Showing papers in "Environmental Earth Sciences in 2009"

Soil erosion prediction using the Revised Universal Soil Loss Equation (RUSLE) in a GIS framework, Chania, Northwestern Crete, Greece

Abstract: Soil erosion is a growing problem in southern Greece and particularly in the island of Crete, the biggest Greek island with great agricultural activity. Soil erosion not only decreases agricultural productivity, but also reduces the water availability. In the current study, an effort to predict potential annual soil loss has been conducted. For the prediction, the Revised Universal Soil Loss Equation (RUSLE) has been adopted in a Geographical Information System framework. The RUSLE factors were calculated (in the form of raster layers) for the nine major watersheds which cover the northern part of the Chania Prefecture. The R-factor was calculated from monthly and annual precipitation data. The K-factor was estimated using soil maps available from the Soil Geographical Data Base of Europe at a scale of 1:1,000,000. The LS-factor was calculated from a 30-m digital elevation model. The C-factor was calculated using Remote Sensing techniques. The P-factor in absence of data was set to 1. The results show that an extended part of the area is undergoing severe erosion. The mean annual soil loss is predicted up to ∼200 (t/ha year−1) for some watersheds showing extended erosion and demanding the attention of local administrators.

Accumulation of heavy metals in soil and uptake by plant species with phytoremediation potential

Abstract: Contamination of heavy metals represents one of the most pressing threats to water and soil resources, as well as human health. Phytoremediation can be potentially used to remediate metal contaminated sites. In this study, concentrations of copper, zinc, iron, and magnesium accumulated by native plant species were determined in field conditions of Hame Kasi iron and copper mine in the central part of Iran in Hamadan province. The results showed that metal accumulation by plants differed among species and tissue bodies. Species grown in substrata with elevated metals contained significantly higher metals in plants. Metals accumulated by plants were mostly distributed in root tissues, suggesting that an exclusion strategy for metal tolerance exists widely amongst them. The mentioned species could accumulate relatively higher metal concentrations far above the toxic concentration in the plant shoots. With high translocation factor, metal concentration ratio of plant shoots to roots indicates internal detoxification metal tolerance mechanism; thus, they have potential for phytoextraction. The factors affecting metal accumulation by plant species including metal concentrations, pH, electrical conductivity, and nutrient status in substrata were measured. Mostly, concentrations of zinc and copper in both aboveground and underground tissues of the plants were significantly, positively related to their total in substrata, while iron, zinc, and copper were negatively correlated to soil phosphorus.

GIS for the assessment of the groundwater recharge potential zone

Abstract: Water resources in Taiwan are unevenly distributed in spatial and temporal domains. Effectively utilizing the water resources is an imperative task due to climate change. At present, groundwater contributes 34% of the total annual water supply and is an important fresh water resource. However, over-exploitation has decreased groundwater availability and has led to land subsidence. Assessing the potential zone of groundwater recharge is extremely important for the protection of water quality and the management of groundwater systems. The Chih-Pen Creek basin in eastern Taiwan is examined in this study to assess its groundwater resources potential. Remote sensing and the geographical information system (GIS) are used to integrate five contributing factors: lithology, land cover/land use, lineaments, drainage, and slope. The weights of factors contributing to the groundwater recharge are derived using aerial photos, geology maps, a land use database, and field verification. The resultant map of the groundwater potential zone demonstrates that the highest recharge potential area is located towards the downstream regions in the basin because of the high infiltration rates caused by gravelly sand and agricultural land use in these regions. In contrast, the least effective recharge potential area is in upstream regions due to the low infiltration of limestone.

Evaluation of morphometric parameters of drainage networks derived from topographic maps and DEM in point of floods

Abstract: An evaluation of morphometric parameters of two drainage networks derived from different sources was done to determine the influence of sub-basins to flooding on the main channel in the Havran River basin (Balikesir-Turkey). Drainage networks for the sub-basins were derived from both topographic maps scaled 1:25.000 and a 10-m resolution digital elevation model (DEM) using geographic information systems (GIS). Blue lines, representing fluvial channels on the topographic maps were accepted as a drainage network, which does not depict all exterior links in the basin. The second drainage network was extracted from the DEM using minimum accumulation area threshold to include all exterior links. Morphometric parameters were applied to the two types of drainage networks at sub-basin levels. These parameters were used to assess the influence of the sub-basins on the main channel with respect to flooding. The results show that the drainage network of sub-basin 4—where a dam was constructed on its outlet to mitigate potential floods—has a lower influence morphometrically to produce probable floods on the main channel than that of sub-basins 1, 3, and 5. The construction of the dam will help reduce flooding on the main channel from sub-basin 4 but it will not prevent potential flooding from sub-basin 1, 3 and 5, which join the main channel downstream of sub-basin 4. Therefore, flood mitigation efforts should be considered in order to protect the settlement and agricultural lands on the floodplain downstream of the dam. In order to increase our understanding of flood hazards, and to determine appropriate mitigation solutions, drainage morphometry research should be included as an essential component to hydrologic studies.

