Journal ArticleDOI
Synthesis of cyclic carbonates from epoxides and CO2 catalyzed by potassium halide in the presence of β-cyclodextrin
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TLDR
In this paper, a cycloaddition of CO2 with propylene oxide (PO) to propylene carbonate (PC) catalyzed by potassium halide (KCl, KBr, and KI) in the presence of β-cyclodextrin was studied at various conditions.About:
This article is published in Green Chemistry.The article was published on 2008-12-01. It has received 170 citations till now. The article focuses on the topics: Cycloaddition & Propylene oxide.read more
Citations
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Catalysis for the valorization of exhaust carbon: from CO2 to chemicals, materials, and fuels. technological use of CO2.
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Organic Carbonates as Solvents in Synthesis and Catalysis
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Capture and conversion of CO2 at ambient conditions by a conjugated microporous polymer.
TL;DR: The cobalt-coordinated conjugated microporous polymers can also simultaneously function as heterogeneous catalysts for the reaction of CO2 and propylene oxide at atmospheric pressure and room temperature, wherein the polymers demonstrate better efficiency than a homogeneous salen-cobalt catalyst.
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Sustainable metal-based catalysts for the synthesis of cyclic carbonates containing five-membered rings
TL;DR: The use of sustainable metal-based catalysts for the synthesis of five-membered ring containing cyclic carbonates from epoxides and carbon dioxide is critically reviewed in this article, which is restricted to catalysis by the abundant metals: sodium, potassium, aluminium, calcium, titanium and iron.
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Synthesis of Cyclic Carbonates from Epoxides and Carbon Dioxide by Using Organocatalysts
TL;DR: Available metal-free catalysts for the preparation of cyclic carbonates are described and elaborated concerning the overall sustainability of the process and the required reaction conditions, as well as the activity of the catalysts and their reusability, are compared and evaluated.
References
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Transformation of carbon dioxide.
TL;DR: Reaction Mechanism, Synthesis of Urea and Urethane Derivatives, and Alcohol Homologation 2382 10.1.
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Global challenges and strategies for control, conversion and utilization of CO2 for sustainable development involving energy, catalysis, adsorption and chemical processing
TL;DR: In this paper, the authors proposed to use CO2 for environmentally-benign physical and chemical processing that adds value to the process, using CO2 as an alternate medium or solvent or co-reactant or a combination of them.
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Biomimetic Reactions Catalyzed by Cyclodextrins and Their Derivatives.
Ronald Breslow,Suwei Dong +1 more
TL;DR: This review will cover all the literature on reactions in which cyclodextrins bind substrates and then either catalyze their reactions or mimic a step in an enzymatic catalytic sequence, however, it will not describe work in which Cyclodextrin simply change the course of a reaction without playing an obvious catalytic role involving substrate binding.
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Reactive Applications of Cyclic Alkylene Carbonates
TL;DR: The use of cyclic alkylene carbonates as reactive intermediates has been extensively studied in the literature as mentioned in this paper, but the range of their usefulness in industrial applications has only been fully realized in the past decade.