scispace - formally typeset
Search or ask a question

Showing papers on "Pore water pressure published in 2006"


Journal ArticleDOI
17 Nov 2006-Science
TL;DR: The volumetric expansion of freezing pore water is widely assumed to be a major cause of rock fracture in cold humid regions, but data from experiments simulating natural freezing regimes indicate that bedrock fracture results instead from ice segregation, supporting a conceptual model in which ice segregation in near-surface permafrost leads progressively to rock fracture and heave.
Abstract: The volumetric expansion of freezing pore water is widely assumed to be a major cause of rock fracture in cold humid regions. Data from experiments simulating natural freezing regimes indicate that bedrock fracture results instead from ice segregation. Fracture depth and timing are also numerically simulated by coupling heat and mass transfer with a fracture model. The depth and geometry of fractures match those in Arctic permafrost and ice-age weathering profiles. This agreement supports a conceptual model in which ice segregation in near-surface permafrost leads progressively to rock fracture and heave, whereas permafrost degradation leads episodically to melt of segregated ice and rock settlement.

319 citations


Journal ArticleDOI
TL;DR: Charette et al. as discussed by the authors used pore water data from the Waquoit Bay coastal aquifer/subterranean estuary, along with Bay surface water data, to establish a more detailed view into the estuarine chemistry and the chemical diagenesis of Fe, Mn, U, Ba and Sr in coastal aquifers.

275 citations


Journal ArticleDOI
TL;DR: In this paper, the authors used the decomposition rate of plagioclase in fine-grained sediment from the Ocean Drilling Project at Site 984 in the North Atlantic to determine whether the apparent discrepancy between laboratory and field dissolution rates still exists when a mechanistic reactive transport model is used to interpret rates in a natural system.

256 citations


Journal ArticleDOI
TL;DR: In this paper, the authors investigated the amount of attenuation and velocity dispersion caused by different types of heterogeneities in the rock properties, namely, porosity, grain and frame moduli, permeability, and fluid properties.
Abstract: Recent research has established that the dominant P-wave attenuation mechanism in reservoir rocks at seismic frequencies is because of wave-induced fluid flow (mesoscopic loss). The P-wave induces a fluid-pressure difference at mesoscopic-scale inhomogeneities (larger than the pore size but smaller than the wavelength, typically tens of centimeters) and generates fluid flow and slow (diffusion) Biot waves (continuity of pore pressure is achieved by energy conversion to slow P-waves, which diffuse away from the interfaces). In this context, we consider a periodically stratified medium and investigate the amount of attenuation (and velocity dispersion) caused by different types of heterogeneities in the rock properties, namely, porosity, grain and frame moduli, permeability, and fluid properties. The most effective loss mechanisms result from porosity variations and partial saturation, where one of the fluids is very stiff and the other is very compliant, such as, a highly permeable sandstone at shallow depths, saturated with small amounts of gas (around 10% saturation) and water. Grain- and frame-moduli variations are the next cause of attenuation. The relaxation peak moves towards low frequencies as the (background) permeability decreases and the viscosity and thickness of the layers increase. The analysis indicates in which cases the seismic band is in the relaxed regime, and therefore, when the Gassmann equation can yield a good approximation to the wave velocity.

245 citations


Journal ArticleDOI
TL;DR: In this paper, the authors present field measurements and numerical simulations of groundwater dynamics in the intertidal zone of a sandy meso-tidal beach, focusing on vertical hydraulic gradients and pore water salinities, revealing that tides and waves provide important forcing mechanisms for flow and salt transport in the nearshore aquifer.
Abstract: This paper presents field measurements and numerical simulations of groundwater dynamics in the intertidal zone of a sandy meso-tidal beach. The study, focusing on vertical hydraulic gradients and pore water salinities, reveals that tides and waves provide important forcing mechanisms for flow and salt transport in the nearshore aquifer. Such forcing, interacting with the beach morphology, enhances the exchange between the aquifer and ocean. The spatial and temporal variations of vertical hydraulic gradients demonstrate the complexity and dynamic nature of the processes and the extent of mixing between fresh groundwater and seawater in a subterranean estuary''. These results provide evidence of a potentially important reaction zone in the nearshore aquifer driven by oceanic oscillations. Land-derived contaminants may undergo important biogeochemical transformations in this zone prior to discharge.

