University of Sannio

About: University of Sannio is a education organization based out in Benevento, Italy. It is known for research contribution in the topics: Gravitational wave & LIGO. The organization has 1278 authors who have published 6125 publications receiving 167577 citations. The organization is also known as: Università degli Studi del Sannio & Universita degli Studi del Sannio.

Self-assembly on optical fibers: a powerful nanofabrication tool for next generation “lab-on-fiber” optrodes

Abstract: Self-assembly offers a unique resource for the preparation of discrete structures at the nano- and microscale, which are either not accessible by other fabrication techniques or require highly expensive and technologically demanding processes. The possibility of obtaining spontaneous organization of separated components, whether they are molecules, polymers, nano- or micro-objects, into a larger functional unit, enables the development of ready-to-use plug and play devices and components at lower costs. Expanding the applicability of self-assembly approaches at the nanoscale to non-conventional substrates would open up new avenues towards multifunctional platforms customized for specific applications. Recently, the combination of the amazing morphological and optical features of self-assembled patterns with the intrinsic properties of optical fibers to conduct light to a remote location has demonstrated the potentiality to open up new intriguing scenarios featuring unprecedented functionalities and performances. The integration of advanced materials and structures at the nanoscale with optical fiber substrates is the idea behind the so-called lab-on-fiber technology, which is an emerging technology at the forefront of nanophotonics and nanotechnology research. Self-assembly processes can have a key role in implementing cost-effective solutions suitable for the mass production of technologically advanced platforms based on optical fibers towards their real market exploitation. Novel lab-on-fiber optrodes would arise from the sustainable integration of functional materials at the nano- and microscale onto optical fiber substrates. Such devices are able to be easily integrated in hypodermic needles and catheters for in vivo theranostics and point-of-care diagnostics, opening up new frontiers in multidisciplinary technological development to be exploited in life science applications. This work is conceived to provide an overview of the latest strategies, based on self-assembly processes, which have been implemented for the realization of lab-on-fiber optrodes with particular emphasis on the perspectives and challenges that lie ahead. We discuss the main fabrication techniques and strategies aimed at developing new multifunctional optical fiber nanoprobes and their application in real scenarios. Finally, we highlight some of the other self-assembly processes that have not yet been applied to optical fiber sensors, but have the potentiality to be exploited in the fabrication of future lab-on-fiber devices.

Was self-admitted technical debt removal a real removal?: an in-depth perspective

Abstract: Technical Debt (TD) has been defined as "code being not quite right yet", and its presence is often self-admitted by developers through comments. The purpose of such comments is to keep track of TD and appropriately address it when possible. Building on a previous quantitative investigation by Maldonado et al. on the removal of self-admitted technical debt (SATD), in this paper we perform an in-depth quantitative and qualitative study of how SATD is addressed in five Java open source projects. On the one hand, we look at whether SATD is "accidentally" removed, and the extent to which the SATD removal is being documented. We found that that (i) between 20% and 50% of SATD comments are accidentally removed while entire classes or methods are dropped, (ii) 8% of the SATD removal is acknowledged in commit messages, and (iii) while most of the changes addressing SATD require complex source code changes, very often SATD is addressed by specific changes to method calls or conditionals. Our results can be used to better plan TD management or learn patterns for addressing certain kinds of TD and provide recommendations to developers.

Nanosphere Lithography on Fiber: Towards Engineered Lab-On-Fiber SERS Optrodes

Abstract: In this paper we report on the engineering of repeatable surface enhanced Raman scattering (SERS) optical fiber sensor devices (optrodes), as realized through nanosphere lithography. The Lab-on-Fiber SERS optrode consists of polystyrene nanospheres in a close-packed arrays configuration covered by a thin film of gold on the optical fiber tip. The SERS surfaces were fabricated by using a nanosphere lithography approach that is already demonstrated as able to produce highly repeatable patterns on the fiber tip. In order to engineer and optimize the SERS probes, we first evaluated and compared the SERS performances in terms of Enhancement Factor (EF) pertaining to different patterns with different nanosphere diameters and gold thicknesses. To this aim, the EF of SERS surfaces with a pitch of 500, 750 and 1000 nm, and gold films of 20, 30 and 40 nm have been retrieved, adopting the SERS signal of a monolayer of biphenyl-4-thiol (BPT) as a reliable benchmark. The analysis allowed us to identify of the most promising SERS platform: for the samples with nanospheres diameter of 500 nm and gold thickness of 30 nm, we measured values of EF of 4 × 105, which is comparable with state-of-the-art SERS EF achievable with highly performing colloidal gold nanoparticles. The reproducibility of the SERS enhancement was thoroughly evaluated. In particular, the SERS intensity revealed intra-sample (i.e., between different spatial regions of a selected substrate) and inter-sample (i.e., between regions of different substrates) repeatability, with a relative standard deviation lower than 9 and 15%, respectively. Finally, in order to determine the most suitable optical fiber probe, in terms of excitation/collection efficiency and Raman background, we selected several commercially available optical fibers and tested them with a BPT solution used as benchmark. A fiber probe with a pure silica core of 200 µm diameter and high numerical aperture (i.e., 0.5) was found to be the most promising fiber platform, providing the best trade-off between high excitation/collection efficiency and low background. This work, thus, poses the basis for realizing reproducible and engineered Lab-on-Fiber SERS optrodes for in-situ trace detection directed toward highly advanced in vivo sensing.

Late-Quaternary volcanism and transtensional tectonics in the Bay of Naples, Campanian continental margin, Italy

Abstract: ¶The Campanian continental margin is characterised by asymmetric half grabens and large-volume volcanic deposits. Vesuvius and Campi Flegrei are active volcanoes located along the coast of Naples Bay along one of these half grabens. The interpretation of an extensive set of seismic reflection data allowed to reconstruct the stratigraphy and structural pattern in Naples Bay and their relationships with volcanism. The stratigraphic succession is characterised by a complex architecture due to the presence of 157 Ka old submarine and subaerial vents, pyroclastic flow units associated to the Campanian Ignimbrite and the Neapolitan Yellow Tuff, and numerous tuff cones younger than 12 Ka. These volcanic units occur within marine sediments deposited during the late Quaternary sea level oscillations. The structural pattern is characterised by late Quaternary NE- trending normal faults, NW-trending transtensional faults, E–W trending left-lateral faults and WNW-ESE directed folds. The overall fault kinematics and the evaluated very high displacement rates are consistent with an E-trending left-lateral transtensional shear zone located between 41° and 40° N latitude. The relationship between volcanism and tectonics in the Bay of Naples is explained with block rotation associated with this shear zone. Finally, tectonic and stratigraphic data argue against the occurrence of a caldera in the Bay of Naples.