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Journal ArticleDOI

Dumbbell-like Bifunctional Au−Fe3O4 Nanoparticles

TLDR
The dumbbell is formed through epitaxial growth of iron oxide on the Au seeds, and the growth can be affected by the polarity of the solvent, as the use of diphenyl ether results in flower-like Au-Fe(3)O(4) nanoparticles.
Abstract
Dumbbell-like Au−Fe3O4 nanoparticles are synthesized using decomposition of Fe(CO)5 on the surface of the Au nanoparticles followed by oxidation in 1-octadecene solvent. The size of the particles is tuned from 2 to 8 nm for Au and 4 nm to 20 nm for Fe3O4. The particles show the characteristic surface plasmon absorption of Au and the magnetic properties of Fe3O4 that are affected by the interactions between Au and Fe3O4. The dumbbell is formed through epitaxial growth of iron oxide on the Au seeds, and the growth can be affected by the polarity of the solvent, as the use of diphenyl ether results in flower-like Au−Fe3O4 nanoparticles.

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Citations
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Sonochemical synthesis, structure and magnetic properties of air-stable Fe3O4/Au nanoparticles

TL;DR: In this paper, a solution mixture of hydrogen tetrachloroaureate(III) trihydrate (HAuCl4) and (3-aminopropyl)triethoxysilane (APTES)-coated Fe3O4 nanoparticles with further drop-addition of sodium citrate was obtained.
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Gold-coated iron nanoparticles: a novel magnetic resonance agent for T1 and T2 weighted imaging

TL;DR: In this article, a reverse micelle method was used to extract core/shell structured iron(Fe)/gold(Au) nanoparticles and their potential application as magnetic resonance (MR) contrast agent was investigated.
Journal ArticleDOI

Epitaxial CdSe-Au Nanocrystal Heterostructures by Thermal Annealing

TL;DR: The thermal evolution of a collection of heterogeneous CdSe-Au nanosystems prepared by wet-chemical approaches was monitored in situ in the transmission electron microscope to make the heterostructures more suitable for use in nanoscale electronic devices.
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Multifunctional Two-Photon Active Silica-Coated Au@MnO Janus Particles for Selective Dual Functionalization and Imaging

TL;DR: The silica-coated Au@MnO@SiO2 Janus particles were revealed to be highly two-photon active; no indication for an electronic interaction between the dye molecules incorporated in the silica shell surrounding the MnO domains and the attached Au domains was found; fluorescence quenching was observed when dye molecules were bound directly to the Au domains.
Journal ArticleDOI

Solvent-Dependent Surface Plasmon Response and Oxidation of Copper Nanocrystals

TL;DR: In this paper, the authors report the synthesis of colloidal copper nanocrystals and subsequent solvent-dependent oxidation to form copper(I) oxide nanoparticles, and the initial intensity of the copper plasmon was strongly dependent on the properties of the solvent used to form the nanocrystal dispersion.
References
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Journal ArticleDOI

Gold nanoparticles: assembly, supramolecular chemistry, quantum-size-related properties, and applications toward biology, catalysis, and nanotechnology.

TL;DR: A review of gold nanoparticles can be found in this article, where the most stable metal nanoparticles, called gold colloids (AuNPs), have been used for catalysis and biology applications.
Journal ArticleDOI

Monodisperse MFe2O4 (M = Fe, Co, Mn) Nanoparticles

TL;DR: As-synthesized iron oxide nanoparticles have a cubic spinel structure as characterized by HRTEM, SAED, and XRD and can be transformed into hydrophilic ones by adding bipolar surfactants, and aqueous nanoparticle dispersion is readily made.
Journal ArticleDOI

Nanoparticles with Raman Spectroscopic Fingerprints for DNA and RNA Detection

TL;DR: Six dissimilar DNA targets with six Raman-labeled nanoparticle probes were distinguished, as well as two RNA targets with single nucleotide polymorphisms, and the current unoptimized detection limit of this method is 20 femtomolar.
Journal ArticleDOI

Novel Gold Catalysts for the Oxidation of Carbon Monoxide at a Temperature far Below 0 °C

TL;DR: In this article, a variety of gold catalysts are used to catalyze the oxidation of carbon monoxide at temperatures as low as −70 °C and are stable in a moistened gas atmosphere.
Journal ArticleDOI

Epitaxial Growth of Highly Luminescent CdSe/CdS Core/Shell Nanocrystals with Photostability and Electronic Accessibility

TL;DR: The synthesis of epitaxially grown, wurtzite CdSe/CdS core/shell nanocrystals is reported in this paper, where shells of up to three monolayers in thickness were grown on cores ranging in diameter from 23 to 39.
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