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Chitosan as A Preservative for Fruits and Vegetables: A Review on Chemistry and Antimicrobial Properties

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TLDR
In this article, the antimicrobial properties of chitosan and its application as a natural preservative for fresh products are discussed, and the key properties that are related to food preservation are detailed.
Abstract
Chitosan, derived from chitin, a major constituent (in quantity) of crustaceans, is a unique aminopolysaccharide with emerging commercial potential in agriculture, food, pharmaceuticals and nutraceuticals due to its nontoxic, biodegradable and biocompatable properties. Chitosan coating on fruits and vegetables has been found to be effective for the reduction of a variety of harmful micro-organims and extend the shelf-life of these products. In this review, our focus is on the antimicrobial properties of chitosan and its application as a natural preservative for fresh products. We detailed the key properties that are related to food preservation, the molecular mechanism of the antimicrobial activity of chitosan on fungi, gram-positive and gram-negative bacteria, coating methods for using chitosan and its formulation for preserving fruits and vegetables, as well as the radiation method of producing chitosan from chitin. Understanding the economic and scientific factors of chitosan's production and efficiency as a preservative will open its practical application for fruits and vegetable preservation.

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Chitosan as an environment friendly biomaterial - a review on recent modifications and applications.

TL;DR: The abundance of chitosan and diversity in modifications can be effectively utilized in various applications leading to environmental friendly solutions as highlighted in this review.
Journal Article

Chitin and Chitosan

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Challenges and new opportunities on barrier performance of biodegradable polymers for sustainable packaging

TL;DR: In this article, the authors provide an in-depth study on the oxygen/water vapor barrier of representative biodegradable polymers in mainstream research with an emphasis on theoretical models and experimental modifications to improve their barrier properties.
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Chitosan: Structural modification, biological activity and application.

TL;DR: The preparation, physicochemical properties, chemical and physical modification methods of chitosan, which could help to understand its biological activities and applications, and some insights into its future potential are provided.
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Edible coatings and antimicrobial nanoemulsions for enhancing shelf life and reducing foodborne pathogens of fruits and vegetables: A review

TL;DR: Methods in which different coatings are applied to cut fruits and vegetables to prevent the development of foodborne pathogen diseases were reviewed, and essential oils and its nanoemulsion possess antioxidant and antimicrobial characteristics which considered being unique additives in the food industry.
References
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Journal ArticleDOI

Chitin and chitosan polymers: Chemistry, solubility and fiber formation

TL;DR: In this paper, a review discusses the various attempts reported on solving this problem from the point of view of the chemistry and the structure of these polymers highlighting the drawbacks and advantages of each method and proposes that based on considerations of structure-property relations, it is possible to obtain chitin fibers with improved strength by making use of their nanostructures and/or mesophase properties of chitins.
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Chitin and Chitosan Preparation from Marine Sources. Structure, Properties and Applications

TL;DR: Several selected pharmaceutical and biomedical applications are presented, in which chitin and chitosan are recognized as new biomaterials taking advantage of their biocompatibility and biodegradability.
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Biodegradation, biodistribution and toxicity of chitosan.

TL;DR: Research in this area is reviewed and chitosan's potential to be used as a generally regarded as safe (GRAS) material is critically discussed.
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Structures of Gram-Negative Cell Walls and Their Derived Membrane Vesicles

TL;DR: Gram-negative cell walls are strong enough to withstand ;3 atm of turgor pressure, tough enough to endure extreme temperatures and pHs, and elastic enough to be capable of expanding several times their normal surface area.
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Chitosan disrupts the barrier properties of the outer membrane of gram-negative bacteria.

TL;DR: Electron microscopy showed that chitosan caused extensive cell surface alterations and covered the OM with vesicular structures, explaining the loss of the barrier function of the outer membrane, which makes chitOSan a potentially useful indirect antimicrobial for food protection.
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