CO2 absorption by alkaline soils and its implication to the global carbon cycle

Abstract: Motivated by the rapid increase in atmospheric CO2 due to human activities since the Industrial Revolution, and the climate changes it produced, the world’s concerned scientific community has made a huge effort to investigate the global carbon cycle. However, the results reveal that the global CO2 budget cannot be balanced, unless a “missing sink” is invoked. Although numerous studies claimed to find the “missing sink”, none of those claims has been widely accepted. This current study showed that alkaline soil on land are absorbing CO2 at a rate of 0.3–3.0μmolm−2s−1 with an inorganic, non-biological process. The intensity of this CO2 absorption is determined by the salinity, alkalinity, temperature and water content of the saline/alkaline soils, which are widely distributed on land. Further studies revealed that high salinity or alkalinity positively affected the CO2 absorbing intensity, while high temperature and water content had a negative effect on the CO2 absorbing intensity of these soils. This inorganic, non-biological process of CO2 absorption by alkaline soils might have significant implications to the global carbon budget accounting.

Contamination, chemical speciation and vertical distribution of heavy metals in soils of an old and large industrial zone in Northeast China

Abstract: Heavy metal pollution of soils has become a major concern in China as a consequence of rapid urbanization and industrialization in recent years. However, the evaluation on soil heavy metal pollution in Shenyang, the largest heavy industrial base city in China, has not yet been conducted. In this study, accumulation, chemical speciation, and vertical distribution Cu, Zn, Pb and Cd in soils were studied and pollution condition was assessed in Tiexi Industrial District of Shenyang, the largest and oldest industrial zone in Northeastern China. The results showed that in topsoil, the average concentration of total Cu, Zn, Pb, and Cd was 209.06, 599.92, 470.19 and 8.59 mg kg−1, respectively, much higher than the national threshold limit. The values of pollution index and integrated pollution index showed that the pollution level was Cd > Cu > Zn > Pb, and Cd, Cu and Zn belong to heavy pollution level. The residual, Fe and Mn oxide-bound, and organic-bound species accounted for about 90%, while carbonate-bound and exchangeable species accounted for about 10%. This study indicates that the soils in the industrial zone were widely and extremely polluted by multi-heavy metals as a result of long-term industrial activities.

Delineation of saltwater intrusion into the freshwater aquifer of Lekki Peninsula, Lagos, Nigeria

Abstract: Recently, the deterioration of water quality in the coastal zones of Lekki Peninsula area of Lagos due to saltwater infiltration into the freshwater aquifer has become a major concern. With the aim of providing valuable information on the hydrogeologic system of the aquifers, the subsurface lithology and delineating the groundwater salinity, vertical electrical resistivity (VES) sounding survey was carried out utilizing surface Schlumberger electrode arrays, and electrode spacing varying between 1 and 150m. The DC resistivity surveys revealed significant variations in subsurface resistivity. Also, the VES resistivity curves showed a dominant trend of decreasing resistivity with depth (thus increasing salinity). In general, the presence of four distinct resistivity zones were delineated viz.: the unconsolidated dry sand (A) having resistivity values ranging between 125 and 1,028Ωm represent the first layer; the fresh water-saturated soil (zone B) having resistivity values which correspond to 32–256Ωm is the second layer; the third layer (zone C) is interpreted as the mixing (transition) zone of fresh with brackish groundwater. The resistivity of this layer ranges from 4 to 32Ωm; while layer four (zone D) is characterized with resistivities values generally below 4Ωm reflecting an aquifer possibly containing brine. The rock matrix, salinity and water saturation are the major factors controlling the resistivity of the formation. Moreover, this investigation shows that saline water intrusion into the aquifers can be accurately mapped using surface DC resistivity method.

Hydrochemical characteristics and groundwater quality assessment in Tirupur Region, Coimbatore District, Tamil Nadu, India

Abstract: Groundwater samples from 62 locations have been collected from Tirupur region viz. Avinashi, Tirupur and Palladam taluks of Coimbatore District. The extensive agricultural industrial activities and urbanization resulted in the contamination of the aquifer. To study the contamination of groundwater, water samples were collected in an area of 180 km2 and analysed for major cations and anions. Most of the locations are contaminated by higher concentration of EC, TDS, K and NO3. Major hydro chemical facies were identified using Piper trilinear diagram. Based on US salinity diagram, most of the samples fall in the field of C3S1, indicating high salinity and low sodium water, which can be used for almost all types of soil with little danger of exchangeable sodium. Majority of the samples are not suitable for domestic purposes and far from drinking water standards. However, PI values indicates that groundwater is suitable for irrigation.

