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Chemically converted graphene: Scalable chemistries to enable processing and fabrication

TLDR
Wallace et al. as discussed by the authors reviewed a wide range of scalable chemistries that potentially could be used to produce processable Graphene, including aqueous and organic solvents, and discussed the differences between natural and synthetic graphite, the necessary steps for converting them into graphene and how graphene can be used for producing composites.
Abstract
There now exists a wide range of scalable chemistries that potentially could be used to produce processable graphene. Graphene holds a lot of promise, but before it can be used commercially, methods are needed for producing processable forms of graphene in scalable amounts and also for incorporating graphene in devices. Gordon Wallace and co-workers at the ARC Centre of Excellence for Electromaterials Science, University of Wollongong in Australia comprehensively review the various chemistries available for chemically converting graphite into graphene. In particular, they consider suitable chemistries for developing graphene dispersions in aqueous and organic solvents and their use for preparing various polymer composites, which can be used to fabricate graphene-based structures and devices. They discuss the differences between natural and synthetic graphite, the necessary steps for converting them into graphene and how graphene can be used to produce composites.

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Self-assembly of flexible free-standing 3D porous MoS2-reduced graphene oxide structure for high-performance lithium-ion batteries

TL;DR: In this paper, a flexible, free-standing MoS2-reduced graphene oxide (MG) film with a 3D porous structure is fabricated via a facile spontaneous self-assembly process and subsequent freeze-drying.
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Graphene hybridization for energy storage applications

TL;DR: This review will focus on diverse graphene hybridization principles and strategies for energy storage applications, and the developed hybridization formulas of using graphene for lithium-ion batteries are systematically categorized from the viewpoint of material structure design, bulk electrode construction, and material/electrode collaborative engineering.
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Electrophoretic deposition of graphene-related materials: A review of the fundamentals

TL;DR: In this article, an overview of the fundamentals and specific technical aspects of this approach, highlighting its advantages and limitations, in particular considering the issues that arise specifically from the behaviour and dimensionality of GRMs.
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Base-Induced Liquid Crystals of Graphene Oxide for Preparing Elastic Graphene Foams with Long-Range Ordered Microstructures

TL;DR: Base-induced graphene oxide (GO) liquid crystals form a highly ordered texture that can be inherited by graphene foams prepared by hydrothermal reduction, showing a long-range ordered microstructure of graphene sheets in 3D.
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The charge carrier dynamics, efficiency and stability of two-dimensional material-based perovskite solar cells.

TL;DR: In this review, the recent progress in the development and application of TDMs (i.e., graphene, graphdiyne, transition metal dichalcogenides, BP, and others) as electrodes, hole transporting layers, electron transporting layers and buffer layers in PSCs is detailed.
References
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Journal ArticleDOI

Electric Field Effect in Atomically Thin Carbon Films

TL;DR: Monocrystalline graphitic films are found to be a two-dimensional semimetal with a tiny overlap between valence and conductance bands and they exhibit a strong ambipolar electric field effect.
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Synthesis of graphene-based nanosheets via chemical reduction of exfoliated graphite oxide

TL;DR: In this paper, a colloidal suspension of exfoliated graphene oxide sheets in water with hydrazine hydrate results in their aggregation and subsequent formation of a high surface area carbon material which consists of thin graphene-based sheets.
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Superior Thermal Conductivity of Single-Layer Graphene

TL;DR: The extremely high value of the thermal conductivity suggests that graphene can outperform carbon nanotubes in heat conduction and establishes graphene as an excellent material for thermal management.
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The chemistry of graphene oxide

TL;DR: This review will be of value to synthetic chemists interested in this emerging field of materials science, as well as those investigating applications of graphene who would find a more thorough treatment of the chemistry of graphene oxide useful in understanding the scope and limitations of current approaches which utilize this material.
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Graphene holds a lot of promise, but before it can be used commercially, methods are needed for producing processable forms of graphene in scalable amounts and also for incorporating graphene in devices.