221 citations


Journal ArticleDOI
TL;DR: In this article, an equilibrium model of methane venting through the hydrate stability zone at southern Hydrate Ridge, offshore Oregon is presented, which self-generates local three-phase equilibrium and allows free gas migration to the seafloor.

217 citations


Journal ArticleDOI
TL;DR: In this paper, the authors quantified the excess pore pressure resulting from gas hydrate dissociation in marine sediments, and found that the amount of excess pressure in confined pore spaces can be up to several tens of megapascals due to the tendency for volume expansion associated with gas hydrates dissociation.
Abstract: [1] This study quantifies the excess pore pressure resulting from gas hydrate dissociation in marine sediments. The excess pore pressure in confined pore spaces can be up to several tens of megapascals due to the tendency for volume expansion associated with gas hydrate dissociation. On the other hand, the magnitude of excess pore pressure in well-connected sediment pores is generally smaller, depending primarily on the hydrate dissociation rate and the sediment permeability. Volume expansion due to gas hydrate dissociation in well-connected pore spaces is related via Darcy's law to an increase in pore pressure and its gradient in sediment, which drives an additional upward fluid flow through the sediment layer overlying the gas hydrate dissociation area. The magnitude of this excess pore pressure is found to be proportional to the rate of gas hydrate dissociation and the depth below seafloor and inversely proportional to sediment permeability and the depth below sea level. The excess pore pressure is the greatest at low initial pressures and decreases rapidly with increasing initial pressure. Excess pore pressure may be the result of gas hydrate dissociation due to continuous sedimentation, tectonic uplift, sea level fall, heating or inhibitor injection. The excess pore pressure is found to be potentially able (1) to facilitate or trigger submarine landslides in shallow water environments, (2) to result in the formation of vertical columns of focused fluid flow and gas migration, and (3) to cause the failure of a sediment layer confined by low-permeability barriers in relatively deep water environments.

199 citations


Journal ArticleDOI
TL;DR: In this article, a series of centrifuge model tests and numerical simulations of these tests were carried out to investigate the surface settlement troughs, excess pore water pressure generation, tunnel stability and arching effects that develop during tunneling in soft clayey soil.

191 citations


Journal ArticleDOI
TL;DR: In this paper, the pore pressure changes due to diffusing rain water and in good agreement with the response of faults described by the rate-state friction law are shown to trigger earthquakes in a few kilometres depth.
Abstract: [1] Fluids are known to be of major importance for the earthquake generation because pore pressure variations alter the strength of faults. Thus they can initiate earthquakes if the crust is close enough to its critical state. Based on the observations of the isolated seismicity below the densely monitored Mt. Hochstaufen, SE Germany, we are now able to demonstrate that the crust can be so close-to-failure that even tiny pressure variations associated with precipitation can trigger earthquakes in a few kilometer depth. We find that the recorded seismicity is highly correlated with the calculated spatiotemporal pore pressure changes due to diffusing rain water and in good agreement with the response of faults described by the rate-state friction law.

186 citations


Journal ArticleDOI
TL;DR: In this article, influential factors of the liquefaction resistance of partially saturated sand are derived from theoretical consideration and effects of the factors are examined through a series of triaxial tests.

177 citations


Journal ArticleDOI
TL;DR: In this article, the authors used a numerical model to show that dilational soils approach the critical void ratio and the arresting effect of negative pore pressures generated by dilation is greatly reduced, leading to a rapid increase in basal pore pressure and rapid downslope acceleration.


