaturated penetrant molecules (thiophene) by π-complexation.
References
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Journal ArticleDOI

Applications of ionic liquids in the chemical industry

TL;DR: There have been parallel and collaborative exchanges between academic research and industrial developments since the materials were first reported in 1914, it is demonstrated.
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An overview of new approaches to deep desulfurization for ultra-clean gasoline, diesel fuel and jet fuel

TL;DR: In this article, the authors discuss the problems of sulfur reduction in highway and non-road fuels and present an overview of new approaches and emerging technologies for ultra-deep desulfurization of refinery streams for ultra clean (ultra-low-sulfur) gasoline, diesel fuels and jet fuels.
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Science and technology of novel processes for deep desulfurization of oil refinery streams: a review☆ ☆

TL;DR: In this article, the applicability and perspectives of various desulfurization technologies are evaluated taking into account the requirements of the produced fuels, and the progress achieved during recent years in catalysis-based HDS technologies (synthesis of improved catalysts, advanced reactor design, combination of distillation and HDS) and in non-HDS processes of sulfur removal (alkylation, extraction, precipitation, oxidation, and adsorption) is illustrated through a number of examples.
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New design approaches to ultra-clean diesel fuels by deep desulfurization and deep dearomatization

TL;DR: In this paper, a selective review on design approaches and associated catalysis and chemistry for deep desulfurization and deep dearomatization (hydrogenation) of hydrocarbon fuels, particularly diesel fuels, is presented.
Journal ArticleDOI

Liquid Separation by Membrane Pervaporation: A Review

TL;DR: Pervaporation is one of the most active areas in membrane research, and the pervaporation process has been shown to be an indispensable component for chemical separations.
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