Geochemistry characterization of groundwater in an agricultural area of Razan, Hamadan, Iran

Abstract: This study was conducted to evaluate factors regulating groundwater quality in an area with agriculture as main use. Thirty groundwater samples have been collected from Razan area (Hamadan, Iran) for hydrochemical investigations to understand the sources of dissolved ions and assess the chemical quality of the groundwater. The chemical compositions of the groundwater are dominated by Na+, Ca2+, HCO3 −, Cl− and SO4 2−, which have been derived largely from natural chemical weathering of carbonate, gypsum and anthropogenic activities of fertilizer’s source. The production of SO4 2− has multiple origins, mainly from dissolution of sulphate minerals, oxidation of sulphide minerals and anthropogenic sources. The major anthropogenic components in the groundwater include Na+, Cl−, SO4 2− and NO3 −, with Cl− and NO3 − being the main contributors to groundwater pollution in Razan area.

The impact of disposal and treatment of coal mining wastes on environment and farmland.

Abstract: In China, coal mining wastes have traditionally been dumped in cone-shaped heaps that have the potential to pollute air, soil and water environments and landscapes through dust generation, leachate production, self-ignition and as a consequence of an absence of vegetation cover. Since 1980s, the disposal technique for coal mining wastes has been changing and in many instances the wastes are now transported directly to subsided land as a fill to enable the reuse of that land. Thus, today, both coal mining waste dumps from the past and filled subsided lands are in existence. However, the comparative impacts of these different disposal techniques on the environment and farmland productivity have not been studied in detail. Using Dongtan (DT), Nantun (NT) and Xinglongzhuang (XLZ) coal mines as examples, the components of coal mining wastes and their potential pollution contribution to soil, surface water and ground water are tested in-situ. The results show that contaminants are released after self-ignition and weathering of coal mining wastes, but they are not above the allowable environmental standards. However, despite these findings, more and closer attention needs to be paid to the mobility, transportation and accumulation of these contaminants in the environment over time.

Hydrogeochemical processes in the groundwater environment of Muktsar, Punjab: conventional graphical and multivariate statistical approach

Abstract: Understanding the hydrogeochemical processes that govern groundwater quality is important for sustainable management of the water resource A study with the objective of identifying the hydro-geochemical processes and their relation with existing quality of groundwater was carried out in an intensively cultivated district of Punjab, India The study approach includes conventional graphical plots and multivariate analysis of the hydrochemical data to define the geochemical evaluation of aquifer system based on the ionic constituents, water types, hydrochemical facies and factors controlling groundwater quality The results suggest that different natural hydrogeochemical processes like simple dissolution, mixing, weathering of carbonate minerals locally known as “kankar” silicate weathering and ion exchange are the key factors in the pre-monsoon, which was superseded by leaching processes loaded with anthropogenic inputs in the post-monsoon Limited reverse ion exchange has been noticed at few locations of the study area especially in pre-monsoon periods There was a significant effect of monsoon observed in terms of hardness and the significant amount of area with temporary hardness (Ca2+–Mg2+–HCO3- type) in the pre-monsoon switched to permanent hardness domain, ie (Ca2+–Mg2+–Cl− type) by the post-monsoon At most, factor analyses substantiate the findings of conventional graphical plots and provide greater confidence in data-interpretation Thus, the study highlights the descriptive capabilities of conventional and multivariate techniques as effective tools in groundwater evaluation

A framework for karst ecohydrology

Abstract: Ecohydrology can be defined as the science of integrating hydrological and biological processes over varied spatial and temporal scales. There exists in karst a strong and direct interaction between the circulation and storage of groundwater and surface water. These fluxes in turn affect the spatial distribution of organisms in these habitats. Because of the fact that the appearance, storage and circulation of water in karstified areas is significantly different from other more homogenous and isotropic terrains, karst ecohydrology should develop original methods and approaches. At the same time, traditional approaches are also very useful. Large karst underground geomorphological patterns occur in many sizes and varieties, ranging from a few meters long or deep to very large, the deepest being deeper than 1km and longer than hundreds of kilometres. In this article, special attention is paid to ecohydrological functions of karst underground features (caves, pits, conduits, etc.), which play a crucial dual role in (1) hydrology and hydrogeology of water circulation and storage and (2) ecology of many rare and endangered species. Differences in morphology, hydrology, hydrogeology and climate have resulted in a range of different environments, which provide the opportunity for the coexistence of different species. The role of the epikarst and vadose zones, as well as caves in ecohydrological processes, is discussed. The importance of the flood factor in karst ecology is analysed. The aim of this article is to move forward the discussion among different disciplines to promote and develop a conceptual framework for karst ecohydrology.