Journal ArticleDOI
01 May 2006
TL;DR: In this paper, the radon mass balance was constructed by assuming that radon may be advected via groundwater discharge into all compartments of the boat basin and the mixing outputs from an inner box would be an input into the adjacent box.
Abstract: Estimates of groundwater discharge into a boat basin in Donnalucata, southeastern Sicily, based on radon measurements are reported. A continuous monitor was deployed at several locations that made repeated integrated measurements of radon concentration in the seawater once per hour. We observed large differences in the concentrations (60–2500 Bq m −3 ) and inventories (90–3200 Bq m −2 ) of 222 Rn at various locations within the boat basin. The station closest to shore had the highest concentration by far (up to over 3000 Bq m −3 ), reflecting inputs of radon-rich groundwater into this zone. We constructed a radon mass balance by assuming that radon may be advected via groundwater discharge into all compartments of the boat basin and the mixing outputs from an inner “box” would be an input into the adjacent box. We also made allowances for atmospheric evasion losses that were occasionally very high due to high winds and huge concentration gradients across the air–sea interface. Once the radon fluxes have been estimated, we could calculate groundwater discharge by dividing these fluxes by the radon concentration of the groundwater. Should the groundwater be entering the basin by widely disseminated seepage through bottom sediments, it would be appropriate to use values of pore water derived by sediment equilibration techniques. These values (2700±200 Bq m −3 ) are close to those from several samples from shallow wells collected near the boat basin (1700–2700 Bq m −3 ). However, we measured higher radon levels than this in the waters of the innermost portion of the basin. We thus elected to assume that the main radon entry was either via direct spring input with activities (15 100 Bq m −3 ) similar to those measured from a natural spring on a nearby beach or a blend of spring water with surficial aquifer water. The resulting range in our calculated groundwater discharges into the boat basin is 1200 to 7400 m 3 day −1 . These estimates are higher than those based on seepage meters (range=300–1000 m 3 day −1 ), probably because of the wide spatial variability of the spring and seep inputs.

Journal ArticleDOI
TL;DR: In this article, the pore space of water-saturated bentonite is divided into macropore and interlayer nanopore compartments, and the relative contributions of pore-network geometry and diffusive behavior of water molecules near montmorillonite basal surfaces are determined quantitatively.
Abstract: Compacted Na-bentonite clay barriers, widely used in the isolation of solid-waste landfills and other contaminated sites, have been proposed for a similar use in the disposal of high-level radioactive waste. Molecular diffusion through the pore space in these barriers plays a key role in their performance, thus motivating recent measurements of the apparent diffusion coefficient tensor of water tracers in compacted, water-saturated Na-bentonites. In the present study, we introduce a conceptual model in which the pore space of water-saturated bentonite is divided into ‘macropore’ and ‘interlayer nanopore’ compartments. With this model we determine quantitatively the relative contributions of pore-network geometry (expressed as a geometric factor) and of the diffusive behavior of water molecules near montmorillonite basal surfaces (expressed as a constrictivity factor) to the apparent diffusion coefficient tensor. Our model predicts, in agreement with experiment, that the mean principal value of the apparent diffusion coefficient tensor follows a single relationship when plotted against the partial montmorillonite dry density (mass of montmorillonite per combined volume of montmorillonite and pore space). Using a single fitted parameter, the mean principal geometric factor, our model successfully describes this relationship for a broad range of bentonite-water systems, from dilute gel to highly-compacted bentonite with 80% of its pore water in interlayer nanopores.

Posted ContentDOI
TL;DR: In this paper, the authors measured intrinsic permeability of sedimentary rocks from the Western Foothills of Taiwan, using nitrogen gas and distilled water as pore fluids, during several effective pressure cycling tests at room temperature.
Abstract: . The difference between gas and water permeabilities is significant not only for solving gas-water two-phase flow problems, but also for quick measurements of permeability using gas as pore fluid. We have measured intrinsic permeability of sedimentary rocks from the Western Foothills of Taiwan, using nitrogen gas and distilled water as pore fluids, during several effective-pressure cycling tests at room temperature. The observed difference in gas and water permeabilities has been analyzed in view of the Klinkenberg effect. This effect is due to slip flow of gas at pore walls which enhances gas flow when pore sizes are very small. Experimental results show (1) that gas permeability is larger than water permeability by several times to one order of magnitude, (2) that gas permeability increases with increasing pore pressure, and (3) that water permeability slightly increases with increasing pore-pressure gradient across the specimen. The results (1) and (2) can be explained by Klinkenberg effect quantitatively with an empirical power law for Klinkenberg constant. Thus water permeability can be estimated from gas permeability. The Klinkenberg effect is important when permeability is lower than 10−18 m2 and at low differential pore pressures, and its correction is essential for estimating water permeability from the measurement of gas permeability. A simple Bingham-flow model of pore water can explain the overall trend of the result (3) above. More sophisticated models with a pore-size distribution and with realistic rheology of water film is needed to account for the observed deviation from Darcy's law.

