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Superior Electrochemical Performance and Storage Mechanism of Na3V2(PO4)3 Cathode for Room-Temperature Sodium-Ion Batteries

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TLDR
The 100 Talent Project of the Chinese Academy of Sciences, Program for New Century Excellent Talents in University [NCET-09-0628], SRF for ROCS, SEM as discussed by the authors.
Abstract
863 Project [2009AA033101]; "973" Projects [2010CB833102]; NSFC [50972164, 51222210]; CAS project [KJCX2-YW-W26]; 100 Talent Project of the Chinese Academy of Sciences, Program for New Century Excellent Talents in University [NCET-09-0628]; SRF for ROCS, SEM

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Citations
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Room-temperature all-solid-state sodium batteries with robust ceramic interface between rigid electrolyte and electrode materials

TL;DR: In this article, the inter-ceramic contact problems are solved by combining the infiltration of a porous electrolyte scaffold by precursor solution with in situ synthesis of electrode active material (chemical infiltration) to fabricate model cells using Na3V2P3O12 (NVP), Na3.4Zr2Si2.6O12 and Na as the positive electrode, electrolyte and negative electrode materials, respectively.
Journal ArticleDOI

Stabilizing fluorine to achieve high-voltage and ultra-stable Na3V2(PO4)2F3 cathode for sodium ion batteries

TL;DR: In this paper, a feasible strategy of stabilizing fluorine is proposed to eliminate the low-voltage plateau in Na3V2(PO4)2F3 cathode, which can effectively guarantee the existence of fluorine and modulate the local electronic structure of V to maintain [VO4F2], thus eliminating the undesirable plateau.
Journal ArticleDOI

Na 3 V 2 (PO 4 ) 3 /C nanocomposite synthesized via pre-reduction process as high-performance cathode material for sodium-ion batteries

TL;DR: In this article, a Na3V2(PO4)3/C nanocomposite was successfully synthesized by a simple pre-reduction and subsequent calcination process.
Journal ArticleDOI

Intercalation pseudocapacitance of FeVO4·nH2O nanowires anode for high-energy and high-power sodium-ion capacitor

TL;DR: In this article, the pseudocapacitive FeVO4·0.6H2O nanowires anode was used to obtain high specific capacity, high initial coulombic efficiency, remarkable rate capability and cycling stability for sodium-ion intercalation.
Journal ArticleDOI

Maricite NaFePO4/C/graphene: a novel hybrid cathode for sodium-ion batteries

TL;DR: In this article, the first time a maricite NaFePO4 nanoparticle entwined graphene sheets capable of delivering an outstanding capacity of 142 mA/h g−1 after 300 cycles, corresponding to ∼98% capacity retention.
References
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Building better batteries

TL;DR: Researchers must find a sustainable way of providing the power their modern lifestyles demand to ensure the continued existence of clean energy sources.
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Challenges for Rechargeable Li Batteries

TL;DR: In this paper, the authors reviewed the challenges for further development of Li rechargeable batteries for electric vehicles and proposed a nonflammable electrolyte with either a larger window between its lowest unoccupied molecular orbital and highest occupied molecular orbital (HOMO) or a constituent that can develop rapidly a solid/ electrolyte-interface (SEI) layer to prevent plating of Li on a carbon anode during a fast charge of the battery.
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Phospho‐olivines as Positive‐Electrode Materials for Rechargeable Lithium Batteries

TL;DR: In this article, the authors showed that a reversible loss in capacity with increasing current density appears to be associated with a diffusion-limited transfer of lithium across the two-phase interface.
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Na-ion batteries, recent advances and present challenges to become low cost energy storage systems

TL;DR: In this paper, a review of Na-ion battery materials is presented, with the aim of providing a wide view of the systems that have already been explored and a starting point for the new research on this battery technology.
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Electrochemical Na Insertion and Solid Electrolyte Interphase for Hard-Carbon Electrodes and Application to Na-Ion Batteries

TL;DR: In this paper, a 3-volt secondary Na-ion battery possessing environmental and cost friendliness, Na+-shuttlecock hard-carbon/NaNi0.5Mn 0.5O2 cell, demonstrates steady cycling performance as next generation secondary batteries and an alternative to Li-ion batteries.
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