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Superior Electrochemical Performance and Storage Mechanism of Na3V2(PO4)3 Cathode for Room-Temperature Sodium-Ion Batteries

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TLDR
The 100 Talent Project of the Chinese Academy of Sciences, Program for New Century Excellent Talents in University [NCET-09-0628], SRF for ROCS, SEM as discussed by the authors.
Abstract
863 Project [2009AA033101]; "973" Projects [2010CB833102]; NSFC [50972164, 51222210]; CAS project [KJCX2-YW-W26]; 100 Talent Project of the Chinese Academy of Sciences, Program for New Century Excellent Talents in University [NCET-09-0628]; SRF for ROCS, SEM

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Citations
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Suppressing H2 evolution by using a hydrogel for reversible Na storage in Na3V2(PO4)3

TL;DR: In this article, the authors reported a low-cost hydrogel electrolyte by adding 3 wt% poly(acrylate sodium) (PAAS) into 1 M Na2SO4 aqueous electrolyte, which achieves a widened electrochemical stability window (ESW) of 2.45 V on stainless steel current collector from 2.12 V in 1 M N 2SO4 anode material, and the H2 evolution potential reached −1.75 V vs. Ag/AgCl on titanium current collector.
Journal ArticleDOI

Boosting rate and cycling performance of K-doped Na3V2(PO4)2F3 cathode for high-energy-density sodium-ion batteries

TL;DR: In this article , the effects of K-doping on the crystal structure, kinetic properties and electrochemical performance of NVPF were investigated, and the results demonstrate that the Na2.90K0.10V2(PO4)3F3 (K 0.10-NVPF) exhibits a high capacity (120.8mm g−1 at 0.1 C), high rate capability (66mm g −1 at 30 C), and excellent cycling performance (a capacity retention of 97.5% at 1 C over 500 cycles).
Journal ArticleDOI

Crystallinity Tuning of Na3V2(PO4)3: Unlocking Sodium Storage Capacity and Inducing Pseudocapacitance Behavior

TL;DR: In this paper , a self-supporting 3D porous NVP materials with different crystallinity are fabricated on carbon foam substrates by a facile electrostatic spray deposition method, and the V5+/V4+ redox couple is effectively activated and the threeelectron reactions are realized in NVP for sodium storage by a proper crystallinity tuning.
References
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Building better batteries

TL;DR: Researchers must find a sustainable way of providing the power their modern lifestyles demand to ensure the continued existence of clean energy sources.
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Challenges for Rechargeable Li Batteries

TL;DR: In this paper, the authors reviewed the challenges for further development of Li rechargeable batteries for electric vehicles and proposed a nonflammable electrolyte with either a larger window between its lowest unoccupied molecular orbital and highest occupied molecular orbital (HOMO) or a constituent that can develop rapidly a solid/ electrolyte-interface (SEI) layer to prevent plating of Li on a carbon anode during a fast charge of the battery.
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Phospho‐olivines as Positive‐Electrode Materials for Rechargeable Lithium Batteries

TL;DR: In this article, the authors showed that a reversible loss in capacity with increasing current density appears to be associated with a diffusion-limited transfer of lithium across the two-phase interface.
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Na-ion batteries, recent advances and present challenges to become low cost energy storage systems

TL;DR: In this paper, a review of Na-ion battery materials is presented, with the aim of providing a wide view of the systems that have already been explored and a starting point for the new research on this battery technology.
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Electrochemical Na Insertion and Solid Electrolyte Interphase for Hard-Carbon Electrodes and Application to Na-Ion Batteries

TL;DR: In this paper, a 3-volt secondary Na-ion battery possessing environmental and cost friendliness, Na+-shuttlecock hard-carbon/NaNi0.5Mn 0.5O2 cell, demonstrates steady cycling performance as next generation secondary batteries and an alternative to Li-ion batteries.
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