scispace - formally typeset
Open AccessJournal ArticleDOI

Self-propelled motion of a fluid droplet under chemical reaction.

Shunsuke Yabunaka, +2 more
- 21 Feb 2012 - 
- Vol. 136, Iss: 7, pp 074904-074904
Reads0
Chats0
TLDR
There is a bifurcation from a motionless state to a propagating state of droplet by changing the strength of the Marangoni effect.
Abstract
We study self-propelled dynamics of a droplet due to a Marangoni effect and chemical reactions in a binary fluid with a dilute third component of chemical product which affects the interfacial energy of a droplet. The equation for the migration velocity of the center of mass of a droplet is derived in the limit of an infinitesimally thin interface. We found that there is a bifurcation from a motionless state to a propagating state of droplet by changing the strength of the Marangoni effect.

read more

Content maybe subject to copyright    Report

Citations
More filters
Journal ArticleDOI

Self-propulsion of pure water droplets by spontaneous Marangoni-stress-driven motion.

TL;DR: Experiments with a highly concentrated solution of salt instead of water, and tetradecane instead of squalane, confirm the above mechanism, and the present swimming droplets are able to carry external bodies such as large colloids, salt crystals, and even cells.
Journal ArticleDOI

Physics of active emulsions

TL;DR: The physics of phase separation and emulsions are discussed and it is shown how the concepts that govern such phenomena can be extended to capture the physics of active emulsion.
Journal ArticleDOI

Perspective: Nanomotors without moving parts that propel themselves in solution

TL;DR: Chemically powered self-propelled nanomotors without moving parts that rely on asymmetric chemical reactions to effect directed motion are the focus of this article.
Journal ArticleDOI

Marangoni flow at droplet interfaces: Three-dimensional solution and applications

TL;DR: In this article, the full 3D Marangoni flow generated by a non-uniform surface tension profile at the interface of a self-propelled spherical emulsion droplet is derived.
Journal ArticleDOI

Self-propelled motion switching in nematic liquid crystal droplets in aqueous surfactant solutions.

TL;DR: In a thin cell whose thickness is smaller than that of the initial droplet size, the droplets show more complex trajectories, including "figure-8s" and zigzags, which are attributed to autochemotaxis of the droplet.
References
More filters
Journal ArticleDOI

Diffuse-interface methods in fluid mechanics

TL;DR: Issues including sharp-interface analyses that relate these models to the classical free-boundary problem, computational approaches to describe interfacial phenomena, and models of fully miscible fluids are addressed.
Journal ArticleDOI

The motion of bubbles in a vertical temperature gradient

TL;DR: In this article, it has been demonstrated that small bubbles in pure liquids can be held stationary or driven downwards by means of a sufficiently strong negative temperature gradient in the vertical direction, due to the stresses resulting from the thermal variation of surface tension at the bubble surface.
Journal ArticleDOI

Swarming behavior of simple model squirmers

TL;DR: In this paper, the collective behavior of self-propelling liquid droplets, which closely mimic the locomotion of some protozoal organisms, the so-called squirmers, was studied experimentally.
Journal ArticleDOI

Self-Propelled Oil Droplets Consuming Fuel Surfactant

TL;DR: A micrometer-sized oil droplet of 4-octylaniline containing 5 mol % of an amphiphilic catalyst exhibited a self-propelled motion, producing tiny oil droplets, in an aqueous dispersion of an Amphiphilic precursor of4-oct Dylaniline.
Journal ArticleDOI

Coarse‐grained description of thermo‐capillary flow

TL;DR: In this paper, an order parameter representation of a two-phase binary fluid is used in which the interfacial region separating the phases naturally occupies a transition zone of small width, and a modified Navier-Stokes equation that incorporates an explicit coupling to the order parameter field governs fluid flow.
Related Papers (5)
Frequently Asked Questions (15)
Q1. What is the force arising from the first, second, and third terms?

The force arising from the first, second, and third terms can be written asf α = −∇αp − φ∇α δF δφ − c∇α δF δc = −∇αp′′ + f α‖ + f α⊥ ,(5)where p′′ has some additive terms to p, whose explicit form is unnecessary for incompressible fluids since only the transverse components of the velocity is relevant. 

The Stokes approximation is employed for the local velocity v and it takes the form0 = − ∇p − φ ∇ δF δφ − c ∇ δF δc + η0∇2 v, (4)where p is determined such that the velocity field satisfies the incompressibility condition ∇ · v = 0. 

when the relaxation rate is finite, the droplet tends to shift further since the interfacial energy is an increasing function of c. 

Since the first order correction to the concentration c is given by c( r) = −[−D∇2 + γ ]−1H ( r) and the operator [− D∇2 + γ ]−1 is positive definite, the concentration c tends to increase (decrease) at the front (rear). 

Since the interface velocity is arbitrarily small in the vicinity of the drift bifurcation threshold, the second assumption is consistently justified in the theory. 

if the time-delayed effect τuα dominates the term −uα which corresponds to the Stokes drag force, the droplet undergoes migration. 

The first order correction from the convective term gives us P = 31/56 as shown in Appendix D. Since migration of droplet occurs for τ ≥ 1, this indicates that the stronger Marangoni effect is necessary when the convection of the third component exists. 

In this experiment, the molecules which constitute the droplet are produced by a chemical reaction which takes place at the droplet surface. 

Phys. 136, 074904 (2012)that the concentration variation is φ(x) = φe > 0 inside the droplet and φ(x) = −φe at the surrounding matrix. 

21 The second term in Eq. (3) indicates consumption of c with the rate γ > 0 due to a chemical reaction and with c = c∞ for | r| → ∞ whereas the last term represents production of c, which occurs inside a droplet with radius R, whose center of mass is located at rG. 

This work was supported by the JSPS Core-to-Core Program “International research network for non-equilibrium dynamics of soft matter” and the Grant-in-Aid for the Global COE Program “The Next Generation of Physics, Spun from Universality and Emergence” from the Ministry of Education, Culture, Sports, Science and Technology (MEXT) of Japan. 

The authors consider a fluid mixture where the free energy is given in terms of the local concentration difference φ = φA − φB byF {φ} = ∫ d r [ B(c)2 ( ∇φ)2 + fGL(φ) + f0(c)] , (1)where φA(φB) is the local concentration of the component A (B) and f0(c) = cln c. 

The dimensionless coefficients depend only on R̂ = Rβ and are given bym̂(R̂) = mDβ2τc, (48)τ̂ (R̂) = ττc, (49)ĝ(R̂) = g(Dβ)2τc. (50) These scaled coefficients have been evaluated numerically and plotted in Figs. 

From the left-hand side of Eq. (2), the authors note that the normal component V(a, t) of the interface velocity is given byV (a, t) = vα( r(a), t)nα(a). 

(21) Equations (20) and (21) are manipulated in Appendix B asuα1 = − 8σ1R15 η0∫ da′nα(a′)cI (a′), (22)uα2 = σ1R25 η0∫ da′(δαδ − nα(a′)nδ(a′))(∇δc)I . (23)In Sec. III, the authors will derive the time-evolution equation for u from Eq. (19) with Eqs. (20) and (21) by solving Eq. (3) for the third component c.