Journal ArticleDOI
Catalytic hydrogenation of C=C and C=O in unsaturated fatty acid methyl esters
TLDR
In this paper, the authors summarized recent developments in hydrogenation of CC and CO in FAMEs with focus on catalysts, reaction mechanisms, and reactor conditions, and the opportunities for future research in the field are outlined.About:
This article is published in Catalysis Science & Technology.The article was published on 2014-07-07. It has received 48 citations till now. The article focuses on the topics: Unsaturated fatty acid & Biodiesel.read more
Citations
More filters
Journal ArticleDOI
Heterogeneous and homogeneous catalysis for the hydrogenation of carboxylic acid derivatives: history, advances and future directions
James Charles Pritchard,Georgy A. Filonenko,Robbert van Putten,Emiel J. M. Hensen,Evgeny A. Pidko +4 more
TL;DR: This Review focuses on the mechanistic aspects of the catalytic hydrogenation and highlights the bifunctional nature of the mechanism that is preferred for supported metal catalysts as well as homogeneous transition metal complexes.
Journal ArticleDOI
The Surface Chemistry of Metal-Based Hydrogenation Catalysis
TL;DR: In this paper, the authors discuss the state-of-the-art of our understanding of some of the fundamental issues associated with hydrogenation catalysis, and assess the status of our knowledge on the adsorption of the organic reactants, the role that strongly adsorbed carbonaceous deposits that form during reaction play in defining the catalytic kinetics, the mechanistic details of the hydrogen dissociative uptake and surface mobility during reaction, and the dynamic changes of the st...
Journal ArticleDOI
Catalytic Total Hydrodeoxygenation of Biomass‐Derived Polyfunctionalized Substrates to Alkanes
TL;DR: The total hydrodeoxygenation of carbohydrate-derived molecules to alkanes, a key reaction in the production of biofuel, was reviewed from the aspect of catalysis.
Journal ArticleDOI
Methods for improving the cold flow properties of biodiesel with high saturated fatty acids content: A review
TL;DR: In this article, a review of the cold flow properties of biodiesel can be found in a mixture of oils with a high content of unsaturated fatty acids, oil fractionation, Alkyl esters structure modification and additive use.
Journal ArticleDOI
Guidelines to Achieving High Selectivity for the Hydrogenation of α,β-Unsaturated Aldehydes with Bimetallic and Dilute Alloy Catalysts: A Review.
Mathilde Luneau,Jin Soo Lim,Dipna A. Patel,E. Charles H. Sykes,Cynthia M. Friend,Philippe Sautet +5 more
TL;DR: This comprehensive review focuses primarily on the role of different metal surfaces as well as the factors that promote the adsorption of the unsaturated aldehyde via its C═O bond, most notably by electronic modification of the surface and formation of the electrophilic sites.
References
More filters
Journal ArticleDOI
Technical aspects of biodiesel production by transesterification—a review
TL;DR: In this paper, various methods of preparation of biodiesel with different combination of oil and catalysts have been described and technical tools and processes for monitoring the transesterification reactions like TLC, GC, HPLC, GPC, 1H NMR and NIR have also been summarized.
Journal ArticleDOI
Recent advances in catalytic hydrogenation of carbon dioxide
TL;DR: A critical review of recent developments in hydrogenation reaction, with emphases on catalytic reactivity, reactor innovation, and reaction mechanism, provides an overview regarding the challenges and opportunities for future research in the field.
Reference BookDOI
Bailey's Industrial oil and fat products
TL;DR: Shahidi et al. as mentioned in this paper proposed a method for the analysis of Fats and Oils and showed that the method can be used to identify the components of a particular type of fat.
Journal ArticleDOI
A review on biodiesel production using catalyzed transesterification
TL;DR: In this article, the main factors affecting the yield of biodiesel, i.e. alcohol quantity, reaction time, reaction temperature and catalyst concentration, are discussed, as well as new new processes for biodiesel production.
Journal ArticleDOI
Combustion of fat and vegetable oil derived fuels in diesel engines
TL;DR: In this paper, the status of fat and oil derived diesel fuels with respect to fuel properties, engine performance, and emissions is reviewed, and it is concluded that the price of the feedstock fat or oil is the major factor determining biodiesel price.