Journal ArticleDOI
Porous and nonporous nanocapsules by H-bonding self-assembly
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TLDR
On the basis of hydrogen bonding, poly(vinylpyrrolidone) and poly(methacrylic acid) were layer-by-layer deposited on the surface of the AgCl microcrystals or SiO2 colloidal particles in aqueous solution to construct core−shell structure particles as discussed by the authors.Abstract:
On the basis of hydrogen bonding, poly(vinylpyrrolidone) and poly(methacrylic acid) were layer-by-layer deposited on the surface of the AgCl microcrystals or SiO2 colloidal particles in aqueous solution to construct core−shell structure particles. When the AgCl and SiO2 cores were removed, the porous and nonporous nanocapsules were obtained, respectively. After the nonporous capsules were incubated in a KSCN and HNO3 mixture solution for 24 h, the capsules shrank and the pores were formed in the shell of the capsules.read more
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Layer‐by‐Layer Hydrogen‐Bonded Polymer Films: From Fundamentals to Applications
TL;DR: In this article, the authors discuss the recent developments in the synthesis of layer-by-layer (LbL) materials based on hydrogen-bonded (HB) assembly, the study of their structure-property relationships, and the prospective applications of HB LbL constructs in biotechnology and biomedicine.
Journal ArticleDOI
Disulfide cross-linked polymer capsules: en route to biodeconstructible systems.
TL;DR: Hydrogen-bonded multilayer thin films were constructed using poly(vinylpyrrolidone) and poly(methacrylic acid) functionalized with cysteamine that included thiol moieties that were cross-linked to render the films stable at physiological pH.
Journal ArticleDOI
Disulfide-Stabilized Poly(methacrylic acid) Capsules: Formation, Cross-Linking, and Degradation Behavior
TL;DR: It is demonstrated that the capsules undergo reversible swelling in response to changes in external pH, and degrade in the presence of a physiological concentration of a natural thiol-containing peptide, glutathione.
Journal ArticleDOI
Hollow polymeric nanostructures—Synthesis, morphology and function
TL;DR: In this article, the development of reliable synthetic routes to polymeric nanostructures of well-defined composition, morphology and function is of scientific importance and technological interest, which can be achieved through direct and template-directed synthesis, core-shell precursors, and selfassembly of copolymers and polymer conjugates, as well as from dendrimers.
Journal ArticleDOI
Hydrogen-bonded interpolymer complexes as materials for pharmaceutical applications.
TL;DR: This review is an attempt to analyse and systematise existing literature on pharmaceutical application of hydrogen-bonded interpolymer complexes.
References
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Nanoengineering of Inorganic and Hybrid Hollow Spheres by Colloidal Templating
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Buildup of ultrathin multilayer films by a self-assembly process: III. Consecutively alternating adsorption of anionic and cationic polyelectrolytes on charged surfaces
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Journal ArticleDOI
Novel Hollow Polymer Shells by Colloid-Templated Assembly of Polyelectrolytes
TL;DR: Possible areas of application for polyelectrolyte shells range from the pharmaceutical, food, cosmetic, and paint industries to catalysis and microcrystallization.
Journal ArticleDOI
Hollow capsule processing through colloidal templating and self-assembly
TL;DR: This article focuses on a recent novel and versatile technique, based on a combination of colloidal templating and self-assembly processes, developed for synthesizing uniform hollow capsules of a broad range of materials.
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