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Bright and ultimately pure red electrophosphorescent diode bearing diphenylquinoxaline

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TLDR
The ultimately pure red OLED using new electrophosphorescent compound, bis(2,3-diphenylquinoxaline)iridium(acetylace-tonate) [(QH)2 Ir(acac]], which is the closest to the ultimate limit of pure red among reported OLEDs, was attained and maintained even in luminance brighter than 600cd/m2.
Abstract
The ultimately pure red OLED using new electrophosphorescent compound, bis(2,3-diphenylquinoxaline)iridium(acetylace-tonate) [(QH)2 Ir(acac)] is described. Electrophosphorescence peak wavelength and bandwidth were advanced for the purest red color stimulus to 680nm with full width at half maximum of 89nm by doping (QH)2 Ir(acac) into a light emitting electron transport layer composed of 3-(4-biphenylyl)-4-phenyl-5-(4-tert-butylphenyl)-1,2,4-triazole. The most vivid red electrophosphorescence with CIE chromaticity coordinates better than x=0.70 and y=0.28, which are the closest to the ultimate limit of pure red among reported OLEDs, was attained and maintained even in luminance brighter than 600cd/m2. A very high maximum external electrophosphorescent quantum efficiency of 10.2% was also realized.

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Journal ArticleDOI

Red-Light-Emitting Iridium Complexes with Hole-Transporting 9-Arylcarbazole Moieties for Electrophosphorescence Efficiency/Color Purity Trade-off Optimization

TL;DR: In this article, the synthesis, structures, photophysics, electrochemistry and electrophosphorescent properties of new red phosphorescent cyclometalated iridium(III) isoquinoline complexes, bearing 9-aryl carbazolyl chromophores, are reported.
Journal ArticleDOI

Efficient and long-time stable red iridium(III) complexes for organic light-emitting diodes based on quinoxaline ligands.

TL;DR: Three heteroleptic orange-red phosphorescent iridium(III) complexes bearing two 2-(4-fluorophenyl)-3-methyl-quinoxaline (fpmqx) cyclometalated ligands combined with three different ancillary ligands, triazolylpyridine (trz), picolinate (pic), and acetylacetonate (acac) are reported on.
Journal ArticleDOI

Highly efficient, deep-red organic light-emitting devices using energy transfer from exciplexes

TL;DR: In this article, the authors developed a highly efficient, deep-red organic light-emitting device with an external quantum efficiency of nearly 18% with a very low turn-on voltage of 2.41 V and an electroluminescence emission wavelength (λEL) of 670 nm using energy transfer from an exciplex host to a deep red phosphorescent emitter, bis(2,3-diphenylquinoxaline)iridium(dipivaloylmethane)[(DPQ)2Ir(dpm)].
Journal ArticleDOI

Rational Design and Characterization of Heteroleptic Phosphorescent Complexes for Highly Efficient Deep-Red Organic Light-Emitting Devices.

TL;DR: Density function theory (DFT) calculations and electrochemical measurements support the genuine pure red phosphorescent emission of fIr1 and dfIr2 based on their clearly distinct electron density distributions of the HOMO/LUMO orbitals compared with other red-emitting Ir(III) derivatives.
Reference EntryDOI

Luminescence Phenomena Involving Metal Enolates

TL;DR: In this paper, the luminescence of rare-earth enolates was investigated for bioassays using time-resolved detection of luminecence for bio-assays.
References
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Journal ArticleDOI

Very high-efficiency green organic light-emitting devices based on electrophosphorescence

TL;DR: In this paper, the performance of an organic light-emitting device employing the green electrophosphorescent material, fac tris(2-phenylpyridine) iridium [Ir(ppy)3] doped into a 4,4′-N,N′-dicarbazole-biphenyl host was described.
Journal ArticleDOI

Electroluminescence of doped organic thin films

TL;DR: In this paper, a multilayer-doped EL was constructed using a hole-transport layer and a luminescent layer, and the electron-hole recombination and emission zones can be confined to about 50 A near the hole.
Journal ArticleDOI

Highly phosphorescent bis-cyclometalated iridium complexes: synthesis, photophysical characterization, and use in organic light emitting diodes.

TL;DR: The synthesis and photophysical study of a family of cyclometalated iridium(III) complexes are reported, and three of the C(**)N2Ir(acac) complexes were used as dopants for organic light emitting diodes (OLEDs) and show some of the highest efficiencies reported for organic Light Emitting Diodes.
Journal ArticleDOI

High-efficiency red electrophosphorescence devices

TL;DR: In this article, the authors demonstrate high-efficiency red electrophosphorescent organic light-emitting devices employing bis(2′-benzo[4,5-a]thienyl)pyridinato-N,C3′) iridium(acetylacetonate) [Btp2Ir(acac)] as a red phosphor.
Journal ArticleDOI

High-efficiency and low-voltage p‐i‐n electrophosphorescent organic light-emitting diodes with double-emission layers

TL;DR: In this article, a double-emission layer (D-EML) was incorporated into p-i-n-type cell architecture to achieve high-efficiency organic light-emitting diodes.
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