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Conducting Polymers Directly Coated on Reduced Graphene Oxide Sheets as High-Performance Supercapacitor Electrodes

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TLDR
In this article, conducting polymers poly(3,4-ethylenedioxythiophene) (PEDOT), polyaniline (PANi), and polypyrrole (PPy) were directly coated on the surface of reduced graphene oxide (RGO) sheets via an in situ polymerization process to prepare conducting polymer-RGO nanocomposites with different loadings of the conducting polymer.
Abstract
In this work, conducting polymers poly(3,4-ethylenedioxythiophene) (PEDOT), polyaniline (PANi), and polypyrrole (PPy) were directly coated on the surface of reduced graphene oxide (RGO) sheets via an in situ polymerization process to prepare conducting-polymer-RGO nanocomposites with different loadings of the conducting polymers. Experiment results showed that ethanol played an important role in achieving a uniform coating of the polymers on RGO sheets. The electrochemical capacitive properties of the composite materials were investigated by using cycle voltammetry and charge/discharge techniques. The composite consisting of RGO and PANi (RGO-PANi) exhibited a specific capacitance of 361 F/g at a current density of 0.3 A/g. The composites consisting of RGO and PPy (RGO-PPy) and PEDOT (RGO-PEDOT) displayed specific capacitances of 248 and 108 F/g, respectively, at the same current density. More than 80% of initial capacitance retained after 1000 charge/discharge cycles, suggesting a good cycling stability ...

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Flexible graphene–polyaniline composite paper for high-performance supercapacitor

TL;DR: In this paper, a grey metallic luster has been fabricated for the first time, by a convenient one-step method on a large scale, where the assembly of graphene oxide dispersion into ordered paper occurs simultaneously with the chemical reduction of the oxide to graphene.
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Research progress on conducting polymer based supercapacitor electrode materials

TL;DR: A review of conducting polymer (CP)-based supercapacitors can be found in this article, where the authors summarized recent research progress of conducting polymer-based electrodes for ultracapacitors, including polypyrrole, polyaniline and polythiophene.
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Recent progress on graphene-based photocatalysts: current status and future perspectives

TL;DR: In this tutorial review, the applications of GR-based nanocomposites in photocatalysis, including nonselective processes for degradation of pollutants, selective transformations for organic synthesis and water splitting to clean hydrogen energy, are summarized systematically.
Journal ArticleDOI

Polyaniline and polypyrrole pseudocapacitor electrodes with excellent cycling stability.

TL;DR: This work demonstrates a simple and general strategy to substantially enhance the cycling stability of conductive polymer electrodes by deposition of a thin carbonaceous shell onto their surface by fabricating stable polymer electrodes with comparable specific capacitance and pseudocapacitive behavior as the bare polymer electrodes.
Journal ArticleDOI

Highly Flexible, Freestanding Supercapacitor Electrode with Enhanced Performance Obtained by Hybridizing Polypyrrole Chains with MXene

TL;DR: In this paper, a new approach to enhance PPy's capacitance and cycling stability by forming a freestanding and conductive hybrid film through intercalating polypyrrole into layered Ti3C2, a MXene material, was reported.
References
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Journal ArticleDOI

Materials for electrochemical capacitors

TL;DR: This work has shown that combination of pseudo-capacitive nanomaterials, including oxides, nitrides and polymers, with the latest generation of nanostructured lithium electrodes has brought the energy density of electrochemical capacitors closer to that of batteries.
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Synthesis of graphene-based nanosheets via chemical reduction of exfoliated graphite oxide

TL;DR: In this paper, a colloidal suspension of exfoliated graphene oxide sheets in water with hydrazine hydrate results in their aggregation and subsequent formation of a high surface area carbon material which consists of thin graphene-based sheets.
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Graphene-based composite materials

TL;DR: The bottom-up chemical approach of tuning the graphene sheet properties provides a path to a broad new class of graphene-based materials and their use in a variety of applications.
Journal ArticleDOI

Processable aqueous dispersions of graphene nanosheets

TL;DR: It is reported that chemically converted graphene sheets obtained from graphite can readily form stable aqueous colloids through electrostatic stabilization, making it possible to process graphene materials using low-cost solution processing techniques, opening up enormous opportunities to use this unique carbon nanostructure for many technological applications.
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