Journal ArticleDOI
TL;DR: In this paper, the authors investigated the seasonal and spatial scales of aerobic and anaerobic mineralization in a sloping intertidal sand flat (German Wadden Sea) affected by current-induced pore water exchange and pore fluid drainage.
Abstract: This study addresses organic matter decomposition in permeable sediment of a sloping intertidal sand flat (German Wadden Sea) affected by current-induced pore water exchange and pore fluid drainage. Seasonal and spatial scales of aerobic and anaerobic mineralization were investigated at 2 sites, one near the water line and one on the upper flat. Hydrodynamic forcing during inundation caused deeper oxygen penetration through flushing of the uppermost sediment layer. This flushing resulted in higher areal oxygen consumption rates and lower depth integrated sulfate reduction rates in the submerged flat compared to the rates measured during exposure. Mineralization rates in the top 15 cm of the sediment were similar between both study sites and ranged from 38 (winter) to 280 mmol C m–2 d–1 (summer), with sulfate reduction contributing 3 to 25% to total mineralization, depending on the season. At the upper flat, these seasonal differences were reflected in the pore water concentrations of nutrients, dissolved inorganic carbon (DIC) and dissolved organic carbon (DOC). Near the low water line, however, pore water nutrient and DIC concentrations were independent of the season and up to 15 times higher compared to the values recorded in the upper flat. The differences in concentrations of metabolic products between the 2 sites resulted from a low tide drainage extending deep below the uppermost flushed layer and causing seepage of pore water near the low water line. Mineralization and nutrient release in these permeable intertidal sediments is affected by 2 circulation processes that work on distinctly different temporal and spatial scales: (1) rapid ‘skin circulation’ through the uppermost sediment layer during inundation that is characterized by short flow paths, low pore water residence time and immediate feedback to the ecosystem, and (2) slow ‘body circulation’ through deeper sediment layers during low tide that is characterized by long flow paths and pore water residence times, and acts as a buffered nutrient source to the ecosystem.

Journal ArticleDOI
TL;DR: In this paper, the authors present field measurements of seasonal moisture content and pore water pressure changes within the surface drying zone of a cut slope in the London Clay at Newbury, Berkshire, UK.
Abstract: In temperate European climates, the season of peak water demand by vegetation (summer) is out of phase with the season of greatest rainfall (winter). This results in seasonal fluctuations in soil water content and, in clay soils, associated problems of shrinking and swelling that can in turn contribute to strain-softening and progressive slope failure. This paper presents field measurements of seasonal moisture content and pore water pressure changes within the surface drying zone of a cut slope in the London Clay at Newbury, Berkshire, UK. A climate station was installed at the site to measure the parameters needed to determine specific plant evapotranspiration. This information was used to carry out a water balance calculation to estimate the year-round soil moisture deficit caused by the vegetation. The calculated soil moisture deficit matches reasonably closely the field measurements of soil drying. The field measurements of seasonal changes in pore water pressure and suction are linked quantitatively...