Mapping soil erosion susceptibility using remote sensing and GIS : a case of the Upper Nam Wa Watershed, Nan Province, Thailand

Abstract: Land degradation is still a very common problem in the mountains of Asia because of inappropriate land use practice in steep topography. Many studies have been carried out to map shifting cultivation and areas susceptible to soil erosion. Mostly, estimated soil loss is taken as the basis to classify the level of soil loss susceptibility of area. Factors that influence soil erosion are: rainfall erosivity, soil erodibility, slope length and steepness, crop management and conservation practices. Thus the reliability of estimated soil loss is based on how accurately the different factors were estimated or prepared. As each and every small pixel of our earth surface is different from one area to another, the manner in which the study area was discretized into smaller homogenous sizes and how the most accurate and efficient technique were adopted to estimate the soil loss are very important. The purpose of this study is to produce erosion susceptibility maps for an area that has suffered because of shifting cultivation located in the mountainous regions of Northern Thailand. For this purpose, an integrated approach using RS and GIS-based methods is proposed. Data from the Upper Nam Wa Watershed, a mountainous area of the Northern Thailand were used. An Earth Resources Data Analysis System (ERDAS) imagine image processor has been used for the digital analysis of satellite data and topographical analysis of the contour data for deriving the land use/land cover and the topographical data of the watershed, respectively. ARCInfo and ARCView have been used for carrying out geographical data analysis. The watershed was discretized into hydrologically, topographically, and geographically homogeneous grid cells to capture the watershed heterogeneity. The soil erosion in each cell was calculated using the universal soil loss equation (USLE) by carefully determining its various parameters and classifying the watershed into different levels of soil erosion severity. Results show that during the time of this study most of the areas under shifting cultivation fell in the highest severity class of susceptibility.

Assessing the impacts of land use changes on watershed hydrology using MIKE SHE

Abstract: A fully distributed, physically-based hydrologic modeling system, MIKE SHE, was used in this study to investigate whole-watershed hydrologic response to land use changes within the Gyeongancheon watershed in Korea. A grid of 200 × 200 m was established to represent spatial variations in geology, soil, and land use. Initial model performance was evaluated by comparing observed and simulated streamflow from 1988 to 1991. Results indicated that the calibrated MIKE SHE model was able to predict streamflow well during the calibration and validation periods. Proportional changes in five classes of land use within the watershed were derived from multi-temporal Landsat TM imageries taken in 1980, 1990 and 2000. These imageries revealed that the watershed experienced conversion of approximately 10% non-urban area to urban area between 1980 and 2000. The calibrated MIKE SHE model was then programmed to repeatedly analyze an artificial dataset under the various land use proportions identified in the Landsat TM imageries. The analysis was made to quantitatively assess the impact of land use changes (predominantly urbanization) on watershed hydrology. There were increases in total runoff (5.5%) and overland flow (24.8%) as a response to the land use change.

Arsenic and fluoride in a loess aquifer in the central area of Argentina

Abstract: The objective of this study is to analyze the geochemical conditions associated with the presence of arsenic (As) and fluoride (F) in the phreatic aquifer of Coronel Moldes, in the central sector of the Argentine Chacopampean plain. The studied aquifer is composed of silty sand sediments of aeolian origin, typically loess-like sediments. The geochemical composition of water varies from sodium bicarbonate to sodium sulfate-chloride water. As contents range from low concentrations, below detection level, to 250 μg/l. High values of F (up to 12 mg/l) were recorded. A high As–F correlation was found (R 2 = 0.84). The pH varied from 7.31 to 8.85 and the nitrates reached concentrations up to 200 mg/l, indicating an oxidant environment. The highest values of As and F agreed with sodium bicarbonate waters as well as with the highest values of pH recorded. There was a high correlation between As and F− as well as between As and the Na/Ca ratio. The composition and texture of loess, low permeability and hydraulic gradients together with the geochemical features of sodium bicarbonate waters are proper conditions for the mobilization of As and F in groundwater in the central area of Argentina.

The influence of topography and land use on water quality of Xiangxi River in Three Gorges Reservoir region

Abstract: A self-organizing map (SOM) was used to cluster the water quality data of Xiangxi River in the Three Gorges Reservoir region. The results showed that 81 sampling sites could be divided into several groups representing different land use types. The forest dominated region had low concentrations of most nutrient variables except COD, whereas the agricultural region had high concentrations of NO3N, TN, Alkalinity, and Hardness. The sites downstream of an urban area were high in NH3N, NO2N, PO4P and TP. Redundancy analysis was used to identify the individual effects of topography and land use on river water quality. The results revealed that the watershed factors accounted for 61.7% variations of water quality in the Xiangxi River. Specifically, topographical characteristics explained 26.0% variations of water quality, land use explained 10.2%, and topography and land use together explained 25.5%. More than 50% of the variation in most water quality variables was explained by watershed characteristics. However, water quality variables which are strongly influenced by urban and industrial point source pollution (NH3N, NO2N, PO4P and TP) were not as well correlated with watershed characteristics.

