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Towards the hydrogen economy

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In this article, a description of the potential paths that may make it possible to change from the current energy sources to a cleaner energy production system is provided, the main focus being placed on how the so-called hydrogen economy might eventually be implemented, taking into account the issues of hydrogen production, distribution, storage and use.
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This article is published in International Journal of Hydrogen Energy.The article was published on 2007-08-01 and is currently open access. It has received 747 citations till now. The article focuses on the topics: Hydrogen economy & Energy supply.

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A comparative overview of hydrogen production processes

TL;DR: A comparative overview of the major hydrogen production methods is carried out in this article, where the process descriptions along with the technical and economic aspects of 14 different production methods are discussed, and the results regarding both the conventional and renewable methods are presented.
Journal ArticleDOI

Hydrogen energy, economy and storage: Review and recommendation

TL;DR: In this paper, a brief review of hydrogen as an ideal sustainable energy carrier for the future economy, its storage as the stumbling block as well as the current position of solid-state hydrogen storage in metal hydrides and makes a recommendation based on the most promising novel discoveries made in the field in recent times which suggests a prospective breakthrough towards a hydrogen economy.
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Hydrogen production for energy: An overview

TL;DR: In this article, the authors presented the hydrogen-based energy system as four corners (stages) of a square shaped integrated whole to demonstrate the interconnection and interdependency of these main stages.
Journal ArticleDOI

The future of hydrogen : opportunities and challenges

TL;DR: In this paper, the authors highlight the opportunities and the challenges of introducing hydrogen as alternative fuel in the transport sector from an economic, technical and environmental point of view, through its multi-disciplinary approach.
References
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Journal ArticleDOI

Stabilization Wedges: Solving the Climate Problem for the Next 50 Years with Current Technologies

TL;DR: A portfolio of technologies now exists to meet the world's energy needs over the next 50 years and limit atmospheric CO 2 to a trajectory that avoids a doubling of the preindustrial concentration as mentioned in this paper.
Journal ArticleDOI

Biohydrogen production: prospects and limitations to practical application

TL;DR: In this paper, the authors compare the hydrogen production rates of various bio-hydrogen systems by first standardizing the units of hydrogen production and then calculating the size of biohydrogen system that would be required to power proton exchange membrane (PEM) fuel cells of various sizes.
Journal ArticleDOI

Review of hydrogen storage by adsorption in carbon nanotubes

TL;DR: In this article, a comparison between the different studies of hydrogen adsorption in carbon nanotubes is presented, where the authors consider the possibility of controlling tube diameters and lengths that will enable to optimize nanotube structure for a maximal hydrogen adorption.
ReportDOI

Preliminary screening: Technical and economic assessment of synthesis gas to fuels and chemicals with emphasis on the potential for biomass-derived syngas

TL;DR: In this article, the authors present a review of many syngas to products processes and summarize the salient points regarding the technology status and description, chemistry, catalysts, reactors, gas cleanliness requirements, process and environmental performances, and economics.
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Q1. What are the contributions mentioned in the paper "Towards the hydrogen economy?" ?

Thus, now seems an appropriate time for the scientific community and energy producers to exchange their knowledge in this debate far away from the magic solutions provided by mass media prophets, in an attempt to arrive at realistic guidelines that may help society to understand the important issues involved in the move towards a cleaner energy system. In this essay a description of the potential paths that may make it possible to change from the current energy sources to a cleaner energy production system is provided, the main focus being placed on how the so called hydrogen economy might eventually be implemented. Additionally, the potential exploitation of the different hydrogen sources, both renewable and non-renewable, will be evaluated taking into account their availability and the efficiency of the processes used to transform them into hydrogen. 

The main advantage of hydrogen as a fuel is the absence of CO2 emissions, as well as other pollutant emissions (thermal NOx) if it is employed in low temperature fuel cells. 

In order to supply hydrogen to areas far from the general network it will be necessary to build refuelling stations able to generate hydrogen in situ, by means of electrolysers fed by renewable energies (such as photovoltaic solar panels or windmills) or biomass reformers. 

The so-called Hydrogen Economy is a long-term project that can be defined as an effort to change the current energy system to one which attempts to combine the cleanliness of hydrogen as an energy carrier with the efficiency of fuel cells as devices to transform energy into electricity and heat. 

At the present time the most appropriate fuelcells for this use are the Solid Oxide Fuel Cells (SOFC) which are fitted with non-porous ceramic electrolytes. 

Although clearly the best solution to the negative effects of energy consumption is to continue to decrease the use of fossil fuels, their use on a large scale for electricity generation and H2 production is guaranteed at least for several decades. 

the use of two parallel thermal cycles in which H2 and O2 are produced separately, allows H2 to be obtained at a considerably lower temperature (<1,000ºC). 

In the most favourable situation for the development of a Hydrogen Economy (ESTEC D) in 2050 30% of the cars will be powered by hydrogen feed fuel cells and there will be a capacity of 200-300 GW in installed fuel cells to cogenerate heat and electricity in the residential sector. 

It can also be assumed that the increase in capacity of reformers and electrolysers will lead to a further decrease in their cost and an increase in their efficiency to values close to the theoretical ones. 

In a no-change scenario (Base Scenario of the International Energy Agency, IEA) CO2 emissions in 2050 can be expected to reach 14 Gton of carbon (6). 

In the transition to a hydrogen economy, biomass can be employed as a clean form of energy mainly through the three conversion processes (Table 2) described below:Process 1. Transformation to bio-fuels (bio-ethanol and bio-diesel) that are directly burnt in the internal combustion engine. 

These tanks which are built of carbon fibre are used in the bus fleet mentioned above and in some car prototypes such as Ford Focus C-Max with ICE-H2. 

The technological barriers include the cost, the development of economic and appropriate materials for the experimental conditions (separation membranes and heat exchangers) and an increase in thermal efficiency of over 50%. 

The European Union expects that by 2010 these renewable sources will contribute 22% to the total amount of electricity generated (Figure 1). 

For smaller scale storage at production points, similar systems to those employed in vehicles could be applied (pressure tanks, liquid hydrogen tanks, hydrides, etc). 

For instance H2 production for transport by coal reforming, if the authors consider the rate of consumption expected in 2050 (1 Gton H2/year) will be guaranteed for 70 years if electricity and heat are produced from other energy sources (Table 3). 

This problem can be expressed in numbers via the worldwide CO2 emission market, in which an estimated cost of $50/ton would seem to be enough to force the energy companies along the path of implementing carbon-free energy sources. 

These fuels will be transformed in cogeneration thermal plants to produce H2 and electricity (for instance in IGCC plants; integrated gasification in combined cycle) provided with CO2 separation systems (sorbents, membranes, etc). 

Currently the cost of production of hydrogen in centralized coal gasifier systems (without CCS) is more expensive than the cost of H2 from centralized natural gas reforming systems ($0.22/Lge vs. $0.13/Lge) (10). 

the first process is the best alternative to allow a gradual decrease in the consumption of gasoline in the short-term, since bio-fuels can be mixed with standard gasoline or used alone with only minor modifications to the current combustion engines.