Journal ArticleDOI
Synthesis of piperidines
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This article is published in Tetrahedron.The article was published on 2004-02-16. It has received 476 citations till now. The article focuses on the topics: Piperidine.read more
Citations
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Hydroamination: direct addition of amines to alkenes and alkynes.
TL;DR: Hydroamination of Alkenes and Alkynes under Microwave Irradiation and Nitromercuration Reactions 3878 9.8.4.5.
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Chiral Amine Synthesis – Recent Developments and Trends for Enamide Reduction, Reductive Amination, and Imine Reduction
TL;DR: The review examines the chiral amine literature from 2000-2009 concerning enantioselective and diastereoselectives methods for N-acylenamide and enamine reduction, reductive amination, and imine reduction.
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Synthesis of Pyridine and Dihydropyridine Derivatives by Regio- and Stereoselective Addition to N-Activated Pyridines
TL;DR: Stereoselective Addition to N-Activated Pyridines James A. Bull, Guillaume Pelletier,† and Andre ́ B. Charette are credited for this work.
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Phosphine-triggered synthesis of functionalized cyclic compounds
Long-Wu Ye,Jian Zhou,Yong Tang +2 more
TL;DR: This tutorial review summarizes the recent achievements in nucleophilic phosphine catalysis and describes how phosphines can be easily tailored to efficient annulation reactions with good control over reaction selectivity.
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Recent developments in dynamic kinetic resolution
TL;DR: The use of stereoisomers has always been a reliable method of obtaining enantiomerically pure compounds, but the fundamental limitation of the yield to 50% has made it thoroughly unfashionable as mentioned in this paper.
References
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Journal ArticleDOI
Asymmetric Diels-Alder and Ene Reactions in Organic Synthesis. New Synthetic Methods (48)
TL;DR: In this article, a systematic and critical treatment of various stereoface-differentiating principles, including very recent spectacular advances, is presented for the synthesis of chirality centers with predictable relative and absolute configurations.
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Inverse electron-demand Diels-Alder reactions of N-sulfonyl .alpha.,.beta.-unsaturated imines: a general approach to implementation of the 4.pi. participation of 1-aza-1,3-butadienes in Diels-Alder reactions
TL;DR: In this paper, the inverse electron demand Diels-Alder reactions of N-sulfonyl-1-aza-1,3-butadienes are described.
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Palladium/benzoic acid catalyzed hydroamination of alkynes
TL;DR: The reaction of the internal alkyne with alcohols 2 in the presence of a catalytic amount of Pd(PPh3)4 and benzoic acid in dioxane at 100°C gave the allylic ethers 3 in good to high yields as discussed by the authors.
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Enamide-olefin ring-closing metathesis.
Sape S. Kinderman,Jan H. van Maarseveen,Hans E. Schoemaker,and Henk Hiemstra,Floris P. J. T. Rutjes +4 more
TL;DR: The first examples of ring-closing metathesis reactions of olefin-containing enamides using ruthenium-based catalysts have been demonstrated in this article.