Journal ArticleDOI
Porous, Crystalline, Covalent Organic Frameworks
Adrien P. Côté,Annabelle I. Benin,Nathan W. Ockwig,Michael O'Keeffe,Adam J. Matzger,Omar M. Yaghi +5 more
TLDR
Covalent organic frameworks (COFs) have been designed and successfully synthesized by condensation reactions of phenyl diboronic acid and hexahydroxytriphenylene to form rigid porous architectures with pore sizes ranging from 7 to 27 angstroms.Abstract:
Covalent organic frameworks (COFs) have been designed and successfully synthesized by condensation reactions of phenyl diboronic acid {C6H4[B(OH)2]2} and hexahydroxytriphenylene [C18H6(OH)6]. Powder x-ray diffraction studies of the highly crystalline products (C3H2BO)6.(C9H12)1 (COF-1) and C9H4BO2 (COF-5) revealed expanded porous graphitic layers that are either staggered (COF-1, P6(3)/mmc) or eclipsed (COF-5, P6/mmm). Their crystal structures are entirely held by strong bonds between B, C, and O atoms to form rigid porous architectures with pore sizes ranging from 7 to 27 angstroms. COF-1 and COF-5 exhibit high thermal stability (to temperatures up to 500 degrees to 600 degrees C), permanent porosity, and high surface areas (711 and 1590 square meters per gram, respectively).read more
Citations
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Journal ArticleDOI
Engineering Metal Organic Frameworks for Heterogeneous Catalysis
TL;DR: In conclusion, MOFs as Host Matrices or Nanometric Reaction Cavities should not be considered as a source of concern in the determination of MOFs’ properties in relation to other materials.
Journal ArticleDOI
Covalent organic frameworks (COFs): from design to applications
San-Yuan Ding,Wei Wang +1 more
TL;DR: This critical review describes the state-of-the-art development in the design, synthesis, characterisation, and application of the crystalline porous COF materials.
Journal ArticleDOI
Covalent organic frameworks
TL;DR: This tutorial review describes the basic design concepts, the recent synthetic advancements and structural studies, and the frontiers of functional exploration of covalent organic frameworks.
Journal ArticleDOI
Storage of Hydrogen, Methane, and Carbon Dioxide in Highly Porous Covalent Organic Frameworks for Clean Energy Applications
Hiroyasu Furukawa,Omar M. Yaghi +1 more
TL;DR: Findings place COFs among the most porous and the best adsorbents for hydrogen, methane, and carbon dioxide.
References
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