Journal ArticleDOI
Pseudocapacitive Contributions to Charge Storage in Highly Ordered Mesoporous Group V Transition Metal Oxides with Iso-Oriented Layered Nanocrystalline Domains
Kirstin Brezesinski,John Wang,Jan Haetge,Christian Reitz,Sven O. Steinmueller,Sarah H. Tolbert,Bernd M. Smarsly,Bruce Dunn,Torsten Brezesinski +8 more
TLDR
It is demonstrated that these group V transition metal oxides can be readily produced with a high degree of crystallographic alignment on virtually any substrate in contrast to classical solution-phase epitaxy which requires the use of a single-crystalline substrate to achieve oriented crystal growth.Abstract:
Amphiphilic block copolymers are very attractive as templates to produce inorganic architectures with nanoscale periodicity because of their ability to form soft superstructures and to interact with inorganic materials. In this paper, we report the synthesis and electrochemical properties of highly ordered mesoporous T-Nb2O5, L-Ta2O5, and TaNbO5 solid solution thin films with iso-oriented layered nanocrystalline domains. These oxide materials were fabricated by coassembly of inorganic sol−gel reagents with a poly(ethylene-co-butylene)-b-poly(ethylene oxide) diblock copolymer, referred to as KLE. We establish that all materials employed here are highly crystalline and have an ordered cubic pore-solid architecture after thermal treatment. We also demonstrate that these group V transition metal oxides can be readily produced with a high degree of crystallographic alignment on virtually any substrate in contrast to classical solution-phase epitaxy which requires the use of a single-crystalline substrate to ac...read more
Citations
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Journal ArticleDOI
Pseudocapacitive oxide materials for high-rate electrochemical energy storage
TL;DR: In this article, the pseudocapacitance properties of transition metal oxides have been investigated and a review of the most relevant pseudo-capacitive materials in aqueous and non-aqueous electrolytes is presented.
Journal ArticleDOI
High-rate electrochemical energy storage through Li+ intercalation pseudocapacitance
Veronica Augustyn,Jeremy Come,Jeremy Come,Michael A. Lowe,J. W. Kim,Pierre-Louis Taberna,Pierre-Louis Taberna,Sarah H. Tolbert,Héctor D. Abruña,Patrice Simon,Patrice Simon,Bruce Dunn +11 more
TL;DR: This work quantifies the kinetics of charge storage in T-Nb2O5: currents that vary inversely with time, charge-storage capacity that is mostly independent of rate, and redox peaks that exhibit small voltage offsets even at high rates.
Journal ArticleDOI
Electrochemical capacitors: mechanism, materials, systems, characterization and applications
TL;DR: The latest progress in supercapacitors in charge storage mechanisms, electrode materials, electrolyte materials, systems, characterization methods, and applications are reviewed and the newly developed charge storage mechanism for intercalative pseudocapacitive behaviour is clarified for comparison.
Journal ArticleDOI
Nitrogen-doped mesoporous carbon of extraordinary capacitance for electrochemical energy storage
Tianquan Lin,I-Wei Chen,Fengxin Liu,Chongyin Yang,Hui Bi,Fangfang Xu,Fuqiang Huang,Fuqiang Huang +7 more
TL;DR: It is found that a nitrogen-doped ordered mesoporous few-layer carbon has a capacitance of 855 farads per gram in aqueous electrolytes and can be bipolarly charged or discharged at a fast, carbon-like speed and can store a specific energy of 41 watt-hours per kilogram (19.5 watt- hours per liter).
Journal ArticleDOI
Oxygen vacancies enhance pseudocapacitive charge storage properties of MoO3-x.
Hyung-Seok Kim,John B. Cook,John B. Cook,Hao Lin,Jesse S. Ko,Sarah H. Tolbert,Sarah H. Tolbert,Vidvuds Ozolins,Bruce Dunn,Bruce Dunn +9 more
TL;DR: This study underscores the potential importance of incorporating oxygen vacancies into transition metal oxides as a strategy for increasing the charge storage kinetics of redox-active materials.
References
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Journal ArticleDOI
Issues and challenges facing rechargeable lithium batteries
TL;DR: A brief historical review of the development of lithium-based rechargeable batteries is presented, ongoing research strategies are highlighted, and the challenges that remain regarding the synthesis, characterization, electrochemical performance and safety of these systems are discussed.
Journal ArticleDOI
A new family of mesoporous molecular sieves prepared with liquid crystal templates
Jeffrey S. Beck,James C. Vartuli,Wieslaw J. Roth,M. E. Leonowicz,Charles T. Kresge,Kirk D. Schmitt,Cynthia Ting-Wah Chu,David H. Olson,E. W. Sheppard,S. B. McCullen,J. B. Higgins,J.L. Schlenker +11 more
TL;DR: In this paper, the synthesis, characterization, and proposed mechanism of formation of a new family of silicatelaluminosilicate mesoporous molecular sieves designated as M41S is described.
Journal ArticleDOI
First-principles simulation: ideas, illustrations and the CASTEP code
Matthew D. Segall,Philip J. D. Lindan,Matt Probert,Chris J. Pickard,P. J. Hasnip,Stewart J. Clark,Mike C. Payne +6 more
TL;DR: The basics of the suject are looked at, a brief review of the theory is given, examining the strengths and weaknesses of its implementation, and some of the ways simulators approach problems are illustrated through a small case study.
Journal ArticleDOI
Nanostructured materials for advanced energy conversion and storage devices
Antonino S. Aricò,Peter G. Bruce,Bruno Scrosati,Jean-Marie Tarascon,Jean-Marie Tarascon,Walter van Schalkwijk +5 more
TL;DR: This review describes some recent developments in the discovery of nanoelectrolytes and nanoeLECTrodes for lithium batteries, fuel cells and supercapacitors and the advantages and disadvantages of the nanoscale in materials design for such devices.
Journal ArticleDOI
What Are Batteries, Fuel Cells, and Supercapacitors?
Martin Winter,Ralph J. Brodd +1 more
TL;DR: Batteries, fuel cells and supercapacitors belong to the same family of energy conversion devices and are needed to service the wide energy requirements of various devices and systems.