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Journal ArticleDOI

Self-assembling ferroelectric Na0.5K0.5NbO3 thin films by pulsed-laser deposition

C. R. Cho, +1 more
- 06 Jul 1999 - 
- Vol. 75, Iss: 2, pp 268-270
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TLDR
In this article, single-phase Na0.5K 0.5NbO3 (NKN) thin films have been grown on polycrystalline Pt80Ir20 (Pt) and SiO2 (native oxide)/Si (111) substrates using KrF excimer laser ablation of a stoichiometric ceramic target.
Abstract
Highly [100]-axis oriented single-phase Na0.5K0.5NbO3 (NKN) thin films have been grown on polycrystalline Pt80Ir20 (Pt) and SiO2 (native oxide)/Si (111) substrates using KrF excimer laser ablation of a stoichiometric ceramic target. X-ray diffraction θ–2θ scan and rocking curve data are evidence of the strong effect of film self-assembling along the [100] direction regardless of the substrate texture. Furthermore, multiple-cell structuring along the polar axis has been observed in NKN films grown onto the Pt substrate. Ferroelectric measurements yield remnant polarization Pr of 10 μC/cm2 and spontaneous polarization Ps of 17.5 μC/cm2 at 80 kV/cm. The electrical resistivity of the Na0.5K0.5NbO3 film was in the order of 1010 Ω cm at 10 kV/cm. Dielectric permittivity e′ and dissipation factor tan δ have been found to vary 480–440 and 0.028–0.024, respectively, in the frequency range 0.4–100 kHz.

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Citations
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Journal ArticleDOI

Perspective on the Development of Lead-free Piezoceramics

TL;DR: In this paper, general guidelines for the development of lead-free piezoelectric ceramics are presented, ranging from atom to phase diagram, and the current development stage in lead free piezoceramics is then critically assessed.
Journal ArticleDOI

Do we really need ferroelectrics in paraelectric phase only in electrically controlled microwave devices

TL;DR: In this article, the possibilities and benefits of using ferroelectrics in polar phase in electrically controllable microwave devices are considered explicitly for the first time, and the authors consider the use of ceramic (bulk and thick film) ferro-electrics for industrial applications.
Journal ArticleDOI

Fabrication and ferroelectric properties of highly dense lead-free piezoelectric (K0.5Na0.5)NbO3 thick films by aerosol deposition

TL;DR: In this article, a lead-free piezoelectric thin/thick film was fabricated by aerosol-deposition method and the thickness of KNN film was 7.1μm and fully dense films were obtained.
Journal ArticleDOI

Background oxygen effects on pulsed laser deposited Na0.5K0.5NbO3 films: From superparaelectric state to ferroelectricity

TL;DR: In this article, the compositional, crystalline, and electrical properties of Na05K05NbO3 (NKN) thin films grown onto polycrystalline Pt80Ir20 and SiO2 (native oxide)/Si(111) substrates were found to be single phase and highly c-axis oriented X-ray diffraction θ-2θ scans and rocking curve data show a strong effect of NKN film self-assembling along the [001] direction regardless of the substrate texture.
Journal ArticleDOI

Lead-Free Piezoelectric (K,Na)NbO3 Thin Films Derived from Metal Alkoxide Precursors

TL;DR: In this article, a lead-free piezoelectric K0.5NbO3 (KNN) single-phase thin film with good leakage current properties was successfully prepared by optimizing the KxNaxNbOn3 (x0.55Nb On3) composition of the precursor solution.
References
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Journal ArticleDOI

Piezoelectric and Dielectric Properties of Ceramics in the System Potassium—Sodium Niobate

TL;DR: In this article, high radial coupling coefficients were observed for compositions having up to 50 mole % sodium niobate additions to potassium Niobate, and the activity diminishes with additional sodium Niobates content and disappears beyond about 98 mole % additions.
Journal ArticleDOI

Dielectric Properties and Phase Transitions of NaNb O 3 and (Na,K)Nb O 3

TL;DR: In this paper, an optical, dielectric, and structural study has been carried out on NaNb${\mathrm{O}}_{3}$ and the solid solution (Na,K)Nb€{O}$, both single crystals and ceramics being used.
Journal ArticleDOI

Growth of poly- and single-crystal ScN on MgO(001): Role of low-energy N2+ irradiation in determining texture, microstructure evolution, and mechanical properties

TL;DR: In this article, the N 2 to Sc ratio incident at the substrate and growing film was maintained constant at 14, while the ion energy EN2+ was varied from 13 to 50 eV.
Journal ArticleDOI

Effects of high‐flux low‐energy (20–100 eV) ion irradiation during deposition on the microstructure and preferred orientation of Ti0.5Al0.5N alloys grown by ultra‐high‐vacuum reactive magnetron sputtering

TL;DR: In this paper, the effects of incident ion/metal flux ratio Ji/JMe and ion energy Ei on the microstructure, texture, and phase composition of polycrystalline metastable Ti0.5Al 0.5N films produced by reactive magnetron sputtering were investigated using x-ray diffraction (XRD), plan-view and cross-sectional transmission electron microscopy, and Rutherford backscattering spectroscopy.
Journal ArticleDOI

Cu0, Cu+, and Cu2 from excimer‐ablated copper

TL;DR: In this paper, the transition from the thermal to the plasma etch region is studied by measuring the densities and kinetic energies of three copper species (Cu0, Cu+, and Cu2 ) in the etch plume.
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