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Journal ArticleDOI

Principles and procedures for determining absolute differential electron-molecule (atom) scattering cross sections

J C Nickel, +3 more
- 01 Sep 1989 - 
- Vol. 22, Iss: 9, pp 730-738
TLDR
In this article, the absolute elastic and inelastic differential cross sections (DCS) for electron impact on molecular (atomic) species are described and illustrated by examples, and a method of determining absolute differential electron-molecule scattering cross sections is generally applicable and provides reliable results.
Abstract
Procedures and calibration techniques for measuring the absolute elastic and inelastic differential cross sections (DCS) for electron impact on molecular (atomic) species are described and illustrated by examples. The elastic DCS for the molecule under study is first determined by calibration against helium using the relative flow technique. The second step involves the production of energy-loss spectra for the instrument response function, the unfolding of overlapping inelastic structures and the normalization of inelastic intensities to the elastic cross sections. It is concluded that this method of determining absolute differential electron-molecule (atom) scattering cross sections is generally applicable and provides reliable results.

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Citations
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Journal ArticleDOI

Near-threshold electron-impact excitation of argon studied with the time-of-flight technique

TL;DR: In this paper, absolute angle-differential cross-section data are presented for excitation of the 3p54s manifold in argon by electron impact, where the time-of-flight (TOF) technique is employed.
Journal ArticleDOI

A novel approach to unfold the heavily overlapped spectrum of a diatomic molecule: Monte Carlo random walk routine

TL;DR: In this article, a novel procedure to unfold the heavily overlapped valence-shell excitation spectrum of a diatomic molecule has been established, which repeatedly changes the fitting parameter values by Monte Carlo random walk, which can increase the probability of hunting the global minimum variance.
Journal ArticleDOI

Total cross section measurements for electron scattering from dichloromethane

TL;DR: Within their respective uncertainties, the present TCS and those of Karwasz et al. are found to be in very good agreement over their common energy range, however, agreement with the results of Wan etAl.
References
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Book

Data Reduction and Error Analysis for the Physical Sciences

TL;DR: In this paper, Monte Carlo techniques are used to fit dependent and independent variables least squares fit to a polynomial least-squares fit to an arbitrary function fitting composite peaks direct application of the maximum likelihood.
Journal ArticleDOI

Data Reduction and Error Analysis for the Physical Sciences.

TL;DR: Numerical methods matrices graphs and tables histograms and graphs computer routines in Pascal and Monte Carlo techniques dependent and independent variables least-squares fit to a polynomial least-square fit to an arbitrary function fitting composite peaks direct application of the maximum likelihood.
Journal ArticleDOI

The Threshold Law for Single Ionization of Atoms or Ions by Electrons

TL;DR: In this paper, the dependence of the yield on the energy just above a threshold is derived and the derivation is not rigorous because it circumvents some of the difficulties of the three-body problem by applying ergodicity, albeit in a weakened form.
Journal ArticleDOI

Two electrons in a coulomb potential. double-continuum wave functions and threshold law for electron--atom ionization.

TL;DR: In this paper, the Schrodinger equation for two electrons in a Coulomb field is studied in the critical region where both electrons have near-zero kinetic energies, and the main feature of this problem is that the mutual screening between the two electrons determines and is determined by the partition of the available energy between them.
Journal ArticleDOI

Absolute elastic differential electron scattering cross sections for He - A proposed calibration standard from 5 to 200 eV

TL;DR: In this article, the angular distributions for elastically scattered electrons were measured in a crossed-beam geometry using a collimated, differentially pumped atomic-beam source which requires no effective-path-length correction.
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