Journal ArticleDOI
TL;DR: In this paper, an experimental investigation of the complete sequence of sediment behavior under progressive waves is presented, which reveals that excess pore pressure builds up, which is followed by liquefaction during which internal waves are experienced at the interface of the water body and the liquefied sediment, the sequence of processes known from a previous investigation.
Abstract: This paper presents the results of an experimental investigation of the complete sequence of sediment behaviour beneath progressive waves. The sediment was silty with d50 = 0.060 mm. Two kinds of measurements were carried out: pore-water pressure measurements (across the sediment depth), and water-surface elevation measurements. The process of liquefaction/compaction was videotaped from the side simultaneously with the pressure and water-surface elevation measurements. The video records were then analysed to measure: (i) the time development of the mudline, (ii) the time development of liquefaction and compaction fronts in the sediment and (iii) the characteristics of the orbital motion of the liquefied sediment including the motion of the interface between the water body and the sediment. The ranges of the various quantities in the tests were: wave height, H = 9–17 cm, wave period, T = 1.6 sec, water depth = 42 cm, and the Shields parameter = 0.34–0.59. The experiments reveal that, with the introduction of waves, excess pore pressure builds up, which is followed by liquefaction during which internal waves are experienced at the interface of the water body and the liquefied sediment, the sequence of processes known from a previous investigation. This sequence of processes is followed by dissipation of the accumulated excess pore pressure and compaction of the sediment which is followed by the formation of bed ripples. The present results regarding the dissipation and compaction appear to be in agreement with recent centrifuge wave-tank experiments. As for the final stage of the sequence of processes (formation of ripples), the ripple steepness (normalized with the angle of repose) for sediment with liquefaction history is found to be the same as that in sediment with no liquefaction history.

Journal ArticleDOI
TL;DR: In this article, a high-resolution, stationary geophysical and geochemical survey was conducted at Dor Beach, Israel, to examine the shallow coastal hydrogeology and its control on the exchange of submarine groundwater with the shallow Mediterranean Sea.
Abstract: [1] A high-resolution, stationary geophysical and geochemical survey was conducted at Dor Beach, Israel, to examine the shallow coastal hydrogeology and its control on the exchange of submarine groundwater with the shallow Mediterranean Sea. Time-series resistivity profiles using a new 56 electrode (112-m long) marine cable produced detailed profiles of the fresh water/salt water interface and the subtle response of this interface to tidal excursions and other forcing factors. Such information, when ground-truthed with representative pore water salinities and formation resistivity values, can provide unique information of the extent and rates of submarine groundwater discharge (SGD). Time-series 222Rn measurements of the adjacent coastal water column complemented these geophysical techniques and were modeled to yield integrated advective flow rates across the sediment/water interface, which at Dor Beach ranged from about 0 to 30 cm day−1 (mean = 7.1 cm d−1), depending on the tidal range. Such results suggest that the underlying hydrogeologic framework at Dor is favorable for substantial SGD. Extrapolating these SGD estimates across a 100-m wide coastal zone implies that the Rn-derived SGD rate would equal ∼7.1 m3 d−1 per m of shoreline, and that the source of this discharging groundwater is a complex mixture of fresh groundwater derived from the upland Kurkar deposits, as well as locally recycled seawater.

Journal ArticleDOI
TL;DR: In this article, the isotopic composition of pore water ammonium and N org in the anoxic sediments of the Santa Barbara Basin and the Eastern Subtropical North Pacific (ESNP) region was analyzed.

Journal ArticleDOI
TL;DR: Theoretical modelling of the mechanical phenomena induced by jet grouting is presented in this article, where the analysis is developed for the single-fluid method and the jet propagation across the space included between the injection nozzles and the intact soil is first modelled on the basis of the theory of submerged flows.
Abstract: Theoretical modelling of the mechanical phenomena induced by jet grouting is presented The analysis is developed for the single-fluid method The jet propagation across the space included between the injection nozzles and the intact soil is first modelled on the basis of the theory of submerged flows Different possible interaction modes between jet and soil are then assumed for gravels, sands and clays, according to the results of previous experimental investigations In the case of gravels, grout seepage is considered to be the most relevant mechanism For sandy soils, the injected fluid is assumed to penetrate, for a limited extent, into the soil skeleton, producing a considerable increment of the pore pressures and a corresponding reduction of the grain-to-grain contact forces The removal of the soil particles is then triggered by the dragging action of the fluid threads, and the analysis is developed under drained conditions For clayey soils, the jet action is considered as a load imposed on the j

Journal ArticleDOI
TL;DR: In this paper, a series of generated failures in a model with two soil layers was performed by means of a flume device, where the soil layers were made of a medium-sized sand and a fine sand, placed in horizontal layers.