Drinking water quality in villages of southwestern Haryana, India: assessing human health risks associated with hydrochemistry

Abstract: The chemical quality of groundwater of western Haryana, India was assessed for its suitability for drinking purposes. A total of 275 water samples were collected from deep aquifer based hand-pumps situated in 37 different villages/towns of Bhiwani region. The water samples were analyzed for different physico-chemical properties, e.g., pH, total dissolved solids (TDS), total harness (TH), total alkalinity (TA), calcium, magnesium, carbonate, bicarbonate, sulphate, chloride and fluoride concentrations. In this study, the average TDS content was greater ranging 1,692 (Bhiwani block) to 2,560 mg l−1 (Siwani block), and other important parameters of water, e.g., TA (442–1,232 mg l−1), TH (437–864 mg l−1) and bicarbonate (554–672 mg l−1), were also higher than maximum permissible limit by WHO or BIS. The fluoride appeared as a major problem of safe drinking water in this region. We recorded greater fluoride concentration, i.e., 86.0 mg l−1 from Motipura village that is highest fluoride level ever recorded for Haryana state. The average fluoride concentration ranged between 7.1 and 0.8 mg l−1 in different blocks of western Haryana. On the basis of fluoride concentration, Siwani block showed the maximum number of water samples (84% of total collected samples) unsuitable for drinking purposes (containing fluoride >1.5 mg l−1) followed by Charki Dadri block (58%), Bhiwani block (52%), Bawani Khera block (33%) and Loharu block (14%). This study clearly suggest that some health deteriorating chemicals in drinking water were at dangerous level and; therefore, water quality could be a major health threat for local residents of western Haryana. The high fluoride level in drinking water has posed some serious dental health risks in local residents.

Groundwater vulnerability assessment in shallow aquifer of Kathmandu Valley using GIS-based DRASTIC model

Abstract: In this paper, groundwater aquifer vulnerability map has been developed by incorporating the major geological and hydro-geological factors that affect and control the groundwater contamination using GIS based DRASTIC model. This work demonstrates the potential of GIS to derive a map by overlying various spatially referenced digital data layers that portrays cumulative aquifer sensitivity ratings across the Kathmandu Valley, Nepal, providing a relative indication of groundwater vulnerability to contamination. In fact, the groundwater is the major natural resources in Kathmandu for drinking purpose. The decline in groundwater levels due to the over exploitation and thus extracted water from shallow aquifer has been contaminated by the infiltration of pollutants from polluted river and land surface is continuous and serious. As the demand for water for human and industrial use has escalated and at the same time, the engineering and environmental costs are much higher for new water supplies than maintaining the existing sources already in use. Management of groundwater source and protecting its quality is therefore essential to increase efficient use of existing water supplies. Aquifer vulnerability maps developed in this study are valuable tools for environmental planning and predictive groundwater management. Further, a sensitivity analysis has been performed to evaluate the influence of single parameters on aquifer vulnerability assessment such that some subjectivity can be reduced to some extent and then new weights have been computed for each DRASTIC parameters.

Environmental impact assessment of open pit mining in Iran

Abstract: Mining is widely regarded as having adverse effects on environment of both magnitude and diversity. Some of these effects include erosion, formation of sinkhole, biodiversity loss and contamination of groundwater by chemical from the mining process in general and open-pit mining in particular. As such, a repeatable process to evaluate these effects primarily aims to diminish them. This paper applies Folchi method to evaluate the impact of open-pit mining in four Iranian mines that lacked previous geo-environmental assessment. Having key geologic resources, these mines are: Mouteh gold mine, Gol-e-Gohar and Chogart iron mines, and Sarcheshmeh copper mine. The environmental components can be defined as public health and safety, social relationships, air and water quality, flora and fauna hence, various impacting factors from the mining activities were estimated for each environmental component. For this purpose, each impacting factor was first given a magnitude, based solely on the range of possible scenarios. Thereafter, a matrix of weighted factors was derived to systematically quantify and normalize the effects of each impacting factor. The overall impact upon each individual environmental component was then calculated by summing the weighted rates. Here, Folchi method was applied to evaluate those environmental conditions. Based on the acquired results, the present paper finally concludes that amongst four case histories in Iran, Sarcheshmeh copper mine significantly affects the environment, with critical level of air pollution there.

