Indian Institute of Technology Madras

About: Indian Institute of Technology Madras is a facility organization based out in Chennai, Tamil Nadu, India. It is known for research contribution in the topics: Catalysis & Heat transfer. The organization has 20118 authors who have published 36499 publications receiving 590447 citations.

Quantum Clusters in Cavities: Trapped Au15 in Cyclodextrins

Abstract: We have prepared Au15 quantum clusters anchored to α-, β-, and γ-cyclodextrin (CD) cavities. The synthesis process involves the core etching of larger clusters and the simultaneous trapping of the clusters formed inside the CD cavities. The clusters were characterized by various tools, such as optical absorption and luminescence spectroscopies, electrospray ionization−mass spectrometry (ESI-MS), X-ray photoelectron spectroscopy (XPS), circular dichroism spectroscopy, and two-dimensional nuclear magnetic resonance (2D NMR) spectroscopy. Trapping of the cluster in the CD cavity was proven by circular dichroism and also by rotational Overhauser effect spectroscopy (ROESY), in terms of the distinct cross peak between proton “e” of the glutathione (−SG) ligand and the “H3” proton of CD. Dynamic light scattering (DLS) studies showed a hydrodynamic diameter of ∼3−4 nm, indicating one CD molecule per cluster with an extension of one water of hydration. The clusters are intensely luminescent, with major lifetime c...

Use of Surface Waves in Statistical Correlations of Shear Wave Velocity and Penetration Resistance of Chennai Soils

Abstract: Shear wave velocity (V s) is one of the most important input parameter to represent the stiffness of the soil layers. It is preferable to measure V s by in situ wave propagation tests, however it is often not economically feasible to perform the tests at all locations. Hence, a reliable correlation between V s and standard penetration test blow counts (SPT-N) would be a considerable advantage. This paper presents the development of empirical correlations between V s and SPT-N value for different categories of soil in Chennai city characterized by complex variation of soil conditions. The extensive shear wave velocity measurement was carried out using Multichannel Analysis of Surface Waves (MASW) technique at the sites where the SPT-N values are available. The bender element test is performed to compare the field MASW test results for clayey soils. The correlations between shear wave velocity and SPT-N with and without energy corrections were developed for three categories of soil: all soils, sand and clay. The proposed correlations between uncorrected and energy corrected SPT-N were compared with regression equations proposed by various other investigators and found that the developed correlations exhibit good prediction performance. The proposed uncorrected and energy corrected SPT-N relationships show a slight variation in the statistical analysis indicating that both the uncorrected and energy corrected correlations can predict shear wave velocity with equal accuracy. It is also found that the soil type has a little effect on these correlations below SPT-N value of about 10.

Development of LSPR based U-bent plastic optical fiber sensors

Abstract: This study presents design and development of evanescent wave absorbance based U-bent plastic optical fiber (POF) probe with high sensitivity and its applications to refractive index (RI) sensing. The probes were fabricated by a controlled decladding procedure to remove the fluorinated polymer without damaging the poly methyl methacrylate (PMMA) core and a simple and scalable fabrication technique to obtain POF U-bent probes of desired geometry. U-bent probes of fiber diameter from 250 to 1000 μm were fabricated and optimum bend diameter for each fiber diameter was investigated. The sensitivity was found to be maximum when the bend diameter of the probe varies from 2 to 3 times the fiber diameter. Probes with 500 μm core and 1.25 mm bend diameter showed highest sensitivity (5.57Δ A 560 nm /ΔRIU) in the visible region to RI changes from 1.33 to 1.47 with a resolution better than 1 milli RI units. Furthermore, U-bent probes were amine functionalized and coated with gold nanoparticles to obtain a localized surface plasmon resonance (LSPR) based RI sensor that has an 8-fold improvement in RI sensitivity, hence extending their applicability to plasmonic biosensing.

A DSTATCOM Topology With Reduced DC-Link Voltage Rating for Load Compensation With Nonstiff Source

Abstract: The distribution static compensator (DSTATCOM) is used for load compensation in power distribution network. In this paper, a new topology for DSTATCOM applications with nonstiff source is proposed. The proposed topology enables DSTATCOM to have a reduced dc-link voltage without compromising the compensation capability. It uses a series capacitor along with the interfacing inductor and a shunt filter capacitor. With the reduction in dc-link voltage, the average switching frequency of the insulated gate bipolar transistor switches of the DSTATCOM is also reduced. Consequently, the switching losses in the inverter are reduced. Detailed design aspects of the series and shunt capacitors are discussed in this paper. A simulation study of the proposed topology has been carried out using power systems computer-aided design simulator and the results are presented. Experimental studies are carried out to verify the proposed topology.