Journal ArticleDOI
TL;DR: Results show that equilibrium partition models can predict sorption coefficients of freshly spiked and lab-aged soils rather accurately, however, freely dissolved pore water concentrations of field-contaminated soils are orders of magnitude lower than model predictions, and environmental risks can be highly overestimated with these models.
Abstract: Freely dissolved aqueous concentrations in the soil pore water represent an important aspect of bioavailability and risk assessment of contaminated soils. In this study, a negligible depletive partitioning based sampling technique was validated and applied to measure free concentrations of polycyclic aromatic hydrocarbons (PAHs) in spiked, aged and field-contaminated soils. Detailed kinetic studies were performed to select appropriate equilibration times. Freely dissolved aqueous concentrations in the pore water were compared to total concentrations, and sorption coefficients were calculated. Results show that equilibrium partition models can predict sorption coefficients of freshly spiked and lab-aged soils rather accurately. However, freely dissolved pore water concentrations of field-contaminated soils are orders of magnitude lower than model predictions. Consequently, environmental risks can be highly overestimated with these models. The simple and sensitive partitioning-based sampling technique used ...

Journal ArticleDOI
TL;DR: In this article, pore-scale observations of colloid mobilization, transport, and retention within a transparent flow cell packed with partially saturated quartz sand are presented, showing that colloid retention is dominated by adhesion to insular air bubbles at high moisture content and a combination of thin-film straining and immobile water storage at low moisture content.
Abstract: [1] The distribution of colloid-associated contaminants and colloid-sized microorganisms within the vadose zone is controlled, in part, by mobilization and retention processes. In this work, we present pore-scale observations of colloid mobilization, transport, and retention within a transparent flow cell packed with partially saturated quartz sand. Our results show that colloid retention is dominated by adhesion to insular air bubbles at high moisture content and a combination of thin-film straining and immobile water storage at low moisture content. Mobilization of retained colloids under steady flow is governed by slow exchange between zones of immobile and mobile water. During transient flow, characterized by increases in flow rate and moisture content, strained colloids are released from expanding thin films of water and from immobile water zones that reconnect with advecting pore water regions. On the basis of our observations we infer that colloid mobilization and retention within the vadose zone reflects contributions from multiple mechanisms that are sensitive to moisture content and flow regime.

Journal ArticleDOI
01 Apr 2006
TL;DR: In this article, a mathematical model for the rate of root water uptake in tree root zones is proposed. But the model is not suitable for the use of tree roots in railway corridors.
Abstract: The use of native vegetation in the coastal regions of Australia has become increasingly popular for stabilising railway corridors built over expansive clays and compressive soft soils. The tree roots provide three stabilising functions: (a) they reinforce the soil; (b) they dissipate excess pore pressures; and (c) they establish sufficient matric suction to increase the shear strength. The matric suction generated within the tree root zone propagates radially into the soil matrix, as a function of the moisture content change. Considering soil conditions, the type of vegetation and atmospheric conditions, a mathematical model for the rate of root water uptake is developed. A conical shape is considered to represent the geometry of the tree root zone. Based on this model for the rate of root water uptake, the pore water pressure distribution and the movement of the ground adjacent to the tree are numerically analysed. Field measurements taken from the previously published literature are compared with the a...

Journal ArticleDOI
TL;DR: Overpressured formations exhibit several of the following properties when compared with a normally pressured section at the same depth (Dutta, 2002): (1) higher porosities, lower bulk densities, (3) lower effective stresses, (4) higher temperatures, (5) lower interval velocities, and (6) higher Poisson's ratios as mentioned in this paper.
Abstract: Overpressured formations exhibit several of the following properties when compared with a normally pressured section at the same depth (Dutta, 2002): (1) higher porosities, (2) lower bulk densities, (3) lower effective stresses, (4) higher temperatures, (5) lower interval velocities, and (6) higher Poisson's ratios