Estimation of soil compaction parameters by using statistical analyses and artificial neural networks

Abstract: This study presents the application of different methods (simple–multiple analysis and artificial neural networks) for the estimation of the compaction parameters (maximum dry unit weight and optimum moisture content) from classification properties of the soils. Compaction parameters can only be defined experimentally by Proctor tests. The data collected from the dams in some areas of Nigde (Turkey) were used for the estimation of soil compaction parameters. Regression analysis and artificial neural network estimation indicated strong correlations (r 2 = 0.70–0.95) between the compaction parameters and soil classification properties. It has been shown that the correlation equations obtained as a result of regression analyses are in satisfactory agreement with the test results. It is recommended that the proposed correlations will be useful for a preliminary design of a project where there is a financial limitation and limited time.

Soil erosion modeling of a Himalayan watershed using RS and GIS

Abstract: Employing the remote sensing (RS) and geographical information system (GIS), an assessment of sediment yield from Dikrong river basin of Arunachal Pradesh (India) has been presented in this paper. For prediction of soil erosion, the Morgan-Morgan and Finney (MMF) model and the universal soil loss equation (USLE) have been utilized at a spatial grid scale of 100 m × 100 m, an operational unit. The average annual soil loss from the Dikrong river basin is estimated as 75.66 and 57.06 t ha−1 year−1 using MMF and USLE models, respectively. The watershed area falling under the identified very high, severe, and very severe zones of soil erosion need immediate attention for soil conservation.

Current perspectives on the environmental impacts and hazards in karst

Abstract: Karst geo-ecosystems are highly fragile environments that are suffering a progressive degradation caused by human activities in many regions of our planet. The interactions between Man and karst environments have been relevant since Greek and Roman times (Nicod et al. 1997), but the resulting detrimental effects became particularly significant from the industrial revolution. Despite the long history of human-induced impacts on the karst environments and damage caused by hazardous karst processes, these problems were largely overlooked by the scientific community till the beginning of the 90s. Fortunately, both the perception of the importance of the karst systems and the scientific efforts devoted to their understanding have increased considerably in recent times (Ford and Williams 2007). The results of some investigations have been published in several special issues (Catena supplement, Environmental Geology, Oklahoma Geological Survey Circular, Geological Society of London Special Publication, Engineering Geology) (Williams et al. 1993; Burri et al. 1999; Johnson and Neal 2003; Parise and Gunn 2007; Gutierrez et al. 2008c; Parise et al. 2008) and conference proceedings (Sauro et al. 1991; Beck 2003). Subsidence related to sinkhole activity is the most important hazard in karst landscapes (Beck 2003; Waltham et al. 2005). In many regions, financial losses caused by sinkholes are raising considerably due to the humaninduced increase in the probability of occurrence of sinkholes and the development of hazardous areas (Gutierrez et al. 2008a). Some approaches including, mechanical, hydrogeological and predictive modelling (Salvati and Sasowsky 2002; He et al. 2004), geophysical surveys (Ardau et al. 2007), speleological studies (Klimchouk et al. 2002) and palaeokarst investigations (Gutierrez et al. 2008b) have provided enlightening insights on the processes involved in the subsidence phenomena. Other typical environmental problems in karst terrains are related to water quality and quantity (Drew and Hotzl 1999; Goldscheider and Drew 2007; Ravbar 2007), construction of infrastructures (dams, highways, tunnels) (Milanovic 2002), mining and quarrying (Gunn 2004) and other human activities such as, agriculture, waste disposal or urbanisation. This special issue of Environmental Geology contains a selection of peer-reviewed articles presented at the symposium on ‘‘Natural and Anthropogenic Hazards in Karst Areas’’, held in Vienna, Austria, on 16 April 2007, within the framework of the Natural Hazards Programme of the European Geosciences Union General Assembly. The symposium was co-sponsored by the International Union of Speleology (UIS) and by the International Geographical Union (IGU) Commission of Karst Hydrogeology and Speleogenesis. Out of the 35 contributors to the session, 22 accepted the invitation to submit a full paper and finally, 15 peerreviewed articles have been accepted and included in this special issue. They cover many different geographical areas where the interaction between karst systems and human activities results in significant environmental impacts and hazards: Europe (Austria, Bosnia M. Parise (&) National Research Council, IRPI, Bari, Italy e-mail: m.parise@ba.irpi.cnr.it

From radon hazard to risk prediction-based on geological maps, soil gas and indoor measurements in Germany

Abstract: Mapped geological units can be regarded as proxies standing for a complex series of subsoil geochemical and physical properties including the assigned radon activity concentration in soil gas, which is taken as best estimator of the regional geogenic radon potential. Areal distribution of measuring sites for soil gas in Germany is adapted to spatial variation of geology. A grid-based and distance-weighted interpolation procedure is applied, following geologically defined neighbourhood relations of measuring sites and accounting for isolated outcrops of known geology but without measurements. To investigate the statistical relationship between indoor radon, house type and building ground specifications, measurements of the indoor radon concentration have been carried out in more than 10,000 dwellings in different regions of Germany. Multiple regression analyses of variance reveal that besides region-specific geological properties and building characteristics, various house type and living style variables significantly contribute to the explained variance for ground floor radon concentrations. These parameters are also dominant in controlling the radon transfer relation from soil gas to indoor air. Risk prediction maps for radon in houses indicating the probability to exceed certain indoor threshold values can be useful especially for regions with no or only a few measurements of indoor radon.

