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Superior Electrochemical Performance and Storage Mechanism of Na3V2(PO4)3 Cathode for Room-Temperature Sodium-Ion Batteries

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TLDR
The 100 Talent Project of the Chinese Academy of Sciences, Program for New Century Excellent Talents in University [NCET-09-0628], SRF for ROCS, SEM as discussed by the authors.
Abstract
863 Project [2009AA033101]; "973" Projects [2010CB833102]; NSFC [50972164, 51222210]; CAS project [KJCX2-YW-W26]; 100 Talent Project of the Chinese Academy of Sciences, Program for New Century Excellent Talents in University [NCET-09-0628]; SRF for ROCS, SEM

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Citations
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Revealing the atomistic origin of the disorder-enhanced Na-storage performance in NaFePO4 battery cathode

TL;DR: In this article, the degree of disorder in NaFePO4 cathode material was tuned by a mechanochemical route to enhance the performance of Na-ion batteries, achieving an initial capacity of 115 mA/h g−1 at 1'C and an excellent cycling stability of capacity retention of 91.3% after 800 cycles.
Journal ArticleDOI

Mechanistic investigation of ion migration in Na3V2(PO4)2F3 hybrid-ion batteries

TL;DR: An improved solution-based carbothermal reduction methodology makes Na3V2(PO4)2F3 exhibit excellent C-rate and cycling performances, of which the Li-inserted voltage is evaluated by first principles calculations.
Journal ArticleDOI

Interface Concentrated-Confinement Suppressing Cathode Dissolution in Water-in-Salt Electrolyte

TL;DR: In this paper, a susceptible Na3V2(PO4)3 cathode whose time-, cycle-, and state-of-charge-dependent dissolubility was evaluated by multiple electrochemical and chemical methods.
Journal ArticleDOI

Ultrathin MoSe2@N-doped carbon composite nanospheres for stable Na-ion storage.

TL;DR: This work demonstrates the creation of nanospheres composed of Mo-based thin nanosheets (MoS2, MoSe2 and Mo2C) uniform embedded within a N-doped carbon matrix and investigates in detail the electrochemical property in Na ion storage.
Journal ArticleDOI

Ascorbic Acid‐Assisted Synthesis of Mesoporous Sodium Vanadium Phosphate Nanoparticles with Highly sp2‐Coordinated Carbon Coatings as Efficient Cathode Materials for Rechargeable Sodium‐Ion Batteries

TL;DR: In conclusion, mesoporous sodium vanadium phosphate nanoparticles with highly sp(2) -coordinated carbon coatings were successfully synthesized as efficient cathode material for rechargeable sodium-ion batteries by using ascorbic acid as both the reductant and carbon source, followed by calcination at 750 °C in an argon atmosphere.
References
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Journal ArticleDOI

Building better batteries

TL;DR: Researchers must find a sustainable way of providing the power their modern lifestyles demand to ensure the continued existence of clean energy sources.
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Challenges for Rechargeable Li Batteries

TL;DR: In this paper, the authors reviewed the challenges for further development of Li rechargeable batteries for electric vehicles and proposed a nonflammable electrolyte with either a larger window between its lowest unoccupied molecular orbital and highest occupied molecular orbital (HOMO) or a constituent that can develop rapidly a solid/ electrolyte-interface (SEI) layer to prevent plating of Li on a carbon anode during a fast charge of the battery.
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Phospho‐olivines as Positive‐Electrode Materials for Rechargeable Lithium Batteries

TL;DR: In this article, the authors showed that a reversible loss in capacity with increasing current density appears to be associated with a diffusion-limited transfer of lithium across the two-phase interface.
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Na-ion batteries, recent advances and present challenges to become low cost energy storage systems

TL;DR: In this paper, a review of Na-ion battery materials is presented, with the aim of providing a wide view of the systems that have already been explored and a starting point for the new research on this battery technology.
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Electrochemical Na Insertion and Solid Electrolyte Interphase for Hard-Carbon Electrodes and Application to Na-Ion Batteries

TL;DR: In this paper, a 3-volt secondary Na-ion battery possessing environmental and cost friendliness, Na+-shuttlecock hard-carbon/NaNi0.5Mn 0.5O2 cell, demonstrates steady cycling performance as next generation secondary batteries and an alternative to Li-ion batteries.
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