Journal ArticleDOI
TL;DR: In this article, the importance of capillary pressure and adsorbed water in the behavior of heat and moisture transport in concrete exposed to high temperatures is explored by incorporating their behavior explicitly into a computational model.
Abstract: The importance of capillary pressure and adsorbed water in the behavior of heat and moisture transport in concrete exposed to high temperatures is explored by incorporating their behavior explicitly into a computational model. The inclusion of these two phenomena is realized with a formulation of a modified model, which represents an extension to the significant work of Tenchev et al. Comparative studies were carried out, using a benchmark problem, and it was determined that while the Tenchev formulation underestimated the capacity for fluid transport in the concrete, resulting in an overprediction of pore pressures (which may affect the prediction of mechanical damage and spalling), the inclusion of capillary pressure had little effect on the results. More important was the accurate representation of the free water flux, which has a significant effect on the prediction of vapor content and subsequently pore pressure. It was furthermore found that, while the adsorbed water flux may be minimal whe...

Journal ArticleDOI
TL;DR: In this paper, two cores were taken in 1997 and 1998 in the loess unsaturated zone in Inner Mongolia and Shanxi province, respectively, where the tritium profiles of pore water from a test pit and a core taken in 1980's had already been reported.

Journal ArticleDOI
TL;DR: Saturation of the pore water with increasing soil concentrations should therefore be considered in soil toxicity testing, and sorption coefficients that were calculated from freely dissolved concentrations were slightly higher than estimates based on octanol-water partition coefficients.
Abstract: Freely dissolved pore water concentrations are difficult to assess in complex matrixes such as soils or sediments. In this study, a negligible-depletion partitioning-based sampling technique was applied to measure freely dissolved pore water concentrations. A poly(dimethylsiloxane) (PDMS)-coated glass fiber was exposed to a slurry of a soil spiked with several PAHs at concentrations ranging from 2 to 2000 mg/kg. PAH-concentrations in the PDMS coating increased linearly with the total soil concentration until a certain maximum was reached. Freely dissolved pore water concentrations were calculated using PDMS-water partition coefficients, and the calculated maximum pore water concentrations corresponded with the aqueous solubility of the tested compounds. Furthermore, the sampling technique is very sensitive because it can detect freely dissolved pore water concentrations in the ng/L range for the tested PAHs. Freely dissolved pore water concentrations are an important parameter for the exposure of organisms in soil. Saturation of the pore water with increasing soil concentrations should therefore be considered in soil toxicity testing. Sorption coefficients that were calculated from freely dissolved concentrations were slightly higher than estimates based on octanol-water partition coefficients. These differences are discussed in relation to the effects of dissolved organic matter in soil pore water on the determination of sorption coefficients.

Journal ArticleDOI
TL;DR: In this article, the authors combine a numerical model of groundwater flow with critical taper theory to quantify the effects of sediment and decollement permeability, sediment thickness, sediment partitioning between accretion and underthrusting, and plate convergence rate on steady state pore pressure.
Abstract: [1] At many subduction zones, accretionary complexes form as sediment is off-scraped from the subducting plate. Mechanical models that treat accretionary complexes as critically tapered wedges of sediment demonstrate that pore pressure controls their taper angle by modifying basal and internal shear strength. Here, we combine a numerical model of groundwater flow with critical taper theory to quantify the effects of sediment and decollement permeability, sediment thickness, sediment partitioning between accretion and underthrusting, and plate convergence rate on steady state pore pressure. Our results show that pore pressure in accretionary wedges can be viewed as a dynamically maintained response to factors which drive pore pressure (source terms) and those that limit flow (permeability and drainage path length). We find that sediment permeability and incoming sediment thickness are the most important factors, whereas fault permeability and the partitioning of sediment have a small effect. For our base case model scenario, as sediment permeability is increased, pore pressure decreases from near-lithostatic to hydrostatic values and allows stable taper angles to increase from ∼2.5° to 8°–12.5°. With increased sediment thickness in our models (from 100 to 8000 m), increased pore pressure drives a decrease in stable taper angle from 8.4°–12.5° to 15° to <4°) with increased sediment thickness (from <1 to 7 km). One key implication is that hydrologic properties may strongly influence the strength of the crust in a wide range of geologic settings.