A modeling study of seawater intrusion in Alabama Gulf Coast, USA

Abstract: A numerical model of variable-density groundwater flow and miscible salt transport is developed to investigate the extent of seawater intrusion in the Gulf coast aquifers of Alabama, USA. The SEAWAT code is used to solve the density-dependent groundwater flow and solute transport governing equations. The numerical model is calibrated against the observed hydraulic heads measured in 1996 by adjusting the zonation and values of hydraulic conductivity and recharge rate. Using the calibrated model and assuming all the hydrogeologic conditions remain the same as those in 1996, a predictive 40-year simulation run indicates that further seawater intrusion into the coastal aquifers can occur in the study area. Moreover, the predicted intrusion may be more significant in the deeper aquifer than the shallower ones. As the population continues to grow and the demand for groundwater pumping intensifies beyond the 1996 level, it can be expected that the actual extent of seawater intrusion in the future would be more severe than the model prediction. Better strategies for groundwater development and management will be necessary to protect the freshwater aquifers from contamination by seawater intrusion.

History of landslide susceptibility and a chorology of landslide-prone areas in the Western Ghats of Kerala, India

Abstract: Kerala is the third most densely populated state in India. It is a narrow strip of land, of which 47% is occupied by the most prominent orographic feature of peninsular India, The Western Ghats mountain chain. The highlands of Kerala experience several types of landslides, of which debris flows are the most common. They are called “Urul Pottal” in the local vernacular. The west-facing Western Ghats scarps that runs the entire extent of the mountain system is the most prone physiographic unit for landslides. The highlands of the region experience an annual average rainfall as high as 500 cm through the South-West, North-East and Pre-Monsoon showers. A survey of ancient documents and early news papers indicates a reduced rate of slope instability in the past. The processes leading to landslides were accelerated by anthropogenic disturbances such as deforestation since the early 18th century, terracing and obstruction of ephemeral streams and cultivation of crops lacking capability to add root cohesion in steep slopes. The events have become more destructive given the increasing vulnerability of population and property. Majority of mass movements have occurred in hill slopes >20° along the Western Ghats scarps, the only exception being the coastal cliffs. Studies conducted in the state indicates that prolonged and intense rainfall or more particularly a combination of the two and the resultant pore pressure variations are the most important trigger of landslides. The initiation zone of most of the landslides was typical hollows generally having degraded natural vegetation. A survey of post-landslide investigation and news paper reports enabled the identification of 29 major landslide events in the state. All except one of the 14 districts in the state are prone to landslides. Wayanad and Kozhikode districts are prone to deep seated landslides, while Idukki and Kottayam are prone to shallow landslides.

Environmental changes after ecological water conveyance in the lower reaches of Heihe River, northwest China

Abstract: This paper analyzed the dynamic change of the groundwater level by 6 years’ monitoring in field monitoring and the change of vegetation by the field survey and satellite remote sensing after watering in the lower reaches of Heihe River. The findings indicated: (1) the groundwater level elevation and the plant growth are closely related to the volume and the duration of watering. In general, groundwater level elevates dramatically and plants are growing much more vigorously after watering; (2) Watering incidence on groundwater keeps extending with the watering times increasing; (3) Plants grew rapidly in 100–400 m away from the water channel after watering. Watering incidence on vegetation reached 1,000 m; (4) In terms of the function and structure of ecosystem after watering in the lower reaches of Heihe River, the ecological water conveyance does not still reach the goal of ecological restoration at a large spatial scale at present. In addition, in order to solve fundamentally the problem of ecological environment worsens in the lower reaches of Heihe River, some suggestions and countermeasures are put forward.

Water quality deterioration at a karst spring (Gallusquelle, Germany) due to combined sewer overflow: evidence of bacterial and micro-pollutant contamination

Abstract: The concurrent use of karst aquifers as drinking water resources and receptors of combined sewer overflow lacking appropriate pre-treatment may cause conflicts between drinking water supply and storm water management. A storm water tank (SWT) for combined wastewater is identified as the source of sporadic contamination of a karst spring (Gallusquelle, “Schwabische Alb”, SW Germany) used for public water supply. Spring water quality was examined by routine and event sampling and by evaluating physicochemical and microbiological parameters. The total number of microbial colonies growing at 20°C and the number of Escherichia coli colonies rose to values up to four orders of magnitude higher than background, 2–5 days after overflow of the SWT. High concentrations of chloride, sodium, and total organic carbon (TOC) and high values of turbidity coincide with this increase. However, high bacterial contamination is also observed while turbidity and TOC are low. Several wastewater-related organic micro-pollutants such as chlorinated and non-chlorinated organophosphates were detected in the SWT and, depending on their K ow values and their biodegradability, in lower concentrations at the spring.

The effect of possible climate change on natural groundwater recharge based on a simple model: a study of four karstic aquifers in SE Spain

Abstract: The study presented in this paper constitutes an initial approach to the problematic task of evaluating the effects of possible climate change on natural water recharge to aquifers. To estimate such effects, a purpose-designed mathematical model termed Estimation of Recharge in Over-exploited Aquifers (ERAS) has been used. It enables to simulate the monthly water recharge to an aquifer, provided that prior knowledge of the exploitation to which it is subjected and the variation caused by these two actions on the piezometric level of the aquifer is available. The basic data required for its application are: precipitation, temperature, groundwater extraction, stored groundwater surface and storage coefficient. The main advantage presented by this model is its independence of the mechanism by which water is displaced through the ground and within the unsaturated zone. The ERAS code was applied to four over-exploited karstic aquifers in Alto Vinalopo (Alicante, Spain) with the goal of generating a synthesized series of values for natural groundwater recharge in each of the aquifers for the 100 years of the twentieth century. Each series thus obtained after being grouped into decades was subjected to statistical processing, which revealed that in every case a logarithmically decreasing trend was present.

Hydrogeochemical study in the Main Ethiopian Rift: new insights to the source and enrichment mechanism of fluoride

Abstract: The central Main Ethiopian Rift suffers a severe water quality problem, characterized by an anomalously high fluoride (F) content that causes an endemic fluorosis disease. The current study, conducted in the Ziway–Shala lakes basin, indicates that the F content exceeds the permissible limit for drinking prescribed by the World Health Organization (WHO; 1.5 mg/l) in many important wells (up to 20 mg/l), with even more extreme F concentration in hot springs and alkaline lakes (up to 97 and 384 mg/l respectively). The groundwater and surface water from the highlands, typically characterized by low total dissolved solids (TDS) and Ca (Mg)–HCO3 hydrochemical facies, do not show high F content. The subsequent interaction of these waters with the various rocks of the rift valley induces a general increase of the TDS, and a variation of the chemical signature towards Na–HCO3 compositions, with a parallel enrichment of F. The interacting matrixes are mainly rhyolites consisting of volcanic glass and only rare F-bearing accessory minerals (such as alkali amphibole). Comparing the abundance and the composition of the glassy groundmass with other mineral phases, it appears that the former stores most of the total F budget. This glassy material is extremely reactive, and its weathering products (i.e. fluvio/volcano-lacustrine sediments) further concentrate the fluoride. The interaction of these “weathered/reworked” volcanic products with water and carbon dioxide at high pH causes the release of fluoride into the interacting water. This mainly occurs by a process of base-exchange softening with the neo-formed clay minerals (i.e. Ca–Mg uptake by the aquifer matrix, with release of Na into the groundwater). This is plausibly the main enrichment mechanism that explains the high F content of the local groundwater, as evidenced by positive correlation between F, pH, and Na, and inverse correlation between F and Ca (Mg). Saturation indices (SI) have been calculated (using PHREEQC-2) for the different water groups, highlighting that the studied waters are undersaturated in fluorite. In these conditions, fluoride cannot precipitate as CaF2, and so mobilizes freely without forming other complexes. These results have important implications for the development of new exploitation strategies and accurate planning of new drilling sites.

Predictive landslide susceptibility mapping using spatial information in the Pechabun area of Thailand

Abstract: For predictive landslide susceptibility mapping, this study applied and verified probability model, the frequency ratio and statistical model, logistic regression at Pechabun, Thailand, using a geographic information system (GIS) and remote sensing. Landslide locations were identified in the study area from interpretation of aerial photographs and field surveys, and maps of the topography, geology and land cover were constructed to spatial database. The factors that influence landslide occurrence, such as slope gradient, slope aspect and curvature of topography and distance from drainage were calculated from the topographic database. Lithology and distance from fault were extracted and calculated from the geology database. Land cover was classified from Landsat TM satellite image. The frequency ratio and logistic regression coefficient were overlaid for landslide susceptibility mapping as each factor’s ratings. Then the landslide susceptibility map was verified and compared using the existing landslide location. As the verification results, the frequency ratio model showed 76.39% and logistic regression model showed 70.42% in prediction accuracy. The method can be used to reduce hazards associated with landslides